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Book
xii, 306 pages : illustrations (some color) ; 24 cm
  • Preface Editor Contributors Solar Water Splitting Using Semiconductor Systems-- Lorenzo Rovelli and K. Ravindranathan Thampi Photocatalytic Hydrogen Evolution-- Yusuke Yamada and Shunichi Fukuzumi CO2 to Fuels-- Atsushi Urakawa and Jacinto Sa Methane Activation and Transformation over Nanocatalysts-- Rajaram Bal and Ankur Bordoloi Fischer-Tropsch: Fuel Production with Cobalt Catalysts-- Cristina Paun, Jacinto Sa, and Kalala Jalama Syngas to Methanol and Ethanol-- Martin Muhler and Stefan Kaluza Steam Reforming-- Karin Fottinger Biomass to Liquid Biofuels via Heterogeneous Catalysis-- Michael Stocker and Roman Tschentscher Catalytic Pyrolysis of Lignocellulosic Biomass-- K. Seshan Recent Trends in the Purification of H2 Streams by Water-Gas Shift and PROX-- A. Sepulveda-Escribano and J. Silvestre-Albero Index.
  • (source: Nielsen Book Data)
Fuel Production with Heterogeneous Catalysis presents the groundbreaking discoveries, recent developments, and future perspectives of one of the most important areas of renewable energy research-the heterogeneous catalytic production of fuels. Comprised of chapters authored by leading experts in the field, this authoritative text: * Focuses primarily on the state-of-the-art catalysts and catalytic processes anticipated to play a pivotal role in the production of fuels * Describes production of fuels from renewable sources using environmentally friendly technologies * Exposes the advantages and disadvantages of each production process * Suggests solutions to minimize the impact of fuel transportation * Conveys the importance of catalysis for the sustainable production of fuels Fuel Production with Heterogeneous Catalysis delivers a comprehensive overview of the current state of the art of the heterogeneous catalytic production of fuels, providing reaction mechanism schemes, engineering solutions, valuable industry insights, and more.
(source: Nielsen Book Data)
  • Preface Editor Contributors Solar Water Splitting Using Semiconductor Systems-- Lorenzo Rovelli and K. Ravindranathan Thampi Photocatalytic Hydrogen Evolution-- Yusuke Yamada and Shunichi Fukuzumi CO2 to Fuels-- Atsushi Urakawa and Jacinto Sa Methane Activation and Transformation over Nanocatalysts-- Rajaram Bal and Ankur Bordoloi Fischer-Tropsch: Fuel Production with Cobalt Catalysts-- Cristina Paun, Jacinto Sa, and Kalala Jalama Syngas to Methanol and Ethanol-- Martin Muhler and Stefan Kaluza Steam Reforming-- Karin Fottinger Biomass to Liquid Biofuels via Heterogeneous Catalysis-- Michael Stocker and Roman Tschentscher Catalytic Pyrolysis of Lignocellulosic Biomass-- K. Seshan Recent Trends in the Purification of H2 Streams by Water-Gas Shift and PROX-- A. Sepulveda-Escribano and J. Silvestre-Albero Index.
  • (source: Nielsen Book Data)
Fuel Production with Heterogeneous Catalysis presents the groundbreaking discoveries, recent developments, and future perspectives of one of the most important areas of renewable energy research-the heterogeneous catalytic production of fuels. Comprised of chapters authored by leading experts in the field, this authoritative text: * Focuses primarily on the state-of-the-art catalysts and catalytic processes anticipated to play a pivotal role in the production of fuels * Describes production of fuels from renewable sources using environmentally friendly technologies * Exposes the advantages and disadvantages of each production process * Suggests solutions to minimize the impact of fuel transportation * Conveys the importance of catalysis for the sustainable production of fuels Fuel Production with Heterogeneous Catalysis delivers a comprehensive overview of the current state of the art of the heterogeneous catalytic production of fuels, providing reaction mechanism schemes, engineering solutions, valuable industry insights, and more.
