Carbene-catalyzed dynamic kinetic resolution of carboxylic esters
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- Authors:
- Xingkuan Chen
Jacqueline Zi Mei Fong
Jianfeng Xu
Chengli Mou
Yunpeng Lu
Song Yang
Bao-An Song
Yonggui Robin Chi - Source:
- Journal of the American Chemical Society. June 15, 2016, Vol. 138 Issue 23, 7212-7215
- Publication Date:
- 2016-06-15
- Language:
- English
- Abstract:
- The article reports the first carbene-catalyzed dynamic kinetic resolution of alpha,alpha-disubstituted carboxylic esters with up to 99:1 er and 99% yield. The present study clearly illustrates the unique power of carbene-catalyzed reactions of readily available and easy to handle carboxylic esters.
- Format:
- Academic Journal
- Database:
- Gale General OneFile
- Journal:
- Journal of the American Chemical Society
- Volume:
- 138
- Issue:
- 23
- Page Start:
- 7212
- ISSN:
- 00027863