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LEE, Seung-Hwan, LEE, Sung-Gap, YOON, Jung-Rag, and KIM, Hong-Ki
- Journal of power sources (Print). 273:839-843
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Electrical engineering, Electrotechnique, Energy, Énergie, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Electrotechnique. Electroenergetique, Electrical engineering. Electrical power engineering, Matériel électrique divers, Various equipment and components, Condensateurs. Résistances. Filtres, Capacitors. Resistors. Filters, Aluminium Phosphate, Aluminium Phosphates, Aluminio Fosfato, Composé ternaire, Ternary compound, Compuesto ternario, Condensateur électrochimique, Electrolytic capacitor, Condensador electroquímico, Couche ultramince, Ultrathin films, Evaluation performance, Performance evaluation, Evaluación prestación, Forme cylindrique, Cylindrical shape, Forma cilíndrica, Gonflement, Swelling, Inflamiento, Lithium Oxyde, Lithium Oxides, Litio Óxido, Lithium Titanate, Lithium Titanates, Litio Titanato, Matériau modifié, Modified material, Material modificado, Matériau revêtu, Coated material, Material revestido, Performance, Rendimiento, Revêtement, Coatings, Revestimiento, Supercondensateur, Supercapacitor, Supercondensador, Titane Oxyde, Titanium Oxides, Titanio Óxido, Traitement surface, Surface treatment, Tratamiento superficie, Li4Ti5O12, H2Ti12O25, Hybrid supercapacitor, Surface modified, and Swollen phenomenon
- Abstract
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Hydrogen titanium oxide, H2Ti12O25 is prepared by soft chemical method. A fabricated asymmetric hybrid supercapacitor using an AlPO4 modified H2Ti12O25 anode shows electrochemical performance superior to a Li4Ti5O12 anode, including cycling performance. The anode comprised of H2Ti12O25 coated with 3 wt.% AlPO4 shows the energy and power density of 41.1 Wh kg-1, 194.1 W kg-1, respectively, at a current rate of 0.1 A g-1 as well as the highest cycling performance, with 94.1% specific capacitance retained after 1000 cycles at a current rate of 3.0 A g-1. These excellent results are convincing evidence that H2Ti12O25 should be regarded as one of the more promising anode materials.
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XUELIN ZHANG, YANG LI, HAILONG CHEN, ZHIGANG WANG, ZHAOYANG ZENG, MENGYUAN CAI, YUFENG ZHANG, and XIAOWEI LIU
- Journal of power sources (Print). 273:375-379
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Electrical engineering, Electrotechnique, Energy, Énergie, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Electrotechnique. Electroenergetique, Electrical engineering. Electrical power engineering, Electroénergétique, Electrical power engineering, Conversion directe et accumulation d'énergie, Direct energy conversion and energy accumulation, Conversion électrochimique: piles et accumulateurs électrochimiques, piles à combustibles, Electrochemical conversion: primary and secondary batteries, fuel cells, Energie, Energy, Energie. Utilisation thermique des combustibles, Energy. Thermal use of fuels, Appareils de production et de conversion d'énergie: énergie thermique, énergie électrique, énergie mécanique, etc, Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc, Piles à combustible, Fuel cells, Alcool primaire, Primary alcohol, Alcohol primario, Collection courant, Current collection, Colección corriente, Gestion eau, Water management, Gestión del agua, Métal, Metal, Méthanol, Methanol, Metanol, Noyage, Flooding, Inundación, Oxydation, Oxidation, Oxidación, Pile combustible alcool, Alcohol fuel cells, Traitement par plasma, Plasma assisted processing, Traitement surface, Surface treatment, Tratamiento superficie, Collecteur de courant, Current collector, Direct methanol fuel cell, Plasma electrolytic oxidation, and Water flooding
- Abstract
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A novel water management system for micro passive DMFC is fabricated and characterized in this paper. This system consists of both a cathode current collector made of a 316L sintered stainless fiber felt (SSFF) and an aluminum-based end plate fabricated with a perforated flow field. Besides, some water-collecting channels were fabricated on the surface of the cathode end plate and then covered by the plasma electrolytic oxidation (PEO) coating. The results show that the PEO coating plays crucial roles in the water management system. Because of the highly hydrophilic property of the coating, the channels work well in collecting the liquid water from the current collector, and water accumulation along the air-breathing holes can be well prevented, which improves the stability of the micro DMFC.