(source: Nielsen Book Data)
Chemistry & ChemEng Library (Swain)
Status of items at Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) Status
Stacks
TP318 .F835 2015 Unknown
Book
xii, 343 pages : illustrations ; 25 cm
  • Synthesis of Bioactive Heterocyclic Systems Promoted by Silica-Supported Catalysts-- Daniela Lanari and Ornelio Rosati Eco-Benign Synthesis of Indole Derivatives Employing Diverse Heterogeneous Catalysts-- Renuka Jain, Kanti Sharma, and Deepak Kumar Solid Heterogeneous Catalysts Based on Sulfuric Acid and Transition-Metal Salts: Synthesis of Bioactive Heterocycles-- Bahador Karami Heterogeneous Copper-Catalyzed Synthesis of Bioactive Heterocycles-- Xin Lv and Guodong Yuan Silica Sulfuric Acid: A Simple and Powerful Heterogeneous Catalyst in Organic Synthesis-- Sushma S. Kauthale, Sunil U. Tekale, Ambadas B. Rode, Sandeep V. Shinde, K. L. Ameta, and Rajendra P. Pawar Application of Silica-Based Heterogeneous Catalysis for the Synthesis of Bioactive Heterocycles-- Laishram Ronibala Devi and Okram Mukherjee Singh Application of Organometallic Compounds as Heterogeneous Catalysts in Organic Synthesis-- Prachi Rathi, Sudesh Kumar, K. L. Ameta, and Dharma Kishore Ultrasound: An Efficient Tool for the Synthesis of Bioactive Heterocycles-- Essam M. Hussein Nano-Zinc Oxide: An Efficient Heterogeneous Catalyst for the Synthesis of Heterocyclic Compounds-- Sunil U. Tekale, Ambadas B. Rode, K. L. Ameta, and Rajendra P. Pawar Application of Heterogeneous Catalysts for the Synthesis of Bioactive Coumarins-- Lokesh A. Shastri and Manohar V. Kulkarni Silver: A Versatile Heterogeneous Catalyst for Heterocyclic Synthesis-- Chetna Ameta and K. L. Ameta Mesoporous Materials from Novel Silica Source as Heterogeneous Catalyst-- Sujitra Wongkasemjit and Rujirat Longloilert.
  • (source: Nielsen Book Data)
For more than a century, bioactive heterocycles have formed one of the largest areas of research in organic chemistry. They are important from a biological and industrial point of view as well as to the understanding of life processes and efforts to improve the quality of life. Heterogeneous Catalysis: A Versatile Tool for the Synthesis of Bioactive Heterocycles highlights the recent methodologies used in the synthesis of such bioactive systems and focuses on the role of heterogeneous catalysis in the design and synthesis of various biologically active heterocyclic compounds of pharmacological interest. Topics include: * Synthetic protocols for the construction of heterocyclic systems employing silica-bound catalysts * Recent advances in heterogeneous copper-catalyzed reactions for the synthesis of bioactive heterocycles * Features of silica-based heterogeneous catalysts, such as abundance, ease of use, and stability * Ultrasound as an effective tool for accelerating reactions * Organic transformations catalyzed by nano-ZnO as a valuable heterogeneous catalyst * Heterogeneous catalysts employed in the synthesis of coumarins * Heterocyclizations in the presence of silver salts * Home-made organometallic silica sources, known as silatranes Reflecting the focused studies currently conducted in these areas, the book also examines anticancer, antifungal, antibacterial, anti-HIV, anti-inflammatory, antioxidant, and many more biological activities of heterocyclic compounds. It is essential reading for postgraduate and research scholars in the fields of biochemistry, chemical biology, medicinal chemistry and pharmaceutical chemistry.
