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1. User friendly haptic tool for soccer fans with vision disabilities: Design and proof of concept [2022]
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Emmanuel Maravelakis, Antonios Konstantaras, Panagiotis Kyratsis, Nikolaos Bolanakis, Nectarios Vidakis, Markos Petousis, and Katerina Kabassi
- Journal of Graphic Engineering and Design, Vol 13, Iss 3, Pp 19-32 (2022)
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haptic tool, visually impaired people, cad modeling, conceptual design, criteria based model design, 3d printing, soccer, ahp. fuzzy saw, Mechanical drawing. Engineering graphics, and T351-385
- Abstract
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Loss of eyesight inflicts multiple difficulties in everyday lives’ tasks affecting not just the visually impaired but also their loved ones. The sense of being depleted by the otherwise visually perceived satisfaction from attending various events becomes a burden not just in terms of joy but also in relation to accompanying parties. The aim of this research work was to provide a worthy perceived experience of attending a soccer match with the company of a friend, centered at the visually impaired person’s needs and perspective. The methodology developed was based on a holistic approach combining a number of creative tools, in order to explore, visualize and evaluate the proposed solutions, with advanced CAD modeling, rendering techniques and 3D printing technology for improved representation and prototyping of the final product. Evaluation via multi-criteria decision-making casted the developed system as quite usable, suitable for assisting the visually impaired users in absorbing valuable information regarding the real time progress of a live soccer event using the selves-developed tactile interface. That way, visually impaired people are able to use the final product with a great deal of success and “feel the view” and the “time” in a variety of cases, allowing them to better enjoy attending an entertainment event, such as soccer, with the interactive company of a friend.
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Nectarios Vidakis, Constantine David, Markos Petousis, Dimitrios Sagris, Nikolaos Mountakis, and Amalia Moutsopoulou
- Advances in Industrial and Manufacturing Engineering, Vol 5, Iss , Pp 100104- (2022)
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Polylactic acid (PLA), 3D printing, Computed tomography (CT), Surface roughness, Porosity, Industrial engineering. Management engineering, and T55.4-60.8
- Abstract
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In the material extrusion (MEX) Additive Manufacturing (AM) technology, the layer-by-layer nature of the fabricated parts, induces specific features which affect their quality and may restrict their operating performance. Critical quality indicators with distinct technological and industrial impact are surface roughness, dimensional accuracy, and porosity, among others. Their achieving scores can be optimized by adjusting the 3D printing process parameters. The effect of six (6) 3D printing control parameters, i.e., raster deposition angle, infill density, nozzle temperature, bed temperature, printing speed, and layer thickness, on the aforementioned quality indicators is investigated herein. Optical Microscopy, Optical Profilometry, and Micro Χ-Ray Computed Tomography were employed to investigate and document these quality characteristics. Experimental data were processed with Robust Design Theory. An L25 Taguchi orthogonal array (twenty-five runs) was compiled, for the six control parameters with five levels for each one of them. The predictive quadratic regression models were then validated with two additional confirmation runs, with five replicas each. For the first time, the surface quality features, as well as the geometrical and structural characteristics were investigated in such depth (>500 GB of raw experimental data were produced and processed). A deep insight into the quality of the MEX 3D printed parts is provided allowing the control parameters’ ranking and optimization. Prediction equations for the quality features as functions of the control parameters are introduced herein, with merit in the market-driven practice.
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Markos Petousis, Nectarios Vidakis, Nikolaos Mountakis, Vassilis Papadakis, and Lazaros Tzounis
- Nanomaterials, Vol 12, Iss 4292, p 4292 (2022)
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fused filament fabrication (FFF), 3D printing (3DP), polymer nanocomposites, nanoparticles (NPs), melt-processing, Polyamide 12 (PA12), Chemistry, and QD1-999
- Abstract
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The effect of aluminum oxide (Al2O3) nanoparticles (NPs) as a reinforcing agent of Polyamide 12 (PA12) and Polylactic acid (PLA) in fused filament fabrication (FFF) three-dimensional printing (3DP) is reported herein for the first time. Alumina NPs are incorporated via a melt–mixing compounding process, at four different filler loadings. Neat as well as nanocomposite 3DP filaments are prepared as feedstock for the 3DP manufacturing of specimens which are thoroughly investigated for their mechanical properties. Thermogravimetric analyses (TGA) and Raman spectroscopy (RS) proved the nature of the materials. Their morphological characteristics were thoroughly investigated with scanning electron and atomic force microscopy. Al2O3 NPs exhibited a positive reinforcement mechanism at all filler loadings, while the mechanical percolation threshold with the maximum increase of performance was found between 1.0–2.0 wt.% filler loading (1.0 wt.% for PA12, 41.1%, and 56.4% increase in strength and modulus, respectively; 2.0 wt.% for PLA, 40.2%, and 27.1% increase in strength and modulus, respectively). The combination of 3DP and polymer engineering using nanocomposite PA12 and PLA filaments with low-cost filler additives, e.g., Al2O3 NPs, could open new avenues towards a series of potential applications using thermoplastic engineering polymers in FFF 3DP manufacturing.
