Environmentally sustainable catalytic asymmetric oxidations
- Konstantin Bryliakov.
- Boca Raton : CRC Press, Taylor & Francis Group, 
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- Physical description
- xii, 149 pages : illustrations ; 25 cm
At the library
Science Library (Li and Ma)
|QD281 .O9 B79 2015||Unknown|
- Bryliakov, Konstantin, author.
- Includes bibliographical references and index.
- Introduction Transition Metal-Catalyzed Asymmetric Epoxidations Manganese Systems Iron and Ruthenium Systems Titanium Systems Systems Based on Other Metals Transition Metal-Catalyzed Asymmetric Sulfoxidations Vanadium Systems Titanium Systems Iron Systems Systems Based on Other Metals Miscellaneous Transition Metal-Catalyzed Asymmetric Oxidations Cis-Dihydroxylations of Olefins Baeyer-Villiger Oxidations Oxidative Kinetic Resolution of Secondary Alcohols and Desymmetrization of Meso-Diols Enantioselective Aerobic Oxidative Coupling of 2-Naphthols Enantioselective C-H Oxidations Organocatalytic Asymmetric Oxidations Epoxidations Miscellaneous Oxidations Fe- and Mn-Based Synthetic Models of Non-Heme Oygenases: Stereospecific C-H Oxidations Iron Systems Manganese Systems Active Species and Mechanisms of Non-Heme Fe- and Mn-Catalyzed Oxidations Iron Systems Manganese Systems Industrial Perspective General Remarks Some Examples Outlook.
- (source: Nielsen Book Data)
- Publisher's Summary
Catalysis plays a vital role in chemical, petroleum, agriculture, polymer, electronics, pharmaceutical, and other industries. Over 90 percent of chemicals originate from catalytic processes. Toughening economic and environmental constraints have proven to be a challenge for meeting the demand of novel efficient and sustainable regio- and stereoselective catalyst systems. Environmentally Sustainable Catalytic Asymmetric Oxidations provides a comprehensive overview of existing ecologically friendly catalyst systems for various asymmetric oxidation processes. Topics include: * A survey of existing transition metal-based catalyst systems for asymmetric epoxidations (AEs) with O2 and H2O2 * Asymmetric sulfoxidations with H2O2 on chiral metal complexes * An overview of various transition metal-catalyzed oxidative transformations with H2O2 or O2 used as the terminal oxidant * Organocatalytic asymmetric oxidations * Catalytic processes of stereospecific oxidations of C-H functional groups * The role that oxoiron(V) intermediates play in chemo- and stereoselective oxidations catalyzed by non-heme iron complexes The book concludes with a discussion of the opportunities and problems associated with the industrial application of stereoselective processes of catalytic oxidation with H2O2 and O2. It also provides examples of processes with industrial potential. Some of the catalysts presented in this book may serve as promising alternatives for existing catalysts-progressively replacing them in manufacturing processes and ultimately making the chemical industry greener and cleaner.
(source: Nielsen Book Data)
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