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Biochemistry, molecular biology, biophysics, Biochimie, biologie moléculaire, biophysique, Analytical chemistry, Chimie analytique, Pharmacology drugs, Pharmacologie, galénique, Pollution, Sciences exactes et technologie, Exact sciences and technology, Chimie, Chemistry, Chimie analytique, Analytical chemistry, Méthodes chromatographiques et méthodes physiques associées à la chromatographie, Chromatographic methods and physical methods associated with chromatography, Méthodes chromatographiques en phase gazeuse, Gas chromatographic methods, Autres méthodes chromatographiques, Other chromatographic methods, Adsorbant, Adsorbent, Adsorbente, Analyse chimique, Chemical analysis, Análisis químico, Application, Aplicación, Article synthèse, Review, Artículo síntesis, Caractérisation, Characterization, Caracterización, Chromatographie HPLC, HPLC chromatography, Cromatografía HPLC, Chromatographie phase gazeuse, Gas chromatography, Cromatografía fase gaseosa, Chromatographie phase inverse, Reversed phase chromatography, Cromatografía fase inversa, Chromatographie échange ion, Ion exchange chromatography, Cromatografía cambio iónico, Diamant, Diamond, Diamante, Matériau composite, Composite material, Material compuesto, Microscopie électronique balayage, Scanning electron microscopy, Microscopía electrónica barrido, Microscopie électronique transmission, Transmission electron microscopy, Microscopía electrónica transmisión, Morphologie, Morphology, Morfología, Phase stationnaire, Stationary phase, Fase estacionaria, Structure surface, Surface structure, Estructura superficie, Traitement surface, Surface treatment, Tratamiento superficie, Chromatographie HILIC, Hydrophilic Interaction Liquid chromatography, Adsorbents, Chromatography, Composites, and Detonation nanodiamond

The idea of using diamond and diamond containing materials in separation sciences has attracted a strong interest in the past decade. The combination of a unique range of properties, such as chemical inertness, mechanical, thermal and hydrolytic stability, excellent thermal conductivity with minimal thermal expansion and intriguing adsorption properties makes diamond a promising material for use in various modes of chromatography. This review summarises the recent research on the preparation of diamond and diamond based stationary phases, their properties and chromatographic performance. Special attention is devoted to the dominant retention mechanisms evident for particular diamond containing phases, and their subsequent applicability to various modes of chromatography, including chromatography carried out under conditions of high temperature and pressure.

Metallurgy, welding, Métallurgie, soudage, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Metaux. Metallurgie, Metals. Metallurgy, Transformation de matériaux métalliques, Production techniques, Traitements de surface, Surface treatment, Broyage, Grinding(comminution), Molienda, Mahlen, Matériau composite, Composite material, Material compuesto, Verbundwerkstoff, Métallurgie poudre, Powder metallurgy, Metalurgia polvo, Pulvermetallurgie, Oxydation, Oxidation, Oxidación, Traitement surface, Surface treatment, Tratamiento superficie, Oberflaechenbehandlung, Ball milling, Bondcoats, Composites, Cyclic heating, and Powder processing

CoNiCrAlY powder and nano-size alumina powder were milled by a high-energy-attrition ball-mill, and an oxide-dispersed powder was produced with a mixed structure of metal and alumina in each particle. The oxide-dispersed bond coat powder was deposited by HVOF. Pores, however, were observed in the coating since the alumina was deposited without sufficient melting. Isothermal oxidation tests were carried out for the bond coat specimens at a temperature of 1373 K up to 1000 h in air. As a result, oxidation proceeded inside the coating, since oxygen penetrated through pores formed in the dispersed alumina. However, the authors find that another deposition using higher power levels led to a bond coat without pores. A commercially available oxide-dispersed CoNiCrAlY powder was also deposited by HVOF and VPS, and isothermal oxidation tests were performed. The analysis clarifies that the HVOF bond coat exhibited the thinnest thermally grown oxide than those of the VPS bond coat and conventional metallic bond coat. Furnace cycling tests were conducted using the specimens with an additional ceramic thermal-barrier coating. The specimen with the bond coat sprayed by VPS using commercial oxide-dispersed powder showed almost same number of cycles to delamination compared with the specimen with the conventional metal bond coat.

Polymers, paint and wood industries, Polymères, industries des peintures et bois, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Industrie des polymeres, peintures, bois, Polymer industry, paints, wood, Technologie des polymères, Technology of polymers, Formes d'application et semiproduits, Forms of application and semi-finished materials, Matériaux composites, Composites, Argile organique, Organic clay, Arcilla orgánica, Caoutchouc nitrile, Nitrile rubber, Caucho nitrilo, Compatibilisant, Compatibilizer, Compatibilizante, Composé de l'ammonium quaternaire, Quaternary ammonium compound, Amonio cuaternario compuesto, Etude expérimentale, Experimental study, Estudio experimental, Matériau composite, Composite material, Material compuesto, Matériau renforcé dispersion, Dispersion reinforced material, Material renforzado dispersión, Montmorillonite, Montmorilonita, Nanocomposite, Nanocompuesto, Propriété mécanique, Mechanical properties, Propiedad mecánica, Propriété rhéologique, Rheological properties, Propiedad reológica, Propriété thermique, Thermal properties, Propiedad térmica, Propriété traction, Tensile property, Propiedad tracción, Relation mise en oeuvre propriété, Property processing relationship, Relación puesta en marcha propiedad, SBR, Température transition vitreuse, Glass transition temperature, Temperatura transición vítrosa, Traitement surface, Surface treatment, Tratamiento superficie, Viscoélasticité, Viscoelasticity, Viscoelasticidad, Vulcanisat, Vulcanizate, and Vulcanizado

Different montmorillonites either, completely hydrophilic (Mont-0), amphiphilic (Mont-25, Mont-50, and Mont-75) or completely hydrophobic (Mont-100) were used as reinforcing fillers for styrene butadiene rubber (SBR) and acrylonitrile butadiene rubber (NBR) individually to predict the influence of the different forms on the properties of the rubbers (rheometric characteristics and mechanical properties). The shifts in the glass transition temperatures after the clay insertion were determined from dynamic mechanical thermal analysis to investigate the preference and action of each form. In addition, the storage moduli were used as indications to the corresponding mechanical properties of the samples. The influences could be followed after comparing the impacts of aging conditions on the properties of rubber compositions. The obtained data may provide a platform to suggest the mechanism by which these forms can in some cases act as compatibilizers in addition to their reinforcing/plasticizing effect when employed with the physically incompatible NBR/SBR (50/50) blend, which helps to optimize the properties of nanocomposites based on these blends. The proposed mechanism of action showed good correlation with the results of the mechanical properties and x-ray diffraction investigations as well. .