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WEN MA, PENG LI, HONGYING DONG, YU BAI, JINLAN ZHAO, and XIAOZE FAN
- Selected and Expanded Papers from the 2013 International Thermal Spray ConferenceJournal of thermal spray technology. 23(1-2):154-159
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Metallurgy, welding, Métallurgie, soudage, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Metaux. Metallurgie, Metals. Metallurgy, Transformation de matériaux métalliques, Production techniques, Traitements de surface, Surface treatment, Dépôt de matériaux non métalliques, Nonmetallic coatings, Barrière thermique, Thermal barrier, Barrera térmica, Conductivité thermique, Thermal conductivity, Conductividad térmica, Waermeleitfaehigkeit, Dilatation thermique, Thermal expansion, Dilatación térmica, Thermische Ausdehnung, Dopage, Doping, Dopen, Expansion, Expansión, Oxyde d'yttrium, Yttrium oxide, Ytrio óxido, Yttriumoxid, Perovskite, Perovskita, Revêtement non métallique, Non metal coating, Revestimiento no metálico, Nichtmetallischer Ueberzug, Traitement surface, Surface treatment, Tratamiento superficie, Oberflaechenbehandlung, TBC, perovskites, thermal conductivity, and thermal expansion
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Y2O3 and Yb2O3 co-doped strontium hafnate powder with chemistry of Sr(Hf0.9Y0.05Yb0.05)O2.95 (SHYY) was synthesized by a solid-state reaction at 1450 °C. The SHYY showed good phase stability not only from 200 to 1400 °C but also at a high temperature of 1450 °C for a long period, analyzed by differential scanning calorimetry and x-ray diffraction, respectively. The coefficient of thermal expansion of the sintered bulk SHYY was recorded by a high-temperature dilatometer and revealed a positive influence on phase transitions of SrHfO3 by co-doping with Y2O3 and Yb2O3. The thermal conductivity of the bulk SHYY was approximately 16% lower in contrast to that of SrHfO3 at 1000 °C. Good chemical compatibility was observed for SHYY with 8YSZ or Al2O3 powders after a 24 h heat treatment at 1250 °C. The phase stability and the microstructure evolution of the as-sprayed SHYY coating during annealing at 1400 °C were also investigated.
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4. Which powders for cold spray? [2014]
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JEANDIN, M, ROLLAND, G, DESCURNINGES, L. L, and BERGER, M. H
- Cold Spray TechnologySurface engineering. 30(5):291-298
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Metallurgy, welding, Métallurgie, soudage, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Metaux. Metallurgie, Metals. Metallurgy, Transformation de matériaux métalliques, Production techniques, Traitements de surface, Surface treatment, Argent, Silver, Plata, Silber, Choc laser, Laser impact, Choque laser, Dépôt projection, Spray coating, Depósito proyección, Spritzbeschichten, Matériau composite, Composite material, Material compuesto, Verbundwerkstoff, Traitement surface, Surface treatment, Tratamiento superficie, Oberflaechenbehandlung, Cold spray, Composite, Laser shock, Oxide, Powder, Splat, and Tantalum
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Since the major technological issues in cold spray are now controlled, the key parameter for successful coating relates to the powder. The influence of the main characteristics of the starting powder on the final coating properties remains rather unknown. This includes primarily metallurgical, morphological and physico-chemical characteristics of the particles. This article focuses on the so-called local approach to these characteristics to show that the current global approach is insufficient. The discussion is based on many examples of cold spray results, including recent work on Ag-based and Ta cold sprayed-coatings. This results in proposed specifications for powders which are claimed to be tailored for cold spray.
