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Book
xxiv, 763, I-13 : illustrations ; 24 cm
Science Library (Li and Ma)
CHEM-155-01, CHEM-255-01
Book
1 online resource (xvi, 504 pages)
  • Preface xi List of Abbreviations xiii 1 Introduction 1 1.1 Why Study Organometallic Chemistry?, 1 1.2 Coordination Chemistry, 3 1.3 Werner Complexes, 4 1.4 The Trans Effect, 9 1.5 Soft versus Hard Ligands, 10 1.6 The Crystal Field, 11 1.7 The Ligand Field, 19 1.8 The sdn Model and Hypervalency, 21 1.9 Back Bonding, 23 1.10 Electroneutrality, 27 1.11 Types of Ligand, 29 References, 37 Problems, 38 2 Making Sense of Organometallic Complexes 40 2.1 The 18-Electron Rule, 40 2.2 Limitations of the 18-Electron Rule, 48 2.3 Electron Counting in Reactions, 50 2.4 Oxidation State, 51 2.5 Coordination Number and Geometry, 57 2.6 Effects of Complexation, 60 2.7 Differences between Metals, 63 References, 66 Problems, 67 3 Alkyls and Hydrides 69 3.1 Alkyls and Aryls, 69 3.2 Other -Bonded Ligands, 84 3.3 Metal Hydrides, 86 3.4 Sigma Complexes, 89 3.5 Bond Strengths, 92 References, 95 Problems, 96 4 Carbonyls, Phosphines, and Substitution 98 4.1 Metal Carbonyls, 98 4.2 Phosphines, 109 4.3 N-Heterocyclic Carbenes (NHCs), 113 4.4 Dissociative Substitution, 115 4.5 Associative Substitution, 120 4.6 Redox Effects and Interchange Substitution, 122 4.7 Photochemical Substitution, 124 4.8 Counterions and Solvents in Substitution, 127 References, 129 Problems, 131 5 Pi-Complexes 134 5.1 Alkene and Alkyne Complexes, 134 5.2 Allyls, 140 5.3 Diene Complexes, 144 5.4 Cyclopentadienyl Complexes, 147 5.5 Arenes and Other Alicyclic Ligands, 154 5.6 Isolobal Replacement and Metalacycles, 158 5.7 Stability of Polyene and Polyenyl Complexes, 159 References, 160 Problems, 161 6 Oxidative Addition and Reductive Elimination 163 6.1 Introduction, 163 6.2 Concerted Additions, 166 6.3 SN2 Pathways, 168 6.4 Radical Mechanisms, 170 6.5 Ionic Mechanisms, 172 6.6 Reductive Elimination, 173 6.7 -Bond Metathesis, 179 6.8 Oxidative Coupling and Reductive Fragmentation, 180 References, 182 Problems, 182 7 Insertion and Elimination 185 7.1 Introduction, 185 7.2 CO Insertion, 187 7.3 Alkene Insertion, 192 7.4 Outer Sphere Insertions, 197 7.5 , , , and Elimination, 198 References, 201 Problems, 201 8 Addition and Abstraction 204 8.1 Introduction, 204 8.2 Nucleophilic Addition to CO, 207 8.3 Nucleophilic Addition to Polyenes and Polyenyls, 208 8.4 Nucleophilic Abstraction in Hydrides, Alkyls, and Acyls, 215 8.5 Electrophilic Addition and Abstraction, 216 8.6 Single-Electron Transfer and Radical Reactions, 219 References, 221 Problems, 222 9 Homogeneous Catalysis 224 9.1 Catalytic Cycles, 224 9.2 Alkene Isomerization, 231 9.3 Hydrogenation, 233 9.4 Alkene Hydroformylation, 242 9.5 Alkene Hydrocyanation, 245 9.6 Alkene Hydrosilylation and Hydroboration, 246 9.7 Coupling Reactions, 248 9.8 