(source: Nielsen Book Data)
  • Synthesis of Bioactive Heterocyclic Systems Promoted by Silica-Supported Catalysts-- Daniela Lanari and Ornelio Rosati Eco-Benign Synthesis of Indole Derivatives Employing Diverse Heterogeneous Catalysts-- Renuka Jain, Kanti Sharma, and Deepak Kumar Solid Heterogeneous Catalysts Based on Sulfuric Acid and Transition-Metal Salts: Synthesis of Bioactive Heterocycles-- Bahador Karami Heterogeneous Copper-Catalyzed Synthesis of Bioactive Heterocycles-- Xin Lv and Guodong Yuan Silica Sulfuric Acid: A Simple and Powerful Heterogeneous Catalyst in Organic Synthesis-- Sushma S. Kauthale, Sunil U. Tekale, Ambadas B. Rode, Sandeep V. Shinde, K. L. Ameta, and Rajendra P. Pawar Application of Silica-Based Heterogeneous Catalysis for the Synthesis of Bioactive Heterocycles-- Laishram Ronibala Devi and Okram Mukherjee Singh Application of Organometallic Compounds as Heterogeneous Catalysts in Organic Synthesis-- Prachi Rathi, Sudesh Kumar, K. L. Ameta, and Dharma Kishore Ultrasound: An Efficient Tool for the Synthesis of Bioactive Heterocycles-- Essam M. Hussein Nano-Zinc Oxide: An Efficient Heterogeneous Catalyst for the Synthesis of Heterocyclic Compounds-- Sunil U. Tekale, Ambadas B. Rode, K. L. Ameta, and Rajendra P. Pawar Application of Heterogeneous Catalysts for the Synthesis of Bioactive Coumarins-- Lokesh A. Shastri and Manohar V. Kulkarni Silver: A Versatile Heterogeneous Catalyst for Heterocyclic Synthesis-- Chetna Ameta and K. L. Ameta Mesoporous Materials from Novel Silica Source as Heterogeneous Catalyst-- Sujitra Wongkasemjit and Rujirat Longloilert.
  • (source: Nielsen Book Data)
For more than a century, bioactive heterocycles have formed one of the largest areas of research in organic chemistry. They are important from a biological and industrial point of view as well as to the understanding of life processes and efforts to improve the quality of life. Heterogeneous Catalysis: A Versatile Tool for the Synthesis of Bioactive Heterocycles highlights the recent methodologies used in the synthesis of such bioactive systems and focuses on the role of heterogeneous catalysis in the design and synthesis of various biologically active heterocyclic compounds of pharmacological interest. Topics include: * Synthetic protocols for the construction of heterocyclic systems employing silica-bound catalysts * Recent advances in heterogeneous copper-catalyzed reactions for the synthesis of bioactive heterocycles * Features of silica-based heterogeneous catalysts, such as abundance, ease of use, and stability * Ultrasound as an effective tool for accelerating reactions * Organic transformations catalyzed by nano-ZnO as a valuable heterogeneous catalyst * Heterogeneous catalysts employed in the synthesis of coumarins * Heterocyclizations in the presence of silver salts * Home-made organometallic silica sources, known as silatranes Reflecting the focused studies currently conducted in these areas, the book also examines anticancer, antifungal, antibacterial, anti-HIV, anti-inflammatory, antioxidant, and many more biological activities of heterocyclic compounds. It is essential reading for postgraduate and research scholars in the fields of biochemistry, chemical biology, medicinal chemistry and pharmaceutical chemistry.
(source: Nielsen Book Data)
Chemistry & ChemEng Library (Swain)
Status of items at Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) Status
Stacks
QD505 .H462 2015 Unknown
Book
xv, 326 pages, 16 unnumbered pages of plates : illustrations (some color) ; 24 cm
This book presents both the fundamentals concepts and latestachievements of a field that is growing in importance since itrepresents a possible solution for global energy problems. It focuses on an atomic-level understanding ofheterogeneous catalysis involved in important energy conversionprocesses. It presents a concise picture for the entire areaof heterogeneous catalysis with vision at the atomic- and nano-scales, from synthesis, ex-situ and in-situ characterization, catalytic activity and selectivity, to mechanistic understandingbased on experimental exploration and theoretical simulation. The book: * Addresses heterogeneous catalysis, one of the crucialtechnologies employed within the chemical and energyindustries * Presents the recent advances in the synthesis andcharacterization of nanocatalysts as well as a mechanisticunderstanding of catalysis at atomic level for important processesof energy conversion * Provides a foundation for the potential design ofrevolutionarily new technical catalysts and thus the furtherdevelopment of efficient technologies for the global energyeconomy * Includes both theoretical studies and experimentalexploration * Is useful as both a textbook for graduate and undergraduatestudents and a reference book for scientists and engineers inchemistry, materials science, and chemical engineering.