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Achilles Vairis, Markos Petousis, Nikolaos Mountakis, Charikleia Tsarouchidou, and Nectarios Vidakis
- Materials, Vol 15, Iss 8187, p 8187 (2022)
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friction stir welding (FSW), tensile strength, aluminum Al 7075, welding speed, thin sheet, rotational speed, Technology, Electrical engineering. Electronics. Nuclear engineering, TK1-9971, Engineering (General). Civil engineering (General), TA1-2040, Microscopy, QH201-278.5, Descriptive and experimental mechanics, and QC120-168.85
- Abstract
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Welding tools of different designs have been used to join friction stir welding 2-mm-thick Al 7075 sheets, to investigate the effect of the tool geometry on the weld performance. Five cylindrical tools with different pin geometries were manufactured from heat-treatable low alloy steel WNr 1.6582/DIN 34CrNiMo6. Additionally, the effect of the welding speed was considered in the work, with six different speeds ranging from 80 mm/min to 300 mm/min. The weld tool rotational speed was kept constant at 1000 rpm and all other parameters were also kept constant in the experiments. The tensile strength was measured to investigate the mechanical properties of the weld. Results were processed with statistical analysis tools, which showed that the mechanical strength was affected by tool geometry as well as welding speed. The weld tool with the highest pin diameter achieved the highest tensile strength. The welding speed affected the tensile strength differently in the different weld tool geometries studied. The highest weld efficiency reported in the tests is 72.20%, achieved with a cylindrical pin weld tool at 250 mm/min.
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Nectarios Vidakis, Markos Petousis, Athena Maniadi, Vassilis Papadakis, and Amalia Moutsopoulou
- Journal of Composites Science, Vol 6, Iss 315, p 315 (2022)
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high-density polyethylene (HDPE), 3D printing, tensile strength, zinc oxide (ZnO), material extrusion, fused filament fabrication (FFF), Technology, and Science
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The scope of this work was to develop novel polymer composites via melt extrusion and 3D printing, incorporating High-Density Polyethylene filled with zinc oxide particles in various wt. percentages. For each case scenario, a filament of approximately 1.75 mm in diameter was fabricated. Samples for tensile and flexural testing were fabricated with 3D printing. They were then evaluated for their mechanical response according to ASTM standards. According to the documented testing data, the filler increases the mechanical strength of pure HDPE at specific filler concentrations. The highest values reported were a 54.6% increase in the flexural strength with HDPE/ZnO 0.5 wt.% and a 53.8% increase in the tensile strength with 10 wt.% ZnO loading in the composite. Scanning Electron Microscopy (SEM), Raman, and thermal characterization techniques were used. The experimental findings were evaluated in other research areas where they were applicable.