Organometallic Oxidation Catalysis, 250 9.9 Surface, Supported, and Cooperative Catalysis, 251 References, 253 Problems, 256 10 Physical Methods 259 10.1 Isolation, 259 10.2 1H NMR Spectroscopy, 260 10.3 13C NMR Spectroscopy, 264 10.4 31P NMR Spectroscopy, 266 10.5 Dynamic NMR, 268 10.6 Spin Saturation Transfer, 271 10.7 T1 and the Nuclear Overhauser Effect, 272 10.8 IR Spectroscopy, 276 10.9 Crystallography, 279 10.10 Electrochemistry and EPR, 281 10.11 Computation, 283 10.12 Other Methods, 285 References, 287 Problems, 288 11 M L Multiple Bonds 290 11.1 Carbenes, 290 11.2 Carbynes, 302 11.3 Bridging Carbenes and Carbynes, 305 11.4 N-Heterocyclic Carbenes, 306 11.5 Multiple Bonds to Heteroatoms, 310 References, 313 Problems, 315 12 Applications 317 12.1 Alkene Metathesis, 317 12.2 Dimerization, Oligomerization, and Polymerization ofAlkenes, 324 12.3 Activation of CO and CO2, 332 12.4 C H Activation, 336 12.5 Green Chemistry, 343 12.6 Energy Chemistry, 344 References, 347 Problems, 349 13 Clusters, Nanoparticles, Materials, and Surfaces353 13.1 Cluster Structures, 354 13.2 The Isolobal Analogy, 364 13.3 Nanoparticles, 368 13.4 Organometallic Materials, 371 References, 379 Problems, 381 14 Organic Applications 383 14.1 Carbon Carbon Coupling, 384 14.2 Metathesis, 391 14.3 Cyclopropanation and C H Insertion, 393 14.4 Hydrogenation, 394 14.5 Carbonylation, 396 14.6 Oxidation, 399 14.7 C H Activation, 401 14.8 Click Chemistry, 405 References, 406 Problems, 408 15 Paramagnetic and High Oxidation-State Complexes411 15.1 Magnetism and Spin States, 413 15.2 Polyalkyls and Polyhydrides, 420 15.3 Cyclopentadienyl Complexes, 425 15.4 f-Block Complexes, 426 References, 433 Problems, 435 16 Bioorganometallic Chemistry 436 16.1 Introduction, 437 16.2 Coenzyme B12, 442 16.3 Nitrogen Fixation, 449 16.4 Nickel Enzymes, 457 16.5 Biomedical and Biocatalytic Applications, 463 References, 465 Problems, 467 Appendix A: Useful Texts on Allied Topics 469 Appendix B: Major Reaction Types and Hints on Problem Solving472 Solutions to Problems 475 Index 493.
  • (source: Nielsen Book Data)9781118138076 20160616
Fully updated and expanded to reflect recent advances, the sixth edition of this bestselling text provides students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications. Increased focus is given to organic synthesis applications, nanoparticle science, and green chemistry. This edition features: * New sections on Multifunctional Ligands, Oxidation Catalysis, and Green Chemistry * Expanded discussion on topics from the fifth edition: Supramolecular Chemistry, N-Heterocyclic Carbenes, Coupling Reactions, Organometallic Materials, Applications to Organic Synthesis, and Bioorganometallic Chemistry * End-of-chapter problems and their solutions.
(source: Nielsen Book Data)9781118138076 20160616
eReserve
CHEM-155-01, CHEM-255-01
Book
xvii, 998 p. : ill. ; 25 cm.