Chemical industry parachemical industry, Industrie chimique et parachimique, Mechanics acoustics, Mécanique et acoustique, Metallurgy, welding, Métallurgie, soudage, Polymers, paint and wood industries, Polymères, industries des peintures et bois, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Industrie des polymeres, peintures, bois, Polymer industry, paints, wood, Technologie des polymères, Technology of polymers, Formes d'application et semiproduits, Forms of application and semi-finished materials, Matériaux composites, Composites, Conductivité électrique, Electrical conductivity, Conductividad eléctrica, Dérivé du triazole, Triazole derivatives, Triazol derivado, Effet concentration, Concentration effect, Efecto concentración, Etude expérimentale, Experimental study, Estudio experimental, Graphène, Graphene, Matériau composite, Composite material, Material compuesto, Modification chimique, Chemical modification, Modificación química, Morphologie, Morphology, Morfología, Nanocomposite, Nanocompuesto, Polymère conducteur, Conducting polymers, Polymère conjugué, Conjugated polymer, Polímero conjugado, Polyélectrolyte, Polyelectrolyte, Polielectrolito, Propriété thermique, Thermal properties, Propiedad térmica, Propriété électrique, Electrical properties, Propiedad eléctrica, Préparation, Preparation, Preparación, Stabilité thermique, Thermal stability, Estabilidad térmica, Styrènesulfonate polymère, Styrenesulfonate polymer, Estireno sulfonato polímero, Thiophène dérivé polymère, Thiophene derivative polymer, Tiofeno derivado polímero, Traitement surface, Surface treatment, Tratamiento superficie, Ethylènedioxythiophène polymère, Graphène oxyde, Réaction click, A. Nano composites, A. Polymer―matrix composites (PMCs), B. Electrical properties, and D. Photoelectron spectroscopy (XPS)

The well dispersed graphene in poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) composites was achieved by chemical modification via click chemistry under mild condition in order to improve the electrical conductivity of polymer. Graphene sheets were prepared from natural graphite flake by a modified Hummers method followed by reducing with hydrazine. Graphene and PEDOT:PSS were functionalized with alkyne and azide, respectively followed by reacting via click chemistry at room temperature for 48 h using copper sulfate as catalyst. The successful functionalization and click reaction between terminal alkyne groups (―C≡C) on graphene sheets and terminal azide groups (—N3) of PED-OT:PSS were confirmed by Fourier Transform Infrared (FTIR), Raman and X-ray photoelectron (XPS) spectroscopy. The preliminary test to check the dissimilar dispersibility between graphene oxide and alkyne-modified graphene oxide in mixed water/hexane solvent was performed. Thermogravimetric analysis result exhibited the composites having excellent thermal stabilities due to the incorporation of graphene in PEDOT:PSS; however, clicked composites showed slightly lower thermal stabilities than unclicked ones as a result of cleavages of amide linkages and remaining oxygen-containing functionalities. It was also found that the surface morphologies observed by scanning electron microscope of clicked composites were smoother than those of unclicked composites because of the enhancement of interfacial interaction between graphene sheets and PEDOT:PSS matrix, resulting in a decrease in graphene agglomeration and, in turn, an increase in electrical conductivity.

Polymers, paint and wood industries, Polymères, industries des peintures et bois, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Industrie des polymeres, peintures, bois, Polymer industry, paints, wood, Technologie des polymères, Technology of polymers, Formes d'application et semiproduits, Forms of application and semi-finished materials, Matériaux composites, Composites, Acrylate copolymère, Acrylate copolymer, Acrilato copolímero, Composé allylique, Allylic compound, Compuesto alílico, Copolymère réticulé, Crosslinked copolymer, Copolímero reticulado, Effet concentration, Concentration effect, Efecto concentración, Effet mémoire forme, Shape memory effect, Efecto memoria forma, Etude expérimentale, Experimental study, Estudio experimental, Limite élasticité, Yield strength, Límite elasticidad, Matériau composite, Composite material, Material compuesto, Matériau renforcé dispersion, Dispersion reinforced material, Material renforzado dispersión, Morphologie, Morphology, Morfología, Nanocomposite, Nanocompuesto, Polymérisation photochimique, Photopolymerization, Polimerización fotoquímica, Propriété mécanique, Mechanical properties, Propiedad mecánica, Propriété thermique, Thermal properties, Propiedad térmica, Préparation, Preparation, Preparación, Prépolymère, Prepolymer, Prepolímero, Rayonnement UV, Ultraviolet radiation, Radiación ultravioleta, Température transition vitreuse, Glass transition temperature, Temperatura transición vítrosa, Traitement surface, Surface treatment, Tratamiento superficie, Uréthanne copolymère, Urethane copolymer, Uretano copolímero, Uréthanne polymère, Polyurethane, Uretano polímero, Graphène oxyde, UV cure, graphene oxide, hybrids, polyurethanes, and shape memory

Graphene oxide modified chemically with allyl isocyanate (iGO) was incorporated in various amounts into acrylate-terminated polyurethane (PU) via UV curing. The effects of this incorporation on the morphological, mechanical, dynamic mechanical, thermal and shape memory properties of the resulting hybrids were examined. The iGO nanoparticles incorporated into the PU chains acted as both multifunctional crosslinks and reinforcing fillers, and the effects were most pronounced at low iGO contents (0.5 and 1.0 wt%). Consequently, the glassy and rubbery state moduli, yield strength, glass transition temperature, shape fixity and shape recovery ratios were increased on adding up to 1 wt% iGO. At higher iGO loadings, the values of most of these properties decreased due to aggregation and the auto-inhibition of allyl compounds.