(source: Nielsen Book Data)
This book presents both the fundamentals concepts and latestachievements of a field that is growing in importance since itrepresents a possible solution for global energy problems. It focuses on an atomic-level understanding ofheterogeneous catalysis involved in important energy conversionprocesses. It presents a concise picture for the entire areaof heterogeneous catalysis with vision at the atomic- and nano-scales, from synthesis, ex-situ and in-situ characterization, catalytic activity and selectivity, to mechanistic understandingbased on experimental exploration and theoretical simulation. The book: * Addresses heterogeneous catalysis, one of the crucialtechnologies employed within the chemical and energyindustries * Presents the recent advances in the synthesis andcharacterization of nanocatalysts as well as a mechanisticunderstanding of catalysis at atomic level for important processesof energy conversion * Provides a foundation for the potential design ofrevolutionarily new technical catalysts and thus the furtherdevelopment of efficient technologies for the global energyeconomy * Includes both theoretical studies and experimentalexploration * Is useful as both a textbook for graduate and undergraduatestudents and a reference book for scientists and engineers inchemistry, materials science, and chemical engineering.
(source: Nielsen Book Data)
Chemistry & ChemEng Library (Swain)
Status of items at Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) Status
Stacks
QD505 .T36 2015 Unknown
Book
xvi, 507 pages : illustrations ; 29 cm
Addressing a dynamic aspect of organic chemistry, this book describes synthetic strategies and applications for multicomponent reactions including key routes for synthesizing complex molecules. Illustrates the crucial role and the important utility of multicomponent reactions (MCRs) to organic syntheses Compiles novel and efficient synthetic multicomponent procedures to give readers a complete picture of this class of organic reactions Helps readers to design efficient and practical transformations using multicomponent reaction strategies Describes reaction background, applications to synthesize complex molecules and drugs, and reaction mechanisms.
(source: Nielsen Book Data)
Addressing a dynamic aspect of organic chemistry, this book describes synthetic strategies and applications for multicomponent reactions including key routes for synthesizing complex molecules. Illustrates the crucial role and the important utility of multicomponent reactions (MCRs) to organic syntheses Compiles novel and efficient synthetic multicomponent procedures to give readers a complete picture of this class of organic reactions Helps readers to design efficient and practical transformations using multicomponent reaction strategies Describes reaction background, applications to synthesize complex molecules and drugs, and reaction mechanisms.
(source: Nielsen Book Data)
Chemistry & ChemEng Library (Swain)
Status of items at Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) Status
Stacks
QD501 .M868 2015 Unknown
Book
xviii, 410 p. : ill. ; 25 cm
  • Part 1. Organometallic Compounds of Main Group Elements -- 1.1 General and bonding considerations -- 1.2 Alkali metal organometallics: lithium -- 1.3 Organometallic compounds of alkaline earth metals -- 1.4 Zinc, cadmium and mercury -- 1.5 Organometallic compounds of the boron group -- 1.6 Organometallic compounds of the carbon group -- Part 2. Organometallic Compounds of Transition Metals -- 2.1 Ligand types -- 2.2 Common types of organometallic complexes -- 2.3 Electron counting and the 16/18-electron rule -- 2.4 Ligand properties and metal-ligand bonding -- 2.5 L-type *p-acceptor ligands : metal carbonyl complexes -- 2.6 L-type *p-acceptor ligands: alkenes, dienes and alkynes -- 2.7 LX- and L2X-type *p-acceptor ligands: allyl and enyl complexes -- 2.8 L2X-type *p-acceptor ligands: metallocene complexes -- 2.9 Arene complexes -- 2.10 Sigma complexes -- 2.11 Complexes with M-C *s-bonds -- 2.12 Alkylidene complexes -- 2.13 Complexes with MC triple bonds: carbynes -- Part 3. Homogeneous Catalysis with Organometallic Transition Metal Complexes -- 3.1 General considerations -- 3.2 Key reaction steps in homogeneous catalysis -- 3.3 Catalytic H-H and H-X additions -- 3.4 Catalytic carbonylations -- 3.5 Alkene oxidations -- 3.6 Coupling reactions -- 3.7 Alkene polymerizations -- Appendix 1 Commonly used solvents and their properties -- Appendix 2 Number and symmetry of infrared-active vibrations of metal carbonyl complexes -- Appendix 3 Answers to exercises -- Appendix 4 Further reading.