  • Preface. Preface to the Second Edition. Preface to the First Edition. Contributors. 1 Catalytic Asymmetric Synthesis in Non-Conventional Media/Conditions ( Chikako Ogawa and Shu Kobayashi ). 2 Asymmetric Organocatalysis. 2A Enantioselective Organocatalysis Involving Iminium, Enamine, SOMO and Photoredox Activation ( Allan J. B. Watson and David W. C. MacMillan ). 2B Asymmetric Acid-Base Bifunctional Catalysis with Organic Molecules ( Yi Wang and Li Deng ). 2C Asymmetric Phase-Transfer and Ion Pair Catalysis ( Seiji Shirakawa and Keiji Maruoka ). 3 Chiral Lewis Acids and Bronsted Acids in Asymmetric Synthesis ( Hisashi Yamamoto and Cheol Hong Cheon ). 4 Asymmetric Synthesis through C H Activation ( Huw M. L. Davies and Jorn Hansen ). 5 Asymmetric Carbon-Heteroatom Bond-Forming Reactions ( Yoshiji Takemoto and Hideto Miyabe ). 6 Enzyme-Catalyzed Asymmetric Synthesis ( Harald Groger ). 7 Transition Metal-Catalyzed Homogeneous Asymmetric Hydrogenation ( Gao Shang, Wei Li and Xumu Zhang ). 8 Asymmetric Carbon-Carbon Bond Forming Reactions. 8A Catalytic Asymmetric Conjugate Addition ( Jian-Xin Ji and Albert S. C. Chan ). 8B Enantioselective Allylic Substitutions with Carbon-Nucleophiles ( Gunter Helmchen, Uli Kazmaier and Sebastian Forster ). 8C Asymmetric Carbometallation and Carbocyclizations ( Iwao Ojima, Joseph J. Kaloko, Stephen J. Chaterpaul, Yu-Han Gary Teng and Chi-Feng Lin ). 8D Asymmetric Ene Reactions and Cycloadditions ( Koichi Mikami and Kohsuke Aikawa ). 8E Catalytic Enantioselective Olefin Metathesis Reactions ( Amir H. Hoveyda, Steven J. Malcolmson, Simon J. Meek and Adil R. Zhugralin ). 9 Asymmetric Hydrosilation of Carbon-Carbon Double Bonds and Related Reactions ( Jin Wook Han and Tamio Hayashi ). 10 Asymmetric Carbonylations ( Cyril Godard, Aurora Ruiz, Montserrat Dieguez, Oscar Pamies and Carmen Claver ). 11 Asymmetric Oxidations and Related Reactions ( Kazuhiro Matsumoto and Tsutomu Katsuki ). 12 Asymmetric Amplification and Autocatalysis ( Kenso Soai, Tsuneomi Kawasaki, and Takanori Shibata ). 13 Asymmetric Polymerization ( Shingo Ito and Kyoko Nozaki ). Index.
  • (source: Nielsen Book Data)9780470175774 20160604
Since the last edition was published seven years ago, catalytic asymmetric synthesis has become crucial to chemistry and to the preparation of pharmaceutical, fine chemical, and agricultural agents. The revised Catalytic Asymmetric Synthesis includes six new chapters on topics like non-conventional media/conditions, organocatalysis, CH activation, and much more, while the book's remaining chapters have been fully updated. A new section on carbon-carbon bond forming reactions, authored by distinguished Nobel prizewinning scientists, has been added. This revision, with a helpful appendix, is an essential reference on catalytic asymmetric synthesis for both chemists and students alike.
(source: Nielsen Book Data)9780470175774 20160604
Science Library (Li and Ma)
CHEM-155-01, CHEM-255-01
Book
xxx, 1127 p. : ill. ; 29 cm.
  • Structure and Bonding Dative Ligands Covalent Ligands Bound Through Metal-Carbon and Metal-Hydride Bonds Covalent Ligands Bound Through Metal-Heteroatom Bonds Ligand Substitution Reactions Oxidative Addition of Non-Polar Reagents Oxidative Addition of Polar Reagents Reductive Elimination Migratory Insertion Elimination Reactions Nucleophilic Attack on Coordinated Ligands Electrophilic Attack on Coordinated Ligands Metal-Ligand Multiple Bonds Principles of Catalysis Homogenous Hydrogenation Hydrofunctionalization and Oxidative Functionalization of Olefins Catalytic Carbonylation Catalytic C-H Functionalization Cross Coupling Allylic Substitution Catalytic Metathesis of Olefins and Alkynes Olefin Polymerization.
  • (source: Nielsen Book Data)9781891389535 20160528
Based on the best-selling classic text by James P. Collman, Louis S. Hegedus, Jack R. Norton, and Richard Finke, Principles and Applications of Organotransition Metal Chemistry, Hartwig's new text provides a comprehensive new update of this vital field. It covers the most important developments in the field over the last 20 years.
(source: Nielsen Book Data)9781891389535 20160528
Science Library (Li and Ma)
CHEM-155-01, CHEM-255-01
Book
xii, 459 p. : ill. ; 29 cm.
  • Formalisms, Electron Counting, Bonding (How Things Work) Organometallic Reaction Mechanisms Synthetic Applications of Transition Metal Hydrides Synthetic Applications of Complexes Containing Metal-Carbon Sigma-Bonds Synthetic Applications of Transition Metal Carbonyl Complexes Synthetic Applications of Transition Metal Carbene Complexes Synthetic Applications of Transition Metal Alkene, Diene, and Dienyl Complexes Synthetic Applications of Transition Metal Alkyne Complexes Synthetic Applications of eta3-Allyl Transition Metal Complexes Synthetic Applications of Transition Metal Arene Complexes Reactions of eta6-Arenemetal Complexes Index.