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LI, Y.-G, WEI, Y.-H, HOU, L.-F, GUO, C.-L, and HAN, P.-J
- MagnesiumSurface engineering. 30(12):933-938
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Metallurgy, welding, Métallurgie, soudage, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Metaux. Metallurgie, Metals. Metallurgy, Transformation de matériaux métalliques, Production techniques, Métallurgie des poudres. Matériaux composites, Powder metallurgy. Composite materials, Métaux et alliages frittés. Cermets, Sintered metals and alloys. Pseudo alloys. Cermets, Traitements de surface, Surface treatment, Corrosion, Action des agents de corrosion, Corrosion environments, Propriétés mécaniques. Rhéologie. Mécanique de la rupture. Tribologie, Mechanical properties and methods of testing. Rheology. Fracture mechanics. Tribology, Frottement. Usure, Contact of materials. Friction. Wear, Propriété mécanique, Mechanical properties, Propiedad mecánica, Composé intermétallique, Intermetallic compound, Compuesto intermetálico, Intermetallische Verbindung, Corrosion électrochimique, Electrochemical corrosion, Corrosión electroquímica, Elektrochemische Korrosion, Frittage, Sintering, Sinterización, Sintern, Microstructure, Microestructura, Mikrogefuege, Métallurgie poudre, Powder metallurgy, Metalurgia polvo, Pulvermetallurgie, Revêtement, Coatings, Revestimiento, Ueberzug, Traitement surface, Surface treatment, Tratamiento superficie, Oberflaechenbehandlung, Tribologie, Tribology, Tribología, Usure, Wear, Desgaste, Verschleiss, Corrosion, and Intermetallics
- Abstract
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An erbium modified Mg17Al12 based coating was fabricated by hot press sintering on as extruded AZ61 Mg alloy. The Er modified coating was composed of Mg17Al12 and Al3Er phases. As a result of the presence of the dispersed Al3Er phase, the coating had a greater microhardness than Mg17Al12. Thermal effects of sintering at 400°C for 1 h caused no obvious deterioration in the wear resistance of the AZ61 Mg matrix. Electrochemical and wear resistance tests showed that the Er modified Mg17Al12 based coating had a lower corrosion current density and a lower friction coefficient than Mg17Al12, the AZ61 Mg matrix and a thermal diffusion coating (TDC). The superior wear resistance of the sintered coating resulted from the hard Al3Er phase. The corrosion resistance of the sintered coating was better than that of the TDC as a result of suppression of hydrogen evolution by the rare earth metal Er.
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TILLMANN, W, LUO, W, and SELVADURAI, U
- Selected and Expanded Papers from the 2013 International Thermal Spray ConferenceJournal of thermal spray technology. 23(1-2):245-251
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Metallurgy, welding, Métallurgie, soudage, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Metaux. Metallurgie, Metals. Metallurgy, Transformation de matériaux métalliques, Production techniques, Traitements de surface, Surface treatment, Propriétés mécaniques. Rhéologie. Mécanique de la rupture. Tribologie, Mechanical properties and methods of testing. Rheology. Fracture mechanics. Tribology, Frottement. Usure, Contact of materials. Friction. Wear, Propriété mécanique, Mechanical properties, Propiedad mecánica, Contrainte résiduelle, Residual stress, Tensión residual, Eigenspannung, Dépôt projection, Spray coating, Depósito proyección, Spritzbeschichten, Projection à chaud, Hot spraying, Proyección en caliente, Spritzen, Revêtement, Coatings, Revestimiento, Ueberzug, Résistance usure, Wear resistance, Resistencia al desgaste, Verschleissfestigkeit, Traitement surface, Surface treatment, Tratamiento superficie, Oberflaechenbehandlung, Tribologie, Tribology, Tribología, Usure, Wear, Desgaste, Verschleiss, iron alloys, residual stress, robot, and wear resistance
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Even though the application of thermal spray coatings on complex geometries gained a greater interest in the last decade, the effect of different geometrical features on the wear behavior is still ill-defined. In this study, the wear resistance of FTC-FeCSiMn coated 3D surfaces was investigated. The wear test was carried out by means of two innovative testing procedures. The first test is a Pin-on-Tubes test where the rotating motion is realized by a lathe chuck. The specimens in the second test were fixed on the table and a robot arm operated the pin. This wear test was applied on specimens with concave or convex surfaces. The residual stresses, which were determined by means of an incremental hole-drilling method, show a dependency on the substrate geometry. The obtained stresses were put in relation to the different radii. After the wear test, a 3D-profilometer determined the wear volume and the sections of the coatings were characterized by a scanning electron microscope. The results indicate that the wear resistance is strongly influenced by the geometry of the substrate.