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Nectarios Vidakis, Markos Petousis, 아킬레스 바이리스, Konstantinos Savvakis, and Athena Maniadi
- Journal of Computational Design and Engineering , 4(4), pp.339-346 Oct, 2017
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Nectarios Vidakis, Markos Petousis, Emanuel Velidakis, Nikolaos Mountakis, Peder Erik Fischer-Griffiths, Sotirios A. Grammatikos, and Lazaros Tzounis
- Polymer Testing, Vol 109, Iss , Pp 107545- (2022)
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Fused filament fabrication (FFF), Three-dimensional (3D) printing, Polypropylene (PP), Aluminum oxide (Al2O3), Nanocomposites, Polymers and polymer manufacture, and TP1080-1185
- Abstract
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Three-dimensional (3D) printed Polypropylene (PP) reinforced with aluminum oxide (Al2O3) nanoparticles (NPs) were developed and fully characterized in this study. Nanocomposite filaments were produced initially following a melt mixing extrusion process, utillised as feedstock for the Fused Filament Fabrication (FFF) specimen manufacturing. Al2O3 NPs at 0.5, 1.0, 2.0 and 4.0 wt% loadings were melt-mixed with the PP thermoplastic matrix. Specific geometry samples were 3D printed and analysed via tensile, flexural, viscoelastic, impact, microhardness and fractographic investigations. Raman spectroscopy verified the polymeric structure and the incorporated Al2O3 NPs within the polymer matrix. Atomic Force Microscopy (AFM) of the extruded filaments revealed the nanoscale roughness induced by the alumina nanoinclusions. All 3D printed nanocomposite structures exhibited enhanced tensile, flexural and thermomechanical properties. Specifically, the best combination was found for the 1.0 wt% loaded specimen showing a tensile and flexural strength increase by approx. 4% and 19%, respectively, with a concomitant slight increase in impact and microhardness properties compared to unfilled PP. Dynamic Mechanical Analysis (DMA) revealed a stiffening mechanism for the PP/Al2O3 nanocomposites being in good agreement with the quasi-static mechanical tests. It could be envisaged that the 3D printed PP/Al2O3 nanocomposites developed herein could find numerous applications as engineered thermoplastics, where enhanced material's static and dynamic mechanical properties are required.
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Nectarios Vidakis, Markos Petousis, Nikolaos Mountakis, Apostolos Korlos, Vassilis Papadakis, and Amalia Moutsopoulou
- Journal of Functional Biomaterials, Vol 13, Iss 115, p 115 (2022)
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polyamide 12 (PA12), titanium nitride (TiN), copper (Cu), cuprous oxide (Cu2O), nanocomposites, material extrusion (MEX), Biotechnology, TP248.13-248.65, Medicine (General), and R5-920
- Abstract
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In this work, for the first time, polyamide 12 (PA12) nanocomposites with binary inclusions in material extrusion (MEX) 3D printing were developed. The aim was to achieve an enhanced mechanical response with the addition of titanium nitride (TiN) and antibacterial performance with the addition of copper (Cu) or cuprous oxide (Cu2O), towards the development of multi-functional nanocomposite materials, exploiting the 3D printing process benefits. The prepared nanocomposites were fully characterized for their mechanical properties. The thermal properties were also investigated. Morphological characterization was performed with atomic force microscopy (AFM) and scanning electron microscopy (SEM). The antibacterial performance was investigated with an agar-well diffusion screening process. Overall, the introduction of these nanofillers induced antibacterial performance in the PA12 matrix materials, while at the same time, the mechanical performance was significantly increased. The results of the study show high potential for expanding the areas in which 3D printing can be used.
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Markos Petousis, Nectarios Vidakis, Nikolaos Mountakis, Sotirios Grammatikos, Vassilis Papadakis, Constantine N. David, Amalia Moutsopoulou, and Subrata C. Das
- Polymers, Vol 14, Iss 3492, p 3492 (2022)
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three-dimensional printing, fused filament fabrication, nanocomposites, polycarbonate, silicon carbide, mechanical characterization, Organic chemistry, and QD241-441
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In this work, the effect of silicon carbide (carborundum, SiC), as a boosting agent of the mechanical response of the polycarbonate (PC) polymer, was investigated. The work aimed to fabricate nanocomposites with an improved mechanical performance and to further expand the utilization of 3D printing in fields requiring an enhanced material response. The nanocomposites were produced by a thermomechanical process in various SiC concentrations in order to evaluate the filler loading in the mechanical enhancement. The samples were 3D printed with the material extrusion (MEX) method. Their mechanical performance was characterized, following international standards, by using dynamic mechanical analysis (DMA) and tensile, flexural, and Charpy’s impact tests. The microhardness of the samples was also measured. The morphological characteristics were examined, and Raman spectra revealed their structure. It was found that SiC can improve the mechanical performance of the PC thermoplastic. A 19.5% increase in the tensile strength was found for the 2 wt.% loading nanocomposite, while the 3 wt.% nanocomposite showed a 16% increase in the flexural strength and a 35.9% higher impact strength when compared to the unfilled PC. No processability issues were faced for the filler loadings that have been studied here.