Polymers, paint and wood industries, Polymères, industries des peintures et bois, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Industrie des polymeres, peintures, bois, Polymer industry, paints, wood, Technologie des polymères, Technology of polymers, Formes d'application et semiproduits, Forms of application and semi-finished materials, Matériaux composites, Composites, Copolymère séquencé, Block copolymer, Copolímero secuencia, Cristallinité, Crystallinity, Cristalinidad, Cristallisation isotherme, Isothermal crystallization, Cristalización isotérmica, Effet concentration, Concentration effect, Efecto concentración, Etude expérimentale, Experimental study, Estudio experimental, Interaction intermoléculaire, Intermolecular interaction, Interacción intermolecular, Lactone copolymère, Lactone copolymer, Lactona copolímero, Lactone polymère, Lactone polymer, Lactona polímero, Matériau composite, Composite material, Material compuesto, Morphologie, Morphology, Morfología, Nanocomposite, Nanocompuesto, Point quantique, Quantum dot, Punto cuántico, Polymère optiquement actif, Optically active polymer, Polímero ópticamente activo, Préparation, Preparation, Preparación, Styrène copolymère, Styrene copolymer, Estireno copolímero, Séléniure de cadmium, Cadmium selenides, Séparation phase, Phase separation, Separación fase, Traitement surface, Surface treatment, Tratamiento superficie, Lactide copolymère, Lactide polymère, Stéréocomplexe, block copolymer, chirality, hybrid materials, nanoparticle, and quantum dot

A new nanoparticle/block copolymer (NP/BCP) hybrid material combining the unique properties of BCP poly(styrene)-b-poly(D-lactide) (PS-b-PDLA) and inorganic NP quantum dots CdSe was developed. A systematic study on the microphase separation of a series of PS-b-PDLAs by small-angle X-ray scattering showed that the degree of order of the separated microdomains depended on the initial state of the BCP and the measurement temperature and can be improved through isothermal crystallization of PDLA, thermal annealing and shear field etc. Incorporating a small amount of NPs into the BCP matrix can improve the mobility of the polymer chains and thus promote self-assembly of the BCP, which leads to hierarchically ordered structures. Excess NPs, however, cannot be completely incorporated into the PDLA domains, resulting in the phase transformation of the BCP, destruction of the ordered structure and even macroscopic phase separation due to the aggregation of NPs. An important observation is that stereocomplexation between PDLA and poly(L-lactide) could provide a driving force to promote microphase separation of the BCP. The strategy presented in the current work has potential applications for developing highly ordered NP/BCP hybrid materials.

Chemical industry parachemical industry, Industrie chimique et parachimique, Mechanics acoustics, Mécanique et acoustique, Metallurgy, welding, Métallurgie, soudage, Polymers, paint and wood industries, Polymères, industries des peintures et bois, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Industrie des polymeres, peintures, bois, Polymer industry, paints, wood, Technologie des polymères, Technology of polymers, Formes d'application et semiproduits, Forms of application and semi-finished materials, Matériaux composites, Composites, Acrylique acide polymère, Acrylic acid polymer, Acrílico ácido polímero, Agent accrochage, Coupling agent, Agente enganche, Alumine, Alumina, Alúmina, Céramique oxyde, Oxide ceramics, Cerámica óxido, Effet concentration, Concentration effect, Efecto concentración, Etude expérimentale, Experimental study, Estudio experimental, Matériau composite, Composite material, Material compuesto, Matériau hybride, Hybrid material, Material híbrido, Morphologie, Morphology, Morfología, Polymérisation radicalaire, Free radical polymerization, Polimerización radicalar, Polyélectrolyte, Polyelectrolyte, Polielectrolito, Procédé sol gel, Sol gel process, Procedimiento sol gel, Propriété chimique, Chemical properties, Propiedad química, Propriété thermique, Thermal properties, Propiedad térmica, Préparation, Preparation, Preparación, Silane organique, Organic silane, Silano orgánico, Stabilité thermique, Thermal stability, Estabilidad térmica, Traitement surface, Surface treatment, Tratamiento superficie, A. Hybrid, B. Surface properties, and E. Surface treatments

Hybrid inorganic-organic materials are promising systems for a variety of applications due to their extraordinary properties from the combination of different building blocks. In this work, we present the synthesis and characterization of a hybrid material based on poly[acrylic acid] (PAA), 3-(trimethoxysilyl)propyl methacrylate (TMPM), and aluminum oxide (Al2O3). The synthesis was carried out using a two-step process: first, a polymerization via radical initiation, and subsequently, a sol-gel process. The hybrids were prepared by keeping constant the amount of acrylic acid and aluminum oxide precursor but changing the amount of TMPM. The physical and chemical properties of the hybrids were investigated using infrared spectroscopy (FT-IR), X-ray diffraction (XRD), N2 absorption (SBET), scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). The results indicate that all of the materials were simultaneous interpenetrating networks (SIPNs) and that the morphologies and the properties depend on the amount of TMPM used. All materials showed good thermal stability, and the surface area of the composite decreased as more TMPM was incorporated in the network.

Polymers, paint and wood industries, Polymères, industries des peintures et bois, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Industrie des polymeres, peintures, bois, Polymer industry, paints, wood, Technologie des polymères, Technology of polymers, Formes d'application et semiproduits, Forms of application and semi-finished materials, Matériaux composites, Composites, Aniline copolymère, Aniline copolymer, Anilina copolímero, Corrosion électrochimique, Electrochemical corrosion, Corrosión electroquímica, Etude expérimentale, Experimental study, Estudio experimental, Imide copolymère, Imide copolymer, Imida copolímero, Matériau composite, Composite material, Material compuesto, Perméabilité gaz, Gas permeability, Permeabilidad gas, Polycondensation, Condensation polymerization, Policondensación, Procédé sol gel, Sol gel process, Procedimiento sol gel, Propriété transport, Transport properties, Propiedad transporte, Propriété électrochimique, Electrochemical properties, Propiedad electroquímica, Préparation, Preparation, Preparación, Revêtement anticorrosion, Corrosion protective coatings, Résistance corrosion, Corrosion resistance, Resistencia corrosión, Silice, Silica, Sílice, Traitement surface, Surface treatment, and Tratamiento superficie

In this study, a series of electroactive polyimide/SiO2 (EPIS) composite materials containing conjugated segments of electroactive amino-capped aniline trimer (AT) unit were successfully prepared. First of all, the amino-modified silica (AMS) particles of ~100 nm in diameter were synthesized by performing the conventional base-catalyzed sol―gel reactions. Subsequently, the AMS nanoparticles were blending into the polymerization reactions between AT and 4,4ʹ-(4,4ʹ-isopropylidenediphenoxy)-bis(phthalic anhydride), leading to the formation of EPIS composites. The as-prepared EPIS materials in the form of coating on cold-rolled steel (CRS) electrode were found to be much superior in corrosion protection over those of non-electroactive polyimide and EPI materials based on a series of electrochemical corrosion measurements in saline. The significant enhancement in corrosion protection of EPIS coatings on CRS electrodes might probably be attributed to the redox catalytic property of organic EPI inducing the formation of passive metal oxide layer and the barrier property of well-dispersed AMS nanoparticles existed in EPI matrix.