  • (source: Nielsen Book Data)
Organometallic chemistry explores the chemistry of the often bewildering variety of compounds featuring metal-carbon bonds. A field that has underpinned the development of new synthetic methods and materials, it is also central to our understanding of catalysis. In his text, Manfred Bochmann distils the extensive knowledge of the field into a succinct overview of essential concepts. The book is enriched throughout with examples that demonstrate how our understanding of organometallic chemistry has led to new applications in research and industry - not least in relation to catalysis - and an extensive reaction schemes and structures give added clarity to the concepts being explained. Striking just the right balance between breadth and depth - and with features throughout to support the learning process - Organometallics and Catalysis is the perfect introduction for undergraduate and graduate students who need a thorough grounding on the subject or are embarking on new research areas. Online Resource Centre: The Online Resource Centre to accompany Organometallics and Catalysis: An Introduction features: For registered adopters of the text: - Figures from the book in electronic format For everyone: - Curated links to relevant video materials on YouTube.
(source: Nielsen Book Data)
  • Part 1. Organometallic Compounds of Main Group Elements -- 1.1 General and bonding considerations -- 1.2 Alkali metal organometallics: lithium -- 1.3 Organometallic compounds of alkaline earth metals -- 1.4 Zinc, cadmium and mercury -- 1.5 Organometallic compounds of the boron group -- 1.6 Organometallic compounds of the carbon group -- Part 2. Organometallic Compounds of Transition Metals -- 2.1 Ligand types -- 2.2 Common types of organometallic complexes -- 2.3 Electron counting and the 16/18-electron rule -- 2.4 Ligand properties and metal-ligand bonding -- 2.5 L-type *p-acceptor ligands : metal carbonyl complexes -- 2.6 L-type *p-acceptor ligands: alkenes, dienes and alkynes -- 2.7 LX- and L2X-type *p-acceptor ligands: allyl and enyl complexes -- 2.8 L2X-type *p-acceptor ligands: metallocene complexes -- 2.9 Arene complexes -- 2.10 Sigma complexes -- 2.11 Complexes with M-C *s-bonds -- 2.12 Alkylidene complexes -- 2.13 Complexes with MC triple bonds: carbynes -- Part 3. Homogeneous Catalysis with Organometallic Transition Metal Complexes -- 3.1 General considerations -- 3.2 Key reaction steps in homogeneous catalysis -- 3.3 Catalytic H-H and H-X additions -- 3.4 Catalytic carbonylations -- 3.5 Alkene oxidations -- 3.6 Coupling reactions -- 3.7 Alkene polymerizations -- Appendix 1 Commonly used solvents and their properties -- Appendix 2 Number and symmetry of infrared-active vibrations of metal carbonyl complexes -- Appendix 3 Answers to exercises -- Appendix 4 Further reading.