  • (source: Nielsen Book Data)9781891389597 20160528
This texts offers a clear and systematic approach to the formation, manipulation, and reactivity of organometallic complexes. It presents the organic chemistry of transition metals by class of metal complex, with many examples of applications in the synthesis of complex natural products and pharmaceuticals.
(source: Nielsen Book Data)9781891389597 20160528
Science Library (Li and Ma)
CHEM-155-01, CHEM-255-01
Book
viii, 521 p. : ill. ; 25 cm.
  • 1. Tools of the Trade-- 2. Rate Law & Mechanism-- 3. Ligand Substitution Reactions-- 4. Stereochemical Change-- 5. Reaction Mechanisms of Organometallic Systems-- 6. Oxidation-Reduction Reaction-- 7. Inorganic Photochemistry-- 8. Bioinorganic Systems-- 9. Kinetics in Heterogeneous Systems-- 10. Experimental Methods-- Problems-- Chemical Abbreviations-- Index.
  • (source: Nielsen Book Data)9780195301007 20160528
This third edition retains the general level and scope of earlier editions, but has been substantially updated with over 900 new references covering the literature through 2005, and 140 more pages of text than the previous edition. In addition to the general updating of materials, there is new or greatly expanded coverage of topics such as Curtin-Hammett conditions, pressure effects, metal hydrides and asymmetric hydrogenation catalysts, the inverted electron-transfer region, intervalence electron transfer, photochemistry of metal carbonyls, methyl transferase and nitric oxide synthase. The new chapter on heterogeneous systems introduces the basic background to this industrially important area. The emphasis is on inorganic examples of gas/liquid and gas/liquid/solid systems and methods of determining heterogeneity.
(source: Nielsen Book Data)9780195301007 20160528
Science Library (Li and Ma)
CHEM-155-01, CHEM-255-01
Book
3 v. (xliii, 1450 p.) : ill., ports. ; 25 cm.
  • VOLUME 1: APPLICATIONS. Introduction (B. Cornils and W. A. Herrmann) Introduction Historical Glossary Applied Homogeneous Catalysis. Carbon Monoxide and Synthesis Gas Chemistry. Hydrogenation (H. Brunner). Reactions of Unsaturated Compounds. Oxidations. Reactions with Hydrogen Cyanide (Hydrocyanation) (S. Krill). Hydrosilyation and Related Reactions of Silicon Compounds (B. Marciniec). Reaction with Nitrogen Compounds: Hydroamination (R. Taube). Reactions of Hydrocarbons and Other Saturated Compounds. Asymmetric Syntheses (R. Noyori, et al.). Ferrocene as a Gasoline and Fuel Additive (W. Herrmann). The Suzuki Cross Coupling (W. Herrmann). VOLUME 2: DEVELOPMENTS. Recent Developments in Homogeneous Catalysis. Development of Methods. Special Catalysts and Processes. Special Products. Epilogue. Homogeneous Catalysis Quo vadis? (W. Herrmann and B. Cornils). Index.
  • (source: Nielsen Book Data)9783527304349 20160528
Homogeneous catalysis is the success story of organometallic chemistry. Since the discovery of hydroformylation by O. Roelen in 1938, catalytic applications have paved the way of organometallic compounds in industry. Bulk and fine chemicals, and even natural products are being produced via homogeneous organometallic catalysis. The enormous breadth of this topic in view of both basic research and industrial application is met in this three volume handbook edited jointly by W. A. Herrmann and B. Cornils. The list of contributors reads like a who-is-who in organometallic chemistry and homogeneous catalysis. In this handbook, experts will find the current state-of-the-art in their field and advanced students will benefit from the concise treatment of important catalytic reactions and processes. With its balanced presentation of the truly interdisciplinary topic and its outstanding editor- and authorship, the 'Cornils/Herrmann' is beyond common standards. Now in its second, completely revised and enlarged edition!.
(source: Nielsen Book Data)9783527304349 20160528
Science Library (Li and Ma)
CHEM-155-01, CHEM-255-01
Book
xii, 281 p. : ill. ; 25 cm.