Chemical industry parachemical industry, Industrie chimique et parachimique, Mechanics acoustics, Mécanique et acoustique, Metallurgy, welding, Métallurgie, soudage, Polymers, paint and wood industries, Polymères, industries des peintures et bois, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Electronique, Electronics, Electronique des semiconducteurs. Microélectronique. Optoélectronique. Dispositifs à l'état solide, Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices, Fabrication microélectronique (technologie des matériaux et des surfaces), Microelectronic fabrication (materials and surfaces technology), Industrie des polymeres, peintures, bois, Polymer industry, paints, wood, Technologie des polymères, Technology of polymers, Formes d'application et semiproduits, Forms of application and semi-finished materials, Matériaux composites, Composites, Domaines d'application, Application fields, Adhésif, Adhesive, Adhesivo, Argent, Silver, Plata, Conductivité thermique, Thermal conductivity, Conductividad térmica, Epoxyde résine, Epoxy resin, Epóxido resina, Etude expérimentale, Experimental study, Estudio experimental, Fabrication microélectronique, Microelectronic fabrication, Fabricación microeléctrica, Iode, Iodine, Iodo, Matériau composite, Composite material, Material compuesto, Microparticule, Microparticle, Micropartícula, Morphologie, Morphology, Morfología, Particule métallique, Metal particle, Partícula metálica, Particule sphérique, Spherical particle, Partícula esférica, Propriété thermique, Thermal properties, Propiedad térmica, Traitement chimique, Chemical treatment, Tratamiento químico, Traitement surface, Surface treatment, Tratamiento superficie, Adhésif conducteur, A. Polymer―matrix composites (PMCs), B. Thermal properties, and D. Scanning electron microscopy (SEM)

Heat dissipation is a critical issue in many areas such as the high-performance electronic devices. The present work gives a detailed investigation regarding a simple and efficient surface modification method, which can remarkably improve the thermal conductivity of the isotropically thermally conductive adhesives (TCAs). Herein we demonstrate that the thermal conductivity of TCAs based on micron-sized silver fillers can be improved to near eightfold merely through simple surface chemistry treatment of the fillers, without changing the conventional epoxy resin (adhesive) processing conditions. Experimental results show that the thermal conductivity of a TCA sample with iodine modified silver fillers (85 wt%, size 1-2 μm. near-spherical particles) achieved 13.5 Wm-1 K-1 when cured at 150 °C. Compared to the unmodified silver-based TCAs, only 1.7 Wm-1 K-1 was achieved when cured in the same condition. This work suggests that through modulating the filler interface of a TCA, the thermal conductivity of a TCA can be drastically improved. These TCAs with superior isotropic thermal conductivity may find many heat dissipation applications e.g. surface mounted devices (SMDs) and high power (printed circuit) motherboards.

Chemical industry parachemical industry, Industrie chimique et parachimique, Mechanics acoustics, Mécanique et acoustique, Metallurgy, welding, Métallurgie, soudage, Polymers, paint and wood industries, Polymères, industries des peintures et bois, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Industrie des polymeres, peintures, bois, Polymer industry, paints, wood, Technologie des polymères, Technology of polymers, Formes d'application et semiproduits, Forms of application and semi-finished materials, Matériaux composites, Composites, Amination, Aminación, Composition chimique, Chemical composition, Composición química, Epoxyde résine, Epoxy resin, Epóxido resina, Etude expérimentale, Experimental study, Estudio experimental, Fibre carbone, Carbon fiber, Fibra carbón, Fibre minérale, Mineral fiber, Fibra inorgánica, Fibre revêtue, Coated fiber, Fibra revestida, Interface fibre matrice, Matrix fiber interface, Interfase fibra matriz, Matériau composite, Composite material, Material compuesto, Matériau renforcé fibre, Fiber reinforced material, Material reforzado fibra, Propriété interface, Interface properties, Propiedad interfase, Propriété mécanique, Mechanical properties, Propiedad mecánica, Relation mise en oeuvre propriété, Property processing relationship, Relación puesta en marcha propiedad, Résistance cisaillement, Shear strength, Resistencia cizallamiento, Stratifié, Laminate, Estratificado, Traitement surface, Surface treatment, Tratamiento superficie, Résistance cisaillement interfacial, Résistance cisaillement interlaminaire, A. Carbon fibers, A. Polymer―matrix composites, B. Surface properties, E. Surface treatments, and Supercritical fluids

To improve the interfacial properties between carbon fibers and epoxy matrix, the fibers were treated by an ammoniac medium, which consisted of supercritical water, ethanol and triethylene tetramine. The images of atomic force microscopy and scanning electron microscope indicate that coating layers are formed on the surfaces of treated fibers. The results of X-ray photoelectron spectroscopy demonstrate that N content on the surfaces of carbon fibers increases and the main ammoniac groups of the coating layers are amino and imino groups. The mechanical measurements indicate that both interlaminar and interface shear strength of carbon fibers are significantly increased after amination.