  • (source: Nielsen Book Data)
Organometallic chemistry explores the chemistry of the often bewildering variety of compounds featuring metal-carbon bonds. A field that has underpinned the development of new synthetic methods and materials, it is also central to our understanding of catalysis. In his text, Manfred Bochmann distils the extensive knowledge of the field into a succinct overview of essential concepts. The book is enriched throughout with examples that demonstrate how our understanding of organometallic chemistry has led to new applications in research and industry - not least in relation to catalysis - and an extensive reaction schemes and structures give added clarity to the concepts being explained. Striking just the right balance between breadth and depth - and with features throughout to support the learning process - Organometallics and Catalysis is the perfect introduction for undergraduate and graduate students who need a thorough grounding on the subject or are embarking on new research areas. Online Resource Centre: The Online Resource Centre to accompany Organometallics and Catalysis: An Introduction features: For registered adopters of the text: - Figures from the book in electronic format For everyone: - Curated links to relevant video materials on YouTube.
(source: Nielsen Book Data)
Chemistry & ChemEng Library (Swain)
Status of items at Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) Status
Stacks
QD411 .B63 2015 Unknown
Book
xx, 744 p. : ill. (some col.) ; 25 cm
  • Preface XIX 1 Setting the Scene 1 1.1 Prologue: Advances since the Early 1990s 1 1.2 Introduction 13 1.3 Perspectives in Catalysis: Past, Present and Future 16 1.4 Definition of Catalytic Activity 32 1.5 Key Advances in Recent Theoretical Treatments: Universability in Heterogeneous Catalysis 52 1.6 Milestones Reached in Industrial Catalysis in the Twentieth Century, and Some Consequential Challenges 54 Problems 61 References 64 Further Reading 66 2 The Fundamentals of Adsorption: Structural and Dynamical Considerations, Isotherms and Energetics 67 2.1 Catalysis Must Always Be Preceded by Adsorption 67 2.2 The Surfaces of Clean Solids are Sometimes Reconstructed 71 2.3 There Are Many Well-Defined Kinds of Ordered Adlayers 74 2.4 Adsorption Isotherms and Isobars 79 2.5 Dynamical Considerations 86 2.6 Relating the Activation Energy to the Energy of Chemisorption. Universality in Heterogeneous Catalysis and the Bronsted Evans Polanyi (BEP) Relation 101 2.7 Deriving Adsorption Isotherms from Kinetic Principles 105 2.8 Energetics of Adsorption 113 2.9 Mobility at Surfaces 126 2.10 Kinetics of Surface Reactions 127 2.11 Autocatalytic, Oscillatory and Complex Heterogeneous Reactions 132 2.12 Microkinetics: A Summary 147 Problems 155 References 161 Further Reading 162 3 The Characterization of Industrial and Model Solid Catalysts 163 Part I: Characterization of Industrial Solid Catalysts 163 3.1 Non-invasive Methods Suitable for Studies Involving Catalytic Reactors 164 Part II: Laboratory Characterization of Solid Catalysts 172 3.2 A Portfolio of Modern Methods: Introducing the Acronyms 172 3.3 Which Elements and Which Phases Are Present? 175 3.4 Probing Surfaces with IR, HREELS, AES and XPS 184 3.5 Ultraviolet Visible and Photoluminescence Spectroscopy 191 3.6 Structure and Crystallography of Surfaces: Nature of Ordered and Reconstructed Surfaces 193 3.7 Other Structural Techniques for Characterizing Bulk and Surfaces of Catalysts 214 3.8 A Miscellany of Other Procedures 258 3.9 Determining the Strength of Surface Bonds: Thermal and Other Temperature-Programmed Methods 259 3.10 Reflections on the Current Scene Pertaining In situ Methods of Studying Catalysts 265 Problems 281 References 288 Further Reading 291 General 291 