Science Library (Li and Ma)
CHEM-155-01, CHEM-255-01
Book
2 v. (xxxv, 3279 p.) : ill. ; 26 cm.
Organized to provide maximum utility to the bench synthetic chemist. * The editor is well-known for his work in exploring, developing, and applying organopalladium chemistry. * Contributors include over 24 world authorities in the field.
(source: Nielsen Book Data)9780471315063 20160528
Science Library (Li and Ma)
CHEM-155-01, CHEM-255-01
Book
xvi, 472 p. : ill. ; 24 cm.
  • Preface. Abbreviations. Introduction: The Olefin Metathesis Reaction. Brief History. The Metal Carbene Mechanism. Equilibria and Stereoselectivity. Survey of Catalyst Systems: Group IV. Group V. GroupVI. Group VII. Group VIII. Photochemically Activated Catalysts. The Metal Carbene/Metallacyclobutane Mechanism: Evidence from Cross-Metathesis Reactions. Evidence from the Stereochemistry of Metathesis of Internal Olefins. Evidence from Ring-Opening Metathesis Polymerization (ROMP). Evidence from the reactions of Well-Defined Metal Carbene Complexes. Evidence from the Reactions of Metallacyclobutane Complexes. Evidence of Initiating Species in Systems with Non-Carbene Catalysts. Theoretical Treatments. Related Reactions: [2+2] Reactions Between Compounds Containing Multiple Bonds. Relationship to Ziegler-Natta Polymerization. Involvement of Three-Membered Ring Compounds in Metathesis Reactions. Ethene and Terminal Alkenes: Ethene. Propene. But-1-ene and its Derivatives. Pent-1-ene and its Derivatives. Hex-1-ene and its Derivatives. Higher Acyclic Terminal Alkenes. Acyclic Disubstituted and Trisubstituted Ethenes. Cis/trans Isomerization. Pent-2-ene and 4-Substituted Derivatives. Hex-2-ene and 4-Methylhex-2-ene.Hept-2-ene and Hept-3-ene. Higher Acyclic Internal Olefins. Stereoselectivity in the Metathesis of Acyclic Olefins. 1,1-Disubstituted Olefins. Trisubstituted Ethenes. Acyclic Functionalized Alkenes: Esters. Other Carbonyl-Containing Compounds. Ethers. Amines. Nitriles. Chlorides and Bromides. Sulfides and Sulfonates. Silancs and Germanes. Phospanes. Acyclic Dienes: Double Bonds Linked only by C Atoms. Double Bonds Linked by C and Si, Ge orSn Atoms. Double Bonds Linked by C and N Atoms. Double Bonds Linked by C, Si, and O Atoms. Divinylferrocene. Some Further Applications in Organic Synthesis. Copolymers by Metathesis Condensation. Cross-Metathesis Between Acyclic Compounds: Ethene.Propene. Butenes. Pentenes. Hexenes. Higher Olefins. Functionalized Olefins. Acetylenes: Metathesis Reactions Involving Total Cleavage of the C=C bond. Metathesis Reactions Involving Cleavage of Two of the thress C=C Bonds. Metathesis Reactions of Enynes and Dienynes. Other Metathesis Routes to Polyacetylenes. Ring-Opening Metathesis Polymerization: General Aspects: Thermodynamic Aspects. Efficiency of Initiation. The Use of Chain-Transfer Agents. Molecular Weight Distributions. Polymer Micostructure. Monocyclic Alkenes and Polyenes: Four-Membered Rings. Five-Membered Rings. Six-Membered Rings. Seven-Membered Rings. Eight-Membered Rings. Nine-Membered Rings. Ten-Membered Rings. Twelve-Membered and Other Rings. Polycyclic Alkenes: Monomers Containing a Fused Cyclobutene Ring. Monomers Containing a Fused Cyclopentene Ring and One Double Bond. Monomers Containing a Fused Cyclopentene Ring and More than One Double Bond. Bicyclo[2.2.1] Compounds Containing Heteroatoms in the Ring System. Other Bicyclic Compounds. Copolymers of Cycloalkenes: Direct Metathesis Copolymerization. Cyclic Co-Oligomers. Block Copolymers by Sequential Addition of Monomers to Living Systems. Block Copolymers by Modification of Homopolymers. Comb and GraftCopolymers. Copolymers by ROMP in Conjunction with Radical Reactions. Cross-Metathesis Between Cyclic and Acyclic Olefins: End-Groups and Telomers. Dependence of Molecular Weight on [M<->2]/[M<->1]. Kinetic Data. Degradation of UnsaturatedPolymers by Metathesis: Degradation by Intramolecular Metathesis. Applications of the Olefin Metathesis Reaction: The Phillips Triolefin Process. The Neohexene Process. The Shell Higher Olefins Process. Other Multistage Processes Involving Metathesis. The Isoamylene Process. (Circle around alpha and omega) ((-Diolefins. trans-Poly(1-Pentenylene). trans-Poly(1-octenylene). Polymers of Norhornene. Polymers of Norbornene Derivatives. Miscellaneous. Bibliography. Subject Index.