Polymers, paint and wood industries, Polymères, industries des peintures et bois, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Industrie des polymeres, peintures, bois, Polymer industry, paints, wood, Technologie des polymères, Technology of polymers, Formes d'application et semiproduits, Forms of application and semi-finished materials, Matériaux composites, Composites, Acide sulfonique, Sulfonic acid, Acido sulfónico, Agent accrochage, Coupling agent, Agente enganche, Benzooxazole dérivé polymère, Benzoxazole derivative polymer, Benzooxazol derivado polímero, Epoxyde résine, Epoxy resin, Epóxido resina, Etude expérimentale, Experimental study, Estudio experimental, Fibre synthétique, Synthetic fiber, Fibra sintética, Interface fibre matrice, Matrix fiber interface, Interfase fibra matriz, Matériau renforcé fibre, Fiber reinforced material, Material reforzado fibra, Molécule polyédrique, Polyhedral molecule, Molécula poliédrica, Mélange polymère, Polymer blends, Oligomère, Oligomer, Oligómero, Polymère aromatique, Aromatic polymer, Polímero aromático, Propriété interface, Interface properties, Propiedad interfase, Propriété surface, Surface properties, Propiedad superficie, Rugosité, Roughness, Rugosidad, Silane organique, Organic silane, Silano orgánico, Silsesquioxane polymère, Silsesquioxane polymer, Silsesquioxano polímero, Traitement surface, Surface treatment, Tratamiento superficie, and Benzobisoxazole(p-phénylène) polymère

A novel three-step approach of methanesulfonic acid/γ-aminopropyl triethoxy silane/GlycidylEthyl polyhedral oligomeric silsesquioxane (MSA/KH550/POSS) was proposed to functionalize the surface of high modulus poly (p-phenylene-2,6-benzobisoxazole) (HMPBO) fibers. Results indicated that GlycidylEthyl POSS was successfully grafted on the surface of HMPBO fibers and the surface roughness of HMPBO fibers was increased obviously. The single fiber pull-out strength of POSS-g-HMPBO/epoxy resin microcomposite was improved to 1.19 MPa, better than that of native HMPBO/epoxy resin microcomposite.

Polymers, paint and wood industries, Polymères, industries des peintures et bois, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Industrie des polymeres, peintures, bois, Polymer industry, paints, wood, Technologie des polymères, Technology of polymers, Formes d'application et semiproduits, Forms of application and semi-finished materials, Matériaux composites, Composites, Caoutchouc liquide, Liquid rubber, Caucho líquido, Caoutchouc naturel époxydé, Epoxidized natural rubber, Caucho natural epóxido, Caoutchouc naturel, Natural rubber, Caucho natural, Cendre, Ash, Ceniza, Déchet industriel, Industrial waste, Desperdicio industrial, Etude expérimentale, Experimental study, Estudio experimental, Huile palme, Palm oil, Aceite palma, Huile végétale, Vegetable oil, Aceite vegetal, Matériau composite, Composite material, Material compuesto, Particule enrobée, Coated particle, Partícula envuelta, Propriété mécanique, Mechanical properties, Propiedad mecánica, Propriété thermique, Thermal properties, Propiedad térmica, Résistance allongement, Elongation strength, Resistencia alargamiento, Résistance traction, Tensile strength, Resistencia tracción, Stabilité thermique, Thermal stability, Estabilidad térmica, Traitement surface, Surface treatment, Tratamiento superficie, Vieillissement thermique, Thermal ageing, Envejecimiento térmico, Ageing, Liquid epoxidized natural rubber, Oil palm ash, and Thermogravimetric analysis

Oil Palm Ash (OPA), coated with a Liquid Epoxidized Natural Rubber (LENR), was prepared prior to compounding with natural rubber and other curing ingredients, using a laboratory two-roll mill. Owing to better interfacial adhesion between the LENR coating layer and the OPA particles, the tensile strength and elongation at break of the LENR-coated OPA showed higher retention than non-coated OPA filled natural rubber composites after being subjected to thermal ageing at 100 °C for two days. Thermogravimetric Analysis (TGA) indicated that the thermal stability of LENR-coated OPA filled natural rubber composites was higher than that of non-coated OPA filled natural rubber composites. However, this phenomenon only occurred from ambient temperature up to the temperature at which the LENR coating phase started to decompose.

Polymers, paint and wood industries, Polymères, industries des peintures et bois, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Industrie des polymeres, peintures, bois, Polymer industry, paints, wood, Technologie des polymères, Technology of polymers, Formes d'application et semiproduits, Forms of application and semi-finished materials, Matériaux composites, Composites, Argile, Clay, Arcilla, Cristallinité, Crystallinity, Cristalinidad, Cristallisation état fondu, Melt crystallization, Cristalización estado fundido, Effet concentration, Concentration effect, Efecto concentración, Ethylène polymère, Polyethylene, Etileno polímero, Etude expérimentale, Experimental study, Estudio experimental, Laponite, Laponita, Matériau composite, Composite material, Material compuesto, Molécule polyédrique, Polyhedral molecule, Molécula poliédrica, Nanocomposite, Nanocompuesto, Nickel Complexe, Nickel Complexes, Niquel Complejo, Oléfine polymère, Olefin polymer, Olefina polímero, Point fusion, Melting point, Punto fusión, Polymère ramifié, Branched polymer, Polímero ramificado, Polymérisation catalyseur complexe, Complex catalyst polymerization, Polimerización catalizador complejo, Propriété thermique, Thermal properties, Propiedad térmica, Silsesquioxane polymère, Silsesquioxane polymer, Silsesquioxano polímero, Structure moléculaire, Molecular structure, Estructura molecular, Traitement surface, Surface treatment, Tratamiento superficie, Degré ramification, Branched polyethylene, Branching structure, Melting and crystallization behavior, OapPOSS-modified clay, and Supported nickel α-diimine catalyst

Ethylene polymerization was catalyzed by using nickel α-diimine covalently supported inside the octaaminopropyl polyhedral oligometric silsesquioxane (OapPOSS)-modified Laponite clay layers. The branching structure, melting, and crystallization of the polyethylene (PE) matrix of PE/OapPOSS-clay nanocomposites were investigated by X-ray diffraction analysis (XRD), nuclear magnetic resonance (NMR), differential scanning calorimetry (DSC) and Fourier transform infrared (FTIR). The results showed that the PE matrix of PE/OapPOSS-clay nanocomposites has lower branching density and higher melting point and degree of crystallinity when compared with those of PE prepared by unsupported catalyst. It is proposed that the chain walking rate of the ethylene polymerization was reduced greatly, resulting in a lower degree of branching because the catalyst has been intercalated into the clay galleries. In order to further investigate the chain branching distribution of the PE matrix of PE/OapPOSS-clay nanocomposites, a DSC technique termed successive self-nucleation and annealing was applied. It was found that the PE matrix of PE/OapPOSS-clay nanocomposites has a larger high melting point fraction, thicker lamella and longer Ln and Lw than PE obtained with unsupported catalyst.