Additional 291 In situ Techniques 291 4 Porous Catalysts: Their Nature and Importance 293 4.1 Definitions and Introduction 293 4.2 Determination of Surface Area 296 4.3 Mercury Porosimetry 306 4.4 Wheeler s Semi-empirical Pore Model 308 4.5 Diffusion in Porous Catalysts 314 4.6 Chemical Reaction in Porous Catalyst Pellets 319 Problems 337 References 340 Further Reading 341 Specific Books 342 General 342 5 Solid State Chemical Aspects of Heterogeneous Catalysts 343 5.1 Recent Advances in Our Knowledge of Some Metal Catalysts: In Their Extended, Cluster or Nanoparticle States 345 5.2 Comments on the Catalytic Behaviour of Nanogold 352 5.3 Recent Advances in the Elucidation of Certain Metal-Oxide Catalysts 359 5.4 Atomic-Scale Edge Structures in Industrial-Style MoS2 Nanocatalysts 363 5.5 Open-Structure Catalysts: from 2D to 3D 364 5.6 Computational Approaches 376 5.7 A Chemist s Guide to the Electronic Structure of Solids and Their Surfaces 389 5.8 Key Advances in Recent Theoretical Treatments of Heterogeneous Catalysis 415 5.9 Selected Applications of DFT to Catalysis 419 5.10 Concluding Remarks Concerning DFT Calculations in Heterogeneous Catalysis 429 Problems 430 References 433 Key References Published Since the First Edition 436 Seminal Books 436 Monographs 437 Book Chapters 437 Further Reading 437 6 Poisoning, Promotion, Deactivation and Selectivity of Catalysts 439 6.1 Background 439 6.2 Catalyst Deactivation 452 6.3 Some Modern Theories of Poisoning and Promotion 463 Problems 474 References 477 Further Reading 477 General 477 Studies of Model Surfaces 477 Theory of Poisoning and Promotion 478 7 Catalytic Process Engineering 479 Part I: Recent Advances in Reactor Design 479 7.1 Novel Operating Strategies 482 Part II: Traditional Methods of Catalytic Process Engineering 499 7.2 Traditional Catalytic Reactors 499 Problems 534 References 538 General References for Part II 539 General 539 Kinetic Models 539 Experimental Chemical Reactor Configurations 540 Slurry Reactors 540 Further Reading 540 8 Heterogeneous Catalysis: Examples, Case Histories and Current Trends 541 8.1 Synthesis of Methanol 541 8.2 Fischer Tropsch Catalysis 546 8.3 Synthesis of Ammonia 568 8.4 Oxidation of Ammonia: Stepping Toward the Fertilizer Industry 588 8.5 In situ Catalytic Reaction and Separation 592 8.6 Automobile Exhaust Catalysts and the Catalytic Monolith 601 8.7 Photocatalytic Breakdown of Water and the Harnessing of Solar Energy 614 8.8 Catalytic Processes in the Petroleum Industry 629 References 651 Further Reading 653 9 Powering the Planet in a Sustainable Manner: Some of Tomorrow s Catalysts (Actual and Desired) and Key Catalytic Features Pertaining to Renewable Feedstocks, Green Chemistry and Clean Technology 655 9.1 Introduction 655 Part I: Prospects, Practices and Principles of Generating Solar Fuels 658 9.2 Powering the Planet with Solar Fuel 658 9.3 Some Significant Advances in Photo-Assisted Water Splitting and Allied Phenomena 659 9.4 The Hydrogen Economy 677 9.4.1 The Methanol Economy 682 Part II: Current Practices in Powering the Planet and Producing Chemicals 685 9.5 Some of Tomorrow s Catalysts: Actual and Desired 685 9.6 A Biorefinery Capable of Producing Transportation Fuels and Commodity Chemicals that Starts with Metabolic Engineering and Ends with Inorganic Solid Catalysts 707 9.7 Non-enzymatic Catalytic Processing of Biomass-Derived Raw Materials to Selected Chemical Products 711 9.8 Strategies for the Design of New Catalysts 719 Part III:Thermochemical Cycles and High-Flux, Solar-Driven Conversions 724 9.9 Solar-Driven, Catalysed Thermochemical Reactions as Alternatives to Fossil-Fuel-Based Energy and Chemical Economies 724 Acknowledgements 726 Problems 726 References 729 Further Reading 732 Index 733.