  • (source: Nielsen Book Data)9780123770455 20160528
This book is a follow-up to Ivins "Olefin Metathesis", (Academic Press, 1983). Bringing the standard text in the field up to date, this Second Edition is a result of rapid growth in the field, sparked by the discovery of numerous well-defined metal carbene complexes that can act as very efficient initiators of all types of olefin metathesis reaction, including ring-closing metathesis of acyclic dienes, enynes, and dienynes; ring-opening metathesis polymerizationof cycloalkenes, acyclic diene metathesis polymerization; and polymerization of alkynes, as well as simple olefin metathesis. "Olefin Metathesis and Metathesis Polymerization" provides a broad, up-to-date account of the subject from its beginnings in 1957 to the latest applications in organic synthesis. The book follows the same format as the original, making it useful to teachers and to researchers, and will be of particular interest to those working in the fields of organic chemistry, polymer chemistry, organometallic chemistry, catalysis, materials science and chemical engineering. It: discusses different classes of olefin metathesis and the choice of reaction conditions and catalyst; considers commercial processes with examples from existing and new technologies; and provides a complete overview of the subject from its beginning to the present day.
(source: Nielsen Book Data)9780123770455 20160528
Science Library (Li and Ma)
CHEM-155-01, CHEM-255-01
Book
xii, 281 p. : ill. ; 25 cm.
  • Reactions and reaction rates-- reactions with a simple kinetic form-- reversible and concurrent reactions-- consecutive reactions - the steady state and other approximations-- consecutive mechanisms - intermediates and numerical solutions-- deduction of reaction mechanisms-- transition state theory and microscopic reversibility-- chain reactions and oscillating reactions-- reactions in solution-- extrakinetic probes of mechanism-- reactions at extreme rates.
  • (source: Nielsen Book Data)9780070202603 20160527
This book covers chemical kinetics from the working chemist's point of view. Competing books present a more theoretical presentation of kinetics. This book is a "how to" book for designing experiments, analyzing them and critiquing them. This book also prepares chemists to devise experiments to test different hypothesis. A large number of examples from the research literature have been used as the main teaching tool. Each book will come with a diskette that helps solve end-of-chapter problems.
(source: Nielsen Book Data)9780070202603 20160527
Science Library (Li and Ma)
CHEM-155-01, CHEM-255-01
Book
xxi, 630 p. : ill. ; 24 cm.
Science Library (Li and Ma)
CHEM-155-01, CHEM-255-01
Book
xvii, 378 p. : ill. ; 25 cm.
  • Homogeneous Asymmetric Hydrogenation. Enantioselective Isomerization of Olefins. Asymmetric Catalysis via Chiral Metal Complexes: Selected Examples. Enantioselective Addition of Organometallic Reagents to Carbonyl Compounds: Chirality Transfer, Multiplication, and Amplification. Three--Component Synthesis of Prostaglandins. Asymmetric Catalysis with Purely Organic Compounds. Heterogeneous Asymmetric Catalysis. Index.
  • (source: Nielsen Book Data)9780471572671 20160528
Deals with basic principles of asymmetric catalysis focusing on its synthetic significance. Covers homogeneous asymmetric hydrogenation, asymmetric catalysis via chiral metal complexes, heterogeneous catalysis and non-organometallic catalysis. The collection of a range of stereoselective reactions illustrate various strategies and methodologies as well as their general utility.
(source: Nielsen Book Data)9780471572671 20160528
Science Library (Li and Ma)
CHEM-155-01, CHEM-255-01
Book
xii, 342 p. : ill. ; 25 cm.