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Nectarios Vidakis, Markos Petousis, Athena Maniadi, Vassilis Papadakis, and Alexandra Manousaki
- Journal of Composites Science, Vol 6, Iss 209, p 209 (2022)
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Fused Filament Fabrication (FFF), 3D printing, nanocomposites, flexural strength, tensile strength, High-Density Polyethylene (HDPE), Technology, and Science
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Aiming to develop more robust, mechanically advanced, Fused Filament Fabrication (FFF) materials, High-Density Polyethylene (HDPE) nanocomposites were developed in the current research work. Titanium Dioxide (TiO2) was selected as filler to be incorporated into the HDPE matrix in concentration steps of 0.5, 2.5, 5, and 10 wt.%. 3D printing nanocomposite filaments were extruded in ~1.75 mm diameter and used to 3D print and test tensile and flexion specimens according to international standards. Reported results indicate that the filler contributes to increasing the mechanical strength of the virgin HDPE at certain filler and filler type concentrations; with the highest values reported to be 37.8% higher in tensile strength with HDPE/TiO2 10 wt.%. Morphological and thermal characterization was performed utilizing Scanning Electron Microscopy (SEM), Raman, Thermogravimetric Analysis (TGA), and Differential Scanning Calorimetry (DSC), while the results were correlated with the available literature.
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Nectarios Vidakis, Markos Petousis, Nikolaos Mountakis, and John D. Kechagias
- Journal of Manufacturing and Materials Processing, Vol 6, Iss 77, p 77 (2022)
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friction stir welding (FSW), poly(methyl methacrylate) (PMMA), fused filament fabrication (FFF), material extrusion (MEX), hybrid additive manufacturing, optimization, Production capacity. Manufacturing capacity, and T58.7-58.8
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In this work, the expansion of friction stir welding (FSW) in parts made via material extrusion (MEX) 3D printing was investigated. Poly(methyl methacrylate) (PMMA) plates were joined in a full factorial experimental design. The effects of three FSW parameters (weld tool pin geometry, rotating speed, and travel speed) on the weld results were studied. The tensile strength was investigated using statistical modeling tools. A morphological characterization study was also conducted on the weld zone, with microscopy. The state of the material during the FSW process was monitored via real-time temperature measurements. The feasibility of the process was verified. The results show high industrial merit for the process. The highest tensile strength was reported for the sample welded with the frustum tool, at 1400 rpm and a 9 mm/min travel speed (the highest studied), with a welding efficiency > 1. This can be attributed to the reduced porosity of the weld area compared to the 3D printed structure, and indicates a high potential for joining 3D-printed PMMA sheets via the FSW process.
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Nectarios Vidakis, Markos Petousis, Apostolos Korlos, Nikolaos Mountakis, and John D. Kechagias
- Polymers, Vol 14, Iss 2474, p 2474 (2022)
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friction stir welding (FSW), acrylonitrile butadiene styrene (ABS), material extrusion (MEX), hybrid additive manufacturing, 3D printing, Organic chemistry, and QD241-441
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The feasibility of joining material extrusion (MEX) 3D-printed acrylonitrile butadiene styrene (ABS) plates with the friction stir welding (FSW) process was investigated herein as a promising topic of hybrid additive manufacturing (HAM). The influence of three process parameters on the mechanical strength of the joints was thoroughly examined and analyzed with a full factorial experimental design and statistical modeling. Hereto, the welding tool pin geometry, travel speed, and rotational speed were investigated. The joint’s efficiency and quality are evaluated through tensile tests and morphological characterization. More specifically, specimens’ areas of particular interest were investigated with stereoscopic, optical, and scanning electron microscopy. Throughout the FSW experimental course, the welding temperature was monitored to evaluate the state of the ABS material during the process. The majority of the welded specimens exhibited increased mechanical strength compared with the respective ones of non-welded 3D printed specimens of the same geometry. Statistical modeling proved that all processing parameters were significant. The feasibility of the FSW process in 3D printed ABS workpieces was confirmed, making the FSW a cost-effective process for joining 3D printing parts, further expanding the industrial merit of the approach.