Polymers, paint and wood industries, Polymères, industries des peintures et bois, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Industrie des polymeres, peintures, bois, Polymer industry, paints, wood, Technologie des polymères, Technology of polymers, Constituants de formulation, Compounding ingredients, Ignifugeants, retardateurs de flamme et réducteurs de fumée, Fireproof agents, Formes d'application et semiproduits, Forms of application and semi-finished materials, Matériaux composites, Composites, Additif, Additive, Aditivo, Agent accrochage, Coupling agent, Agente enganche, Dimension particule, Particle size, Dimensión partícula, Ethylène haute densité polymère, High density ethylene polymer, Etileno alta densidad polímero, Etude expérimentale, Experimental study, Estudio experimental, Hydroxyde de magnésium, Magnesium hydroxide, Magnesio hidróxido, Inflammabilité, Flammability, Inflamabilidad, Matériau composite, Composite material, Material compuesto, Matériau renforcé dispersion, Dispersion reinforced material, Material renforzado dispersión, Morphologie, Morphology, Morfología, Nanocomposite, Nanocompuesto, Oléfine polymère, Olefin polymer, Olefina polímero, Propriété mécanique, Mechanical properties, Propiedad mecánica, Propriété thermique, Thermal properties, Propiedad térmica, Propriété traction, Tensile property, Propiedad tracción, Retardateur flamme, Flame retardant, Retardador llama, Silane organique, Organic silane, Silano orgánico, Stabilité thermique, Thermal stability, Estabilidad térmica, Traitement surface, Surface treatment, and Tratamiento superficie

The modification of magnesium hydroxide (MH) with triethoxy vinyl silane (TVS) was carried out via three different methods and the results are discussed with respect to their effect on the flame retardant and the tensile properties of high density polyethylene (HDPE) nanocomposites. Via a xylene suspension of MH and TVS, via a water suspension of MH and TVS, and via powder mixing of MH and TVS. It was found that in all three cases, Si—O—Mg bonds formed on the MH particles surface. Also, this silane modification induced a certain level of particle agglomeration, but without modifying their morphology or particle size. It was also found that the flame retardant properties of the HDPE nanocomposites did not improve because of the use of silane modified MH. During the flame retardant tests, all nanocomposites passed the UL-94-HB, but it was observed that the flame permanence time was longer when using modified MH. The tensile properties were negatively affected by the addition of unmodified MH; the nanocomposites became hard and brittle, with reduced flexibility. This negative effect was diminished when using silane modified MH.

Polymers, paint and wood industries, Polymères, industries des peintures et bois, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Industrie des polymeres, peintures, bois, Polymer industry, paints, wood, Technologie des polymères, Technology of polymers, Formes d'application et semiproduits, Forms of application and semi-finished materials, Matériaux composites, Composites, Sciences biologiques et medicales, Biological and medical sciences, Sciences biologiques fondamentales et appliquees. Psychologie, Fundamental and applied biological sciences. Psychology, Industries agroalimentaires, Food industries, Généralités, General aspects, Manutention, stockage, conditionnement, transport, Handling, storage, packaging, transport, Amidon, Starch, Almidón, Argile organique, Organic clay, Arcilla orgánica, Biodégradabilité, Biodegradability, Biodegradabilidad, Composé de l'ammonium quaternaire, Quaternary ammonium compound, Amonio cuaternario compuesto, Effet concentration, Concentration effect, Efecto concentración, Emballage, Packaging, Empaque, Etude expérimentale, Experimental study, Estudio experimental, Indice oxygène, Oxygen index, Indice oxígeno, Matériau composite, Composite material, Material compuesto, Morphologie, Morphology, Morfología, Nanocomposite, Nanocompuesto, Oside polymère, Oside polymer, Osido polímero, Perméabilité gaz, Gas permeability, Permeabilidad gas, Produit alimentaire, Foodstuff, Producto alimenticio, Propriété biologique, Biological properties, Propiedad biológica, Propriété thermique, Thermal properties, Propiedad térmica, Propriété transport, Transport properties, Propiedad transporte, Traitement surface, Surface treatment, and Tratamiento superficie

Starch/clay bionanocomposites were prepared by incorporation of varying concentrations of nanoclay (Cloisite® 30B) through solution blending. The chemical interaction of starch with clay was evidenced from ultraviolet-visible (UV-visible) and fourier transform infrared spectroscopy. The material was also characterized through X-ray diffraction, transmission electron microscopy, and scanning electron microscopy study. The bionanocomposites were found to be more thermally stable as revealed from thermogravimetric analysis. The fire retardancy of the bionanocomposites was investigated from limiting oxygen index measurement. The result showed improvement of this property with increase in clay loading. From the measurement of oxygen permeabilities, it was found that the oxygen barrier property of starch/clay (10%) was improved by more than three times compared to virgin starch. The biodegradability of the material combined with the above mentioned properties could make it applicable as food packaging material.

Chemical industry parachemical industry, Industrie chimique et parachimique, Mechanics acoustics, Mécanique et acoustique, Metallurgy, welding, Métallurgie, soudage, Polymers, paint and wood industries, Polymères, industries des peintures et bois, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Industrie des polymeres, peintures, bois, Polymer industry, paints, wood, Technologie des polymères, Technology of polymers, Formes d'application et semiproduits, Forms of application and semi-finished materials, Matériaux composites, Composites, Acide stéarique, Stearic acid, Esteárico ácido, Carbonate de calcium, Calcium carbonate, Calcio carbonato, Degré dispersion, Dispersion degree, Grado dispersión, Effet concentration, Concentration effect, Efecto concentración, Etude expérimentale, Experimental study, Estudio experimental, Lactique acide polymère, Lactic acid polymer, Láctico ácido polímero, Matériau composite, Composite material, Material compuesto, Matériau renforcé dispersion, Dispersion reinforced material, Material renforzado dispersión, Module conservation, Storage modulus, Módulo conservación, Morphologie, Morphology, Morfología, Nanocomposite, Nanocompuesto, Polymère aliphatique, Aliphatic polymer, Polímero alifático, Propriété rhéologique, Rheological properties, Propiedad reológica, Propriété thermique, Thermal properties, Propiedad térmica, Stabilité thermique, Thermal stability, Estabilidad térmica, Traitement surface, Surface treatment, Tratamiento superficie, A. Particle-reinforcement, A. Polymer―matrix composites (PMCs), D. Electron microscopy, and D. Thermal analysis