  • Trends in Homogeneous Catalysis in Industry. Isomerization of Olefins. Reactions of Olefins and Dienes----Hydrogenation and HY Additions. Polymerization and Oligomerization of Olefins and Dienes. Reactions of Carbon Monoxide. Oxidation of Olefins and Dienes. Arene Reactions. Reactions of Acetylenes. Carbene Complexes in Olefin Metathesis and Ring--Forming Reactions. Oxidation of Hydrocarbons by Oxygen. Esterification, Polycondensation, and Related Processes. Homogeneous Catalysis in Halocarbon Chemistry. Appendix. Index.
  • (source: Nielsen Book Data)9780471538295 20160528
Contains a balanced discussion of homogeneous catalytic reactions that are used in industry, featuring every documented example employed in a current commercial process, or that have a broad application in the organic synthesis laboratory. Incorporates synthesis with chiral catalysts in chapters on hydrogenation, CO chemistry and olefin oxidation. New additions include Tennessee Eastman's coal-based acetic anhydride plant and IFP's Dimersol process for dimerizing propylene as well as major changes in the areas on pharmaceuticals, flavors, fragrances, agricultural and electronic chemicals.
(source: Nielsen Book Data)9780471538295 20160528
Science Library (Li and Ma)
CHEM-155-01, CHEM-255-01
Book
x, 989 p. : ill. ; 24 cm.
  • A perspective-- Bonding-- Survey of organotransition metal complexes according to ligand-- Ligand substitution processes-- Oxidative-addition and reductive elimination-- Intramolecular insertion reactions-- Nucleophilic attack on ligands coordinated to transition metals-- Electrophilic attacks on coordinated ligands-- Metallacycles-- Homogeneous catalytic hydrogenation, hydrosilation, and hydrocyanation-- Catalytic polymerization of olefins and acetylenes-- Catalytic reactions involving carbon monoxide-- Synthetic applications of transition metal hydrides-- Synthetic applications of transition metal complexes containing metal carbon bonds-- Synthetic applications of transition metal carbonyl compounds-- Synthetic application of transition metal carbenes and metallacycles-- Synthetic applications of transition metal alkene, diene, and duenyl complexes-- Synthetic applications of transition metal alkyne complexes-- Synthetic applications of -allyl transition metal complexes-- Synthetic applications of transition metal arene complexes.
  • (source: Nielsen Book Data)9780935702514 20160528
This textbook introduces students and experienced chemists to a rapidly growing interdisciplinary subject. It incorporates a thorough revision of the earlier edition, and includes all new developments.
(source: Nielsen Book Data)9780935702514 20160528
Science Library (Li and Ma)
CHEM-155-01, CHEM-255-01
Book
xvi, 455 p. : ill. ; 24 cm.
  • List of Abbreviations-- Introduction-- Fundamentals of Coordination Chemistry-- Nature of the Metal- Carbon Bond and Electronic Configurations of Transition Metal Complexes-- Syntheses of Organotransition Metal Complexes-- Experimental Techniques in Organometallic Chemistry-- Fundamental Processes in Reactions of Organotransition Metal Complexes-- Application of Transition Metal Complexes to Catalysis-- Organic Synthesis Using Transition Metal Complexes-- Topics Related to Catalysis and Organometallics-- Index.
  • (source: Nielsen Book Data)9780471891710 20160528
This text/reference covers basic principles of coordination chemistry, organometallic compounds of transition metals and non-transition metals, reactions, industrial applications, use in synthesis, methods of manipulation for air-sensitive compounds, and an overview of related topics.
(source: Nielsen Book Data)9780471891710 20160528
Science Library (Li and Ma)
CHEM-155-01, CHEM-255-01
Book
xv, 278 p. : ill. ; 23 cm.
Science Library (Li and Ma)
CHEM-155-01, CHEM-255-01
Book
277 p. : ill. ; 22 cm.
This book should be of interest to undergraduates and graduates taking courses in organometallic and transition-metal chemistry.
(source: Nielsen Book Data)9780412221200 20160527
Science Library (Li and Ma)
CHEM-155-01, CHEM-255-01
Book
xvii, 670 p. : ill. ; 24 cm.
Science Library (Li and Ma)
CHEM-155-01, CHEM-255-01