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Markos Petousis, Nectarios Vidakis, Nikolaos Mountakis, Vassilis Papadakis, Sotiria Kanellopoulou, Aikaterini Gaganatsiou, Nikolaos Stefanoudakis, and John Kechagias
- Fibers, Vol 10, Iss 52, p 52 (2022)
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three-dimensional (3D) printing, additive manufacturing, nanocomposites, polylactic acid (PLA), cuprous oxide (Cu2O), cellulose nanofibers (CNF), Chemicals: Manufacture, use, etc., TP200-248, Textile bleaching, dyeing, printing, etc., TP890-933, Biology (General), QH301-705.5, Physics, and QC1-999
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In this work, we present an effective process easily adapted in industrial environments for the development of multifunctional nanocomposites for material extrusion (MEX) 3D printing (3DP). The literature is still very limited in this field, although the interest in such materials is constantly increasing. Nanocomposites with binary inclusions were prepared and investigated in this study. Polylactic acid (PLA) was used as the matrix material, and cuprous oxide (Cu2O) and cellulose nanofibers (CNF) were used as nanoadditives introduced in the matrix material to enhance the mechanical properties and induce antibacterial performance. Specimens were built according to international standards with a thermomechanical process. Tensile, flexural, impact, and microhardness tests were conducted. The effect on the thermal properties of the matrix material was investigated through thermogravimetric analysis, and Raman spectroscopic analysis was conducted. The morphological characteristics were evaluated with atomic force microscopy (AFM), scanning electron microscopy (SEM), and energy-dispersive X-ray (EDS) analyses. The antibacterial performance of the prepared nanomaterials was studied against Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli) bacteria, with a screening agar well diffusion method. All nanocomposites prepared exhibited biocidal properties against the bacteria tested. The tested PLA/1.0 CNF/0.5 Cu2O material had 51.1% higher tensile strength and 35.9% higher flexural strength than the pure PLA material.
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Nectarios Vidakis, Markos Petousis, Mirto Kourinou, Emmanuel Velidakis, Nikolaos Mountakis, Peder Erik Fischer-Griffiths, Sotirios Grammatikos, and Lazaros Tzounis
- Nanocomposites, Vol 7, Iss 1, Pp 184-199 (2021)
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3d printing, conductive polymer composites, nanocomposites, multiwalled carbon nanotubes, polylactic acid, 3d printed electronics, additive manufacturing, fused filament fabrication (fff), Materials of engineering and construction. Mechanics of materials, TA401-492, Polymers and polymer manufacture, and TP1080-1185
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In this work, an industrially scalable method was developed for the preparation of multifunctional nanocomposite filaments. Polylactic Acid (PLA) polymer matrix was enriched with Multi Wall Carbon Nanotubes (MWCNT) at various concentrations, to fabricate 3D-printed parts by the Fused Filament Fabrication (FFF) technology. The effect of the nanofiller loading at the mechanical, thermal, electrical, thermomechanical, and antibacterial performance of the novel nanocomposites fabricated in this work was investigated. The filler loading of 5 wt.% was also tested to reveal its electrothermal Joule heating performance. The antibacterial properties of the nanocomposites were examined through a screening process, against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). For loadings of 1 wt.% and higher the mechanical properties were significantly improved. The 5 wt.% loaning showed measurable antibacterial performance. The nanocomposites prepared herein can be characterized as multifunctional materials, suitable for various industrial applications, such as sensors fabrication, health monitoring devices, etc.
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Nectarios Vidakis, Markos Petousis, Nikolaos Michailidis, Vassilis Papadakis, Apostolos Korlos, Nikolaos Mountakis, and Apostolos Argyros
- Polymers, Vol 14, Iss 1903, p 1903 (2022)
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nanocomposite, cellulose nanofiber (CNF), copper (Cu), copper oxide (Cu2O), antibacterial, vat photopolymerization, Organic chemistry, and QD241-441
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This study introduced binary nanoparticle (NP) inclusions into a biomedical-grade photosensitive resin (Biomed Clear-BC). Multi-functional, three-dimensional (3D) printed objects were manufactured via the vat photopolymerization additive manufacturing (AM) technique. Cellulose nanofibers (CNFs) as one dimensional (1D) nanomaterial have been utilized for the mechanical reinforcement of the resin, while three different spherical NPs, namely copper NPs (nCu), copper oxide NPs (nCuO), and a commercial antimicrobial powder (nAP), endowed the antimicrobial character. The nanoparticle loading was kept constant at 1.0 wt.% to elucidate any synergistic effects as a function of the filler loading. Raman, thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC) revealed the chemical/spectroscopic and thermal properties of the different manufactured samples. Scanning electron microscopy and Atomic Force Microscopy (AFM) revealed the morphology of the samples. Mechanical properties revealed the reinforcement mechanisms, namely that BC/CNF (1.0 wt.%) exhibited a 102% and 154% enhancement in strength and modulus, respectively, while BC/CNF(1.0 wt.%)/AP(1.0 wt.%) exhibited a 95% and 101% enhancement, as well as an antibacterial property, which was studied using a screening agar well diffusion method. This study opens the route towards novel, multi-functional materials for vat photopolymerization 3D printing biomedical applications, where mechanical reinforcement and antibacterial performance are typically required in the operational environment.