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7. Warm Spray Forming of Ti-6Al-4V [2014]
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MOLAK, R. M, ARAKI, H, WATANABE, M, KATANODA, H, OHNO, N, and KURODA, S
- Selected and Expanded Papers from the 2013 International Thermal Spray ConferenceJournal of thermal spray technology. 23(1-2):197-212
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Metallurgy, welding, Métallurgie, soudage, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Metaux. Metallurgie, Metals. Metallurgy, Transformation de matériaux métalliques, Production techniques, Traitements de surface, Surface treatment, Alliage base titane, Titanium base alloys, Aluminium alliage, Aluminium alloy, Aluminio aleación, Aluminiumlegierung, Dépôt projection, Spray coating, Depósito proyección, Spritzbeschichten, Formage projection, Spray forming, Formación proyección, Formage à tiède, Warm forming, Modelado en tibio, Halbwarmumformen, Microstructure, Microestructura, Mikrogefuege, Porosité, Porosity, Porosidad, Porositaet, Traitement surface, Surface treatment, Tratamiento superficie, Oberflaechenbehandlung, Vanadium alliage, Vanadium alloy, Vanadio aleación, Vanadiumlegierung, microstructure, oxygen content, porosity, and warm spraying
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Warm spray (WS) is a modification of high-velocity oxy-fuel spraying, in which the temperature of the supersonic gas flow generated by the combustion of kerosene and oxygen is controlled by diluting the combustion flame with an inert gas such as nitrogen. The inert gas is injected into the mixing chamber placed between the combustion chamber and the powder feed ports, thus the temperature of the propellant gas can be controlled from ∼700 to 2,000 K. Since WS allows for higher particle temperatures in comparison to cold spray, warm sprayed particles are more softened upon impact, thus resulting in greater deformation facilitating the formation of shear instability for bonding. Recently, the combustion pressure of WS has been increased from 1 (low-pressure warm spray) to 4 MPa (high-pressure warm spray) in order to increase the velocity of sprayed particles. Effects of spray parameters on microstructure, mechanical properties, and splats formation of Ti-6Al-4V were systematically studied. Obtained coatings were examined by analyzing the coating cross-section images, microhardness as well as oxygen content. In addition, flattening ratio of splats was calculated as a function of nitrogen flow rate. It was found that the increased particle velocity caused by the increased combustion pressure had significant beneficial effects in terms of improving density and controlling the oxygen level in the sprayed Ti-6Al-4V coatings.