The effect of nano-calcium carbonate on chain linked poly(lactic acid) was investigated. In order to improve inorganic nanofillers/polymer compatibility CaCO3 nanoparticle surface was treated by stearic acid. The nanocomposites were prepared by means of solution blending and further studied by using dynamic mechanical analysis, fourier transform infrared spectroscopy, scanning electron microscopy and thermogravimetric analysis. Morphological analysis performed on nanocomposites fractured surfaces has revealed that the CaCO3 modification induces homogeneous and fine dispersion of nanoparticles into polymer as well as strong interfacial adhesion between the two phases. An increase in the Tg and storage modulus of the resulting nanocomposites was observed with the increase of calcium carbonate ratio. Thermogravimetric results showed a lower degradation temperature with the increase of calciium carbonate ration in the polymer matrix.

Polymers, paint and wood industries, Polymères, industries des peintures et bois, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Industrie des polymeres, peintures, bois, Polymer industry, paints, wood, Technologie des polymères, Technology of polymers, Formes d'application et semiproduits, Forms of application and semi-finished materials, Matériaux composites, Composites, Conductivité électrique superficielle, Surface electrical conductivity, Conductividad eléctrica superficial, Cristallinité, Crystallinity, Cristalinidad, Effet concentration, Concentration effect, Efecto concentración, Etude expérimentale, Experimental study, Estudio experimental, Lactique acide polymère, Lactic acid polymer, Láctico ácido polímero, Matériau composite, Composite material, Material compuesto, Matériau renforcé dispersion, Dispersion reinforced material, Material renforzado dispersión, Module élasticité, Elastic modulus, Módulo elasticidad, Moulage injection, Injection molding, Moldeo por inyección, Nanocomposite, Nanocompuesto, Nanotube carbone, Carbon nanotubes, Nanotube multifeuillets, Multiwalled nanotube, Polymère aliphatique, Aliphatic polymer, Polímero alifático, Propriété mécanique, Mechanical properties, Propiedad mecánica, Propriété thermique, Thermal properties, Propiedad térmica, Propriété électrique, Electrical properties, Propiedad eléctrica, Renforcement mécanique, Strengthening, Refuerzo mecánico, Résistance traction, Tensile strength, Resistencia tracción, Stabilité thermique, Thermal stability, Estabilidad térmica, Traitement surface, Surface treatment, Tratamiento superficie, Cristallisation non isotherme, Fusion multiple, Nanotube carbone fonctionnalisé, and Polymère biodégradable

Structural, mechanical, thermal, and electrical properties of low-loaded (0—1.5 wt%), untreated, and treated (with heat and nitric acid) multiwalled carbon nanotubes (MWCNTs)/poly (lactic acid) (PLA) nanocomposites have been studied. Among all synthesized composites, acid-treated 1.0 wt% MWCNTs reinforced PLA shows superior tensile strength and modulus to those shown by other samples. All nanocomposites including the pure PLA exhibit the orthorhombic β-form crystalline structure with low degree of crystallization, as demonstrated by X-ray diffraction study. Differential scanning calorimetry (DSC) of injection molded samples, respectively, reveals an enhancement of PLA crystallinity by 8% and 14% for untreated and treated nanotubes, relating to the observed improvement in mechanical properties. Nanocomposites show double melting behavior when crystallized nonisothermally by DSC, whilst the pure PLA shows single melting character. Thermogravimetric analysis discloses that the MWCNTs-loaded sample degraded faster than PLA. Surface resistivity of the nanocomposites is found to be dropped drastically by a factor of 1013 with a low loading of MWCNTs (1.5 wt%). A detailed discussion and correlation of the observed structures and properties are presented in this study.

Chemical industry parachemical industry, Industrie chimique et parachimique, Mechanics acoustics, Mécanique et acoustique, Metallurgy, welding, Métallurgie, soudage, Polymers, paint and wood industries, Polymères, industries des peintures et bois, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Industrie des polymeres, peintures, bois, Polymer industry, paints, wood, Technologie des polymères, Technology of polymers, Formes d'application et semiproduits, Forms of application and semi-finished materials, Matériaux composites, Composites, Argile organique, Organic clay, Arcilla orgánica, Caoutchouc thermoplastique, Thermoplastic rubber, Caucho termoplástico, Caprolactone polymère, Polycaprolactone, Caprolactona polímero, Esteruréthanne polymère, Esterurethane polymer, Esteruretano polímero, Etude expérimentale, Experimental study, Estudio experimental, Lactone polymère, Lactone polymer, Lactona polímero, Matériau composite, Composite material, Material compuesto, Montmorillonite, Montmorilonita, Morphologie, Morphology, Morfología, Nanocomposite, Nanocompuesto, Perméabilité vapeur eau, Steam permeability, Permeabilidad vapor agua, Polymère aliphatique, Aliphatic polymer, Polímero alifático, Polymère greffé, Graft polymers, Polymérisation ouverture cycle, Ring opening polymerization, Polimerización abertura ciclo, Propriété mécanique, Mechanical properties, Propiedad mecánica, Propriété thermique, Thermal properties, Propiedad térmica, Propriété transport, Transport properties, Propiedad transporte, Relation structure propriété, Property structure relationship, Relación estructura propiedad, Traitement surface, Surface treatment, Tratamiento superficie, Uréthanne élastomère, Polyurethane elastomer, Uretano elastómero, Mélangeage état fondu, A. Nanoclays, A. Nanocomposites, A. Polymers, B. Thermomechanical properties, and B. Transport properties