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Nectarios Vidakis, Markos Petousis, Sotirios Grammatikos, Vassilis Papadakis, Apostolos Korlos, and Nikolaos Mountakis
- Nanomaterials, Vol 12, Iss 1068, p 1068 (2022)
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three-dimensional (3D) printing, additive manufacturing, nanocomposites, polycarbonate (PC), titanium carbide (TiC), fused filament fabrication (FFF), Chemistry, and QD1-999
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Herein, a polycarbonate (PC) polymer is melt extruded together with titanium carbide (TiC) nano powder for the development of advanced nanocomposite materials in material extrusion (MEX) 3D printing. Raw material for the 3D printing process was prepared in filament form with a thermomechanical extrusion process and specimens were built to be tested according to international standards. A thorough mechanical characterization testing course (tensile, flexural, impact, microhardness, and dynamic mechanical analysis-DMA) was conducted on the 3D printed specimens. The effect of the ceramic filler loading was also investigated. The nanocomposites’ thermal and stoichiometric properties were investigated with thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), energy-dispersive X-ray spectroscopy (EDS), and Raman respectively. The specimens’ 3D printing morphology, quality, and fracture mechanism were investigated with atomic force microscopy (AFM) and scanning electron microscopy (SEM) respectively. The results depicted that the addition of the filler decidedly enhances the mechanical response of the virgin polymer, without compromising properties such as its processability or its thermal stability. The highest improvement of 41.9% was reported for the 2 wt.% filler loading, making the nanocomposite suitable for applications requiring a high mechanical response in 3D printing, in which the matrix material cannot meet the design requirements.
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Nectarios Vidakis, Markos Petousis, Nikolaos Michailidis, Sotirios Grammatikos, Constantine N. David, Nikolaos Mountakis, Apostolos Argyros, and Orsa Boura
- Nanomaterials, Vol 12, Iss 534, p 534 (2022)
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three-dimensional (3D) printing, nanocomposites, polyamide 12 (PA12), cuprous oxide (Cu2O), fused filament fabrication (FFF), biocidal efficiency, Chemistry, and QD1-999
- Abstract
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In the current study, nanocomposites of medical-grade polyamide 12 (PA12) with incorporated copper (I) oxide (cuprous oxide-Cu2O) were prepared and fully characterized for their mechanical, thermal, and antibacterial properties. The investigation was performed on specimens manufactured by fused filament fabrication (FFF) and aimed to produce multi-purpose geometrically complex nanocomposite materials that could be employed in medical, food, and other sectors. Tensile, flexural, impact and Vickers microhardness measurements were conducted on the 3D-printed specimens. The fractographic inspection was conducted utilizing scanning electron microscopy (SEM), to determine the fracture mechanism and qualitatively evaluate the process. Moreover, the thermal properties were determined by thermogravimetric analysis (D/TGA). Finally, their antibacterial performance was assessed through a screening method of well agar diffusion. The results demonstrate that the overall optimum performance was achieved for the nanocomposites with 2.0 wt.% loading, while 0.5 wt.% to 4.0 wt.% loading was concluded to have discrete improvements of either the mechanical, the thermal, or the antibacterial performance.