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BAN, C. L, SHAO, X, and WANG, L. P
- MagnesiumSurface engineering. 30(12):880-885
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Metallurgy, welding, Métallurgie, soudage, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Metaux. Metallurgie, Metals. Metallurgy, Transformation de matériaux métalliques, Production techniques, Traitements de surface, Surface treatment, Dépôt de métaux et d'alliages, Metallic coatings, Corrosion, Action des agents de corrosion, Corrosion environments, Alliage base nickel, Nickel base alloys, Corrosion, Corrosión, Korrosion, Dépôt chimique, Chemical deposition, Depósito químico, Stromloses Beschichten, Irradiation, Irradiación, Bestrahlung, Revêtement métallique, Metal coating, Revestimiento metálico, Metallischer Ueberzug, Résistance corrosion, Corrosion resistance, Resistencia corrosión, Korrosionsbestaendigkeit, Traitement surface, Surface treatment, Tratamiento superficie, Oberflaechenbehandlung, Coatings, Electroless plating, Magnesium alloy, and Ultrasonic irradiation
- Abstract
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Ultrasonic irradiation (UI) is applied to assist the electroless plating (EP) Ni―P coating on a magnesium alloy substrate. The results show that under UI, the Ni―P coating becomes smooth, compact, has refined grains and is free of cracks and pores, leading to significant improvement in the coating corrosion resistance. The crystallinity of the coating is also improved by UI, transforming from amorphous state to mixture of amorphous and nanocrystalline one.
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IRISSOU, E, DADOUCHE, A, and LIMA, R. S
- Selected and Expanded Papers from the 2013 International Thermal Spray ConferenceJournal of thermal spray technology. 23(1-2):252-261
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Metallurgy, welding, Métallurgie, soudage, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Metaux. Metallurgie, Metals. Metallurgy, Transformation de matériaux métalliques, Production techniques, Traitements de surface, Surface treatment, Dépôt de métaux et d'alliages, Metallic coatings, Propriétés mécaniques. Rhéologie. Mécanique de la rupture. Tribologie, Mechanical properties and methods of testing. Rheology. Fracture mechanics. Tribology, Frottement. Usure, Contact of materials. Friction. Wear, Propriété mécanique, Mechanical properties, Propiedad mecánica, Adhérence, Adhesion, Adherencia, Adhaesion, Application, Aplicación, Anwendung, Dépôt projection, Spray coating, Depósito proyección, Spritzbeschichten, Erosion, Erosión, Force adhérence, Adhesive strength, Fuerza adherencia, Haftfestigkeit, Plasma, Projection plasma, Plasma spraying, Proyección plasma, Plasmaspritzen, Projection à chaud, Hot spraying, Proyección en caliente, Spritzen, Revêtement métallique, Metal coating, Revestimiento metálico, Metallischer Ueberzug, Résistance mécanique, Strength, Resistencia mecánica, Festigkeit, Résistance usure, Wear resistance, Resistencia al desgaste, Verschleissfestigkeit, Traitement surface, Surface treatment, Tratamiento superficie, Oberflaechenbehandlung, Tribologie, Tribology, Tribología, Turbine gaz, Gas turbine, Turbina gas, Gasturbine, Usure, Wear, Desgaste, Verschleiss, MCrAlY, abradable coating, adhesive strength, atmospheric plasma spray (APS), erosion resistance, gas turbines, and rubbing wear
- Abstract
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The processing conditions, microstructural and tribological characterizations of plasma-sprayed CoNiCrAlY-BN high temperature abradable coatings are reported in this manuscript. Plasma spray torch parameters were varied to produce a set of abradable coatings exhibiting a broad range of porosity levels (34-62%) and superficial Rockwell hardness values (0-78 HR15Y). Abradability tests have been performed using an abradable-seal test rig, capable of simulating operational wear at different rotor speeds and seal incursion rates (SIRs). These tests allowed determining the rubbing forces and quantifying the blade and seal wear characteristics for slow and fast SIRs. Erosion wear performance and ASTM C633 coating adhesion strength test results are also reported. For optimal abradability performance, it is shown that coating hardness needs to be lower than 70 and 50 HR15Y for slow and fast blade incursion rate conditions, respectively. It is shown that the erosion wear performance, as well as, the coating cohesive strength is a function of the coating hardness. The current results allow defining the coating specifications in terms of hardness and porosity for targeted applications.