The lamellar structure of montmorillonite (MMT) clays exhibits an interesting potential to improve the barrier properties of thermoplastic polyurethanes (TPU). However direct melt blending of an ester-based TPU and functional organoclays, despite showing good filler dispersion, did not allowed for improving neither barrier properties (i.e., sorption and diffusion to water vapor) not mechanical performances with respect to the unfilled TPU. Therefore, two alternative strategies involving poly(ε-caprolactone) (PCL)/ organoclay masterbatches were explored to investigate the possibility to prepare materials with improved mechanical and barrier properties. In the first strategy, a PCL/organoclay masterbatch with high inorganic content was obtained by melt-blending (coined free PCL masterbatch), whereas in the second strategy PCL-grafted organoclay nanohybrids, also with high inorganic content were synthesized by in situ intercalative grafting/ring-opening polymerization of ε-caprolactone (CL). Purposely, ROP of CL was initiated from hydroxyl groups available onto the MMT surface actually organo-modified by alkylammonium cations bearing hydroxyl functions (coined nanohybrid PCL masterbatch). These highly-filled PCL masterbatches (with ca. 25 wt% in inorganics) were then added into the ester-based TPU to prepare nanoclay/polyurethane nanocomposites by melt-blending. The morphology and dispersion of the resulting materials were characterized by X-ray diffraction and transmission electron microscopy. Improved sorption and diffusion properties towards water vapor as well as mechanical properties were measured. Herein, these results are discussed as a function of both clay dispersion and matrix/organoclay interaction.

Polymers, paint and wood industries, Polymères, industries des peintures et bois, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Industrie des polymeres, peintures, bois, Polymer industry, paints, wood, Technologie des polymères, Technology of polymers, Formes d'application et semiproduits, Forms of application and semi-finished materials, Matériaux composites, Composites, Aluminium Hydroxyde, Aluminium Hydroxides, Aluminio Hidróxido, Caoutchouc nitrile, Nitrile rubber, Caucho nitrilo, Cinétique, Kinetics, Cinética, Etude expérimentale, Experimental study, Estudio experimental, Hydroxyde double lamellaire, Layered double hydroxide, Hidróxido doble laminar, Matériau composite, Composite material, Material compuesto, Matériau renforcé dispersion, Dispersion reinforced material, Material renforzado dispersión, Morphologie, Morphology, Morfología, Nanocomposite, Nanocompuesto, Peroxyde organique, Organic peroxide, Peróxido orgánico, Propriété mécanique, Mechanical properties, Propiedad mecánica, Propriété traction, Tensile property, Propiedad tracción, Relation mise en oeuvre propriété, Property processing relationship, Relación puesta en marcha propiedad, Relation mise en oeuvre structure, Structure processing relationship, Relación puesta en marcha estructura, Soufre, Sulfur, Azufre, Stéarate, Stearate, Estearato, Traitement surface, Surface treatment, Tratamiento superficie, Vulcanisat, Vulcanizate, Vulcanizado, Vulcanisation, Vulcanization, Vulcanización, Zinc Hydroxyde, Zinc Hydroxides, Zinc Hidróxido, Sulfur vulcanization, and Zinc oxide

The aim of this investigation is to highlight the potentials of layered double hydroxides (LDH) and to serve as a replacement for zinc oxide and stearic acid from the basic rubber formulation. This will eventually result in about a 10× significant reduction of Zn2+ ion concentration in the final compound. The unique advantage of stearate ion-modified LDH is the delivery of zinc ions to accelerate and stearate ions to activate the vulcanization process. Furthermore, it can also reinforce the rubber matrix by virtue of its layered structure as nanofiller.

Chemical industry parachemical industry, Industrie chimique et parachimique, Mechanics acoustics, Mécanique et acoustique, Metallurgy, welding, Métallurgie, soudage, Polymers, paint and wood industries, Polymères, industries des peintures et bois, Sciences exactes et technologie, Exact sciences and technology, Sciences appliquees, Applied sciences, Industrie des polymeres, peintures, bois, Polymer industry, paints, wood, Technologie des polymères, Technology of polymers, Formes d'application et semiproduits, Forms of application and semi-finished materials, Matériaux composites, Composites, Adhésivité, Adhesivity, Adhesividad, Composite hybride, Hybrid composite, Compuesto híbrido, Dépôt électrophorétique, Electrophoretic deposition, Depósito electroforético, Epoxyde résine, Epoxy resin, Epóxido resina, Etude expérimentale, Experimental study, Estudio experimental, Fibre carbone, Carbon fiber, Fibra carbón, Fibre minérale, Mineral fiber, Fibra inorgánica, Interface fibre matrice, Matrix fiber interface, Interfase fibra matriz, Matériau composite, Composite material, Material compuesto, Modélisation, Modeling, Modelización, Méthode élément fini, Finite element method, Método elemento finito, Nanocomposite, Nanocompuesto, Nanotube carbone, Carbon nanotubes, Propriété interface, Interface properties, Propiedad interfase, Propriété mécanique, Mechanical properties, Propiedad mecánica, Résistance arrachement poussée, Push out resistance, Resistencia empujar, Simulation numérique, Numerical simulation, Simulación numérica, Traitement surface, Surface treatment, Tratamiento superficie, Ténacité, Fracture toughness, Tenacidad, A. Carbon fibers, A. Carbon nanotubes, B. Interfacial strength, C. Finite element analysis (FEA), and D. Electrophoretic deposition

Electrophoretic deposition (EPD) of carbon nanotubes (CNTs) on carbon fibers has been implemented as a continuous process on laboratory-scale. The interfacial adhesion and fracture toughness of the carbon fibers in an epoxy composite is assessed by a modified single-fiber push-out test. A detailed energy analysis yields the different energy contributions in the push-out process. A comparison between CNT-deposited, as received and oxidized carbon fibers (passing through the EPD process without CNT) indicates that interfacial adhesion and fracture toughness are not affected by the different fiber treatments. Interfacial friction after fiber debonding, however, is significantly changed. This is confirmed by finite element simulation which has to include friction for reproducing the essential features of the load―displacement plots from fiber push-out. Scanning electron micrographs indicate little interaction between CNT and carbon fibers, but point to changes in surface roughness of CNT-deposited and oxidized fibers after push-out. Therefore, the cyclic loading―unloading fiber push-out test seems well suited to investigate the micromechanical behavior of carbon fiber composites and to discriminate and quantify the different energy contributions to the total load―displacement curves.