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Nectarios Vidakis, Markos Petousis, Emmanuel Velidakis, Apostolos Korlos, John D. Kechagias, Dimitris Tsikritzis, and Nikolaos Mountakis
- Polymers, Vol 14, Iss 440, p 440 (2022)
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fused filament fabrication (FFF), 3D printing, antibacterial, additive manufacturing (AM), silver, polyamide 12 (PA12), Organic chemistry, and QD241-441
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During the COVID-19 pandemic, wide use of 3D printing technologies has been enabled. Fused filament fabrication (FFF) is the most widely used technique in 3D printing communities worldwide for the fabrication of medical components such as face shields and respiratory valves. In the current study, the potential of Polyamide 12 (PA12) silver-doped antibacterial nanopowder (AgDANP) nanocomposites is evaluated for everyday FFF usage. Filling loadings of 1.0-2.0-3.0 and 4.0 wt.% were selected for nanocomposite preparation. Mechanical performance analysis was conducted on the basis of tensile, flexural, impact, and Vickers microhardness measurements in FFF 3D-printed specimens. Scanning Electron Microscopy (SEM) images were used for morphology and processing evaluation, as well as thermal performance measurements, conducted by Thermogravimetric Analysis (TGA) tests. Finally, the antibacterial performance was tested using the agar-well diffusion screening method, and the shape effect of the specimens was also investigated. The addition of 2.0 wt.% AgDANPs resulted in an enhancement of approximately 27% for both tensile and flexural stresses, while the antibacterial performance was sufficiently high among the nanocomposites tested. The shape effect exhibited the potential for antibacterial performance at low filling ratios, while the effect was diminished with increasing filler of AgDANPs.
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Nectarios Vidakis, Markos Petousis, Emmanuel Velidakis, Nikolaos Mountakis, Dimitris Tsikritzis, Aikaterini Gkagkanatsiou, and Sotiria Kanellopoulou
- Biomimetics, Vol 7, Iss 8, p 8 (2022)
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stereolithography (SLA), 3D printing, antibacterial, additive manufacturing (AM), copper (Cu), resin, and Technology
- Abstract
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Metals, such as silver, gold, and copper are known for their biocidal properties, mimicking the host defense peptides (HDPs) of the immune system. Developing materials with such properties has great importance in medicine, especially when combined with 3D printing technology, which is an additional asset for various applications. In this work, copper nanoparticles were used as filler in stereolithography (SLA) ultraviolet (UV) cured commercial resin to induce such biocidal properties in the material. The nanocomposites developed featured enhanced mechanical responses when compared with the neat material. The prepared nanocomposites were employed to manufacture specimens with the SLA process, to be tested for their mechanical response according to international standards. The process followed was evaluated with Scanning Electron Microscopy (SEM), Atomic Force Microscopy (AFM), energy-dispersive X-ray spectroscopy (EDS), and thermogravimetric analysis (TGA). The antibacterial activity of the fabricated nanocomposites was evaluated using the agar-well diffusion method. Results showed enhanced mechanical performance of approximately 33.7% in the tensile tests for the nanocomposites filled with 1.0 wt.%. ratios, when compared to the neat matrix material, while this loading showed sufficient antibacterial performance when compared to lower filler loadings, providing an added value for the fabrication of effective nanocomposites in medical applications with the SLA process.
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Markos Petousis, Nectarios Vidakis, Emmanuel Velidakis, John D. Kechagias, Constantine N. David, Stefanos Papadakis, and Nikolaos Mountakis
- Biomimetics, Vol 7, Iss 12, p 12 (2022)
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stereolithography (SLA), 3D printing, antibacterial, additive manufacturing (AM), Cuprous Oxide, resin, and Technology
- Abstract
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In this study, Cuprous Oxide (Cu2O), known for its mechanism against bacteria, was used as filler to induce biocidal properties on a common commercial resin stereolithography (SLA) 3D printing resin. The aim was to develop nanocomposites suitable for the SLA process with a low-cost process that mimic host defense peptides (HDPs). Such materials have a huge economic and societal influence on the global technological war on illness and exploiting 3D printing characteristics is an additional asset for these materials. Their mechanical performance was also investigated with tensile, flexural, Charpy’s impact, and Vickers microhardness tests. Morphological analysis was performed through scanning electron microscopy (SEM), atomic force microscopy (AFM), and energy-dispersive X-ray spectroscopy (EDS) analysis, while the thermal behavior was studied through Thermogravimetric Analysis (TGA). The antibacterial activity of the fabricated nanocomposites was investigated using a screening agar well diffusion method, for a gram-negative and a gram-positive bacterium. Three-dimensional printed nanocomposites exhibited antibacterial performance in all loadings studied, while their mechanical enhancement was approximately 20% even at low filler loadings, revealing a multi-functional performance and a potential of Cuprous Oxide implementation in SLA resin matrices for engineering and medical applications.
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