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RUI WENG, HAIFENG ZHANG, and XIAOWEI LIU
- Micro/Nano Devices and Systems 2013: An open thematic journal issueMicroelectronic engineering. 119:183-187
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Electronics, Electronique, Sciences exactes et technologie, Exact sciences and technology, Physique, Physics, Domaines interdisciplinaires: science des materiaux; rheologie, Cross-disciplinary physics: materials science; rheology, Science des matériaux, Materials science, Méthodes de nanofabrication, Methods of nanofabrication, Formation de nanomotifs, Nanoscale pattern formation, Traitements de surface, Surface treatments, Sciences appliquees, Applied sciences, Electronique, Electronics, Electronique des semiconducteurs. Microélectronique. Optoélectronique. Dispositifs à l'état solide, Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices, Dispositifs à ondes acoustiques, piézoélectriques, piézorésistifs, Acoustic wave devices, piezoelectric and piezoresistive devices, Metaux. Metallurgie, Metals. Metallurgy, Transformation de matériaux métalliques, Production techniques, Surface treatment, Composé III-VI, III-VI compound, Compuesto III-VI, Alumine, Alumina, Alúmina, Tonerde, Aluminium, Aluminio, Angle contact, Contact angle, Angulo contacto, Kontaktwinkel, Anodisation, Anodizing, Anodización, Elektrolytisches Oxidieren, Courant intense, High strength current, Corriente intensa, Diminution coût, Cost lowering, Reducción costes, Kostensenkung, Dispositif entraînement, Driving device, Dispositivo arrastre, Durcissement, Hardening, Endurecimiento, Haerten, Electrolyte acide, Acid electrolyte, Electrólito ácido, Evaluation performance, Performance evaluation, Evaluación prestación, Formation nanomotif, Nanopatterning, Formacíon nanomotivo, Gyroscope, Giroscopio, Microscopie électronique balayage, Scanning electron microscopy, Microscopía electrónica barrido, Rasterelektronenmikroskopie, Nanocomposite, Nanocompuesto, Nanofil, Nanowires, Nanostructure, Nanoestructura, Précision élevée, High precision, Precisión elevada, Rotor, Surface rugueuse, Rough surface, Superficie rugosa, Rauhe Oberflaeche, Traitement surface, Surface treatment, Tratamiento superficie, Oberflaechenbehandlung, Traitement(durcissement), Curing, Vitesse déplacement, Speed, Velocidad desplazamiento, Geschwindigkeit, 0707D, 8107B, 8107V, 8116R, Al2O3, Matériau nanostructuré, Nanostructured material, Drag reduction, Liquid-floated rotor gyroscope, Nanostructured, and Oleophobic
- Abstract
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Liquid-floated rotor gyroscopes can provide high accuracy at small volume and low cost. In rotor gyroscopes, the rotating speed of rotor can significantly affect the detection accuracy. This work presents a new kind of liquid-floated rotor gyroscope using super-oleophobic surface processing, which can improve the performance of driving system. In this work, an unconventional anodization in oxalic-acid electrolyte under high current was employed to fabricate diverse nanostructured alumina surfaces. The top-view SEM image shows the nanowire pyramid structure on the surface of processed sample. Modification of the rough surfaces was achieved by dipping substrates in 0.5 wt% 1H,1H,2H,2H-perfluoro-octadecyltrichlorosilane-in-hexane and then curing then at 120 °C for 1 h. The maximum contact angle (CA) of the aluminum rotor with nanowire pyramid structure was measured to be 156° in average. The oleophobicity of the rotor surface was used to reduce the resistance in the floating liquid. The test results show that, under the normal working state, the rotating speed of super-oleophobic rotor can be reached up to 3200 rpm. While a similar system without the micro-nano composite structure can only reach 2860 rpm. Thus, the nanostructured super-oleophobic alumina surface processing can greatly increase the rotating speed, thereby improving the performance of the gyro system.
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