  • (source: Nielsen Book Data)
This long-awaited second edition of the successful introduction to the fundamentals of heterogeneous catalysis is now completely revised and updated. Written by internationally acclaimed experts, this textbook includes fundamentals of adsorption, characterizing catalysts and their surfaces, the significance of pore structure and surface area, solid-state and surface chemistry, poisoning, promotion, deactivation and selectivity of catalysts, as well as catalytic process engineering. A final section provides a number of examples and case histories. With its color and numerous graphics plus references to help readers to easily find further reading, this is a pivotal work for an understanding of the principles involved.
(source: Nielsen Book Data)
  • Preface XIX 1 Setting the Scene 1 1.1 Prologue: Advances since the Early 1990s 1 1.2 Introduction 13 1.3 Perspectives in Catalysis: Past, Present and Future 16 1.4 Definition of Catalytic Activity 32 1.5 Key Advances in Recent Theoretical Treatments: Universability in Heterogeneous Catalysis 52 1.6 Milestones Reached in Industrial Catalysis in the Twentieth Century, and Some Consequential Challenges 54 Problems 61 References 64 Further Reading 66 2 The Fundamentals of Adsorption: Structural and Dynamical Considerations, Isotherms and Energetics 67 2.1 Catalysis Must Always Be Preceded by Adsorption 67 2.2 The Surfaces of Clean Solids are Sometimes Reconstructed 71 2.3 There Are Many Well-Defined Kinds of Ordered Adlayers 74 2.4 Adsorption Isotherms and Isobars 79 2.5 Dynamical Considerations 86 2.6 Relating the Activation Energy to the Energy of Chemisorption. Universality in Heterogeneous Catalysis and the Bronsted Evans Polanyi (BEP) Relation 101 2.7 Deriving Adsorption Isotherms from Kinetic Principles 105 2.8 Energetics of Adsorption 113 2.9 Mobility at Surfaces 126 2.10 Kinetics of Surface Reactions 127 2.11 Autocatalytic, Oscillatory and Complex Heterogeneous Reactions 132 2.12 Microkinetics: A Summary 147 Problems 155 References 161 Further Reading 162 3 The Characterization of Industrial and Model Solid Catalysts 163 Part I: Characterization of Industrial Solid Catalysts 163 3.1 Non-invasive Methods Suitable for Studies Involving Catalytic Reactors 164 Part II: Laboratory Characterization of Solid Catalysts 172 3.2 A Portfolio of Modern Methods: Introducing the Acronyms 172 3.3 Which Elements and Which Phases Are Present? 175 3.4 Probing Surfaces with IR, HREELS, AES and XPS 184 3.5 Ultraviolet Visible and Photoluminescence Spectroscopy 191 3.6 Structure and Crystallography of Surfaces: Nature of Ordered and Reconstructed Surfaces 193 3.7 Other Structural Techniques for Characterizing Bulk and Surfaces of Catalysts 214 3.8 A Miscellany of Other Procedures 258 3.9 Determining the Strength of Surface Bonds: Thermal and Other Temperature-Programmed Methods 259 3.10 Reflections on the Current Scene Pertaining In situ Methods of Studying Catalysts 265 Problems 281 References 288 Further Reading 291 General 291 Additional 291 In situ Techniques 291 4 Porous Catalysts: Their Nature and Importance 293 4.1 Definitions and Introduction 293 4.2 Determination of Surface Area 296 4.3 Mercury Porosimetry 306 4.4 Wheeler s Semi-empirical Pore Model 308 4.5 Diffusion in Porous Catalysts 314 4.6 Chemical Reaction in Porous Catalyst Pellets 319 Problems 337 References 340 Further Reading 341 Specific Books 342 General 342 5 Solid State Chemical Aspects of Heterogeneous Catalysts 343 5.1 Recent Advances in Our Knowledge of Some Metal Catalysts: In Their Extended, Cluster or Nanoparticle States 345 5.2 Comments on the Catalytic Behaviour of Nanogold 352 5.3 Recent Advances in the Elucidation of Certain Metal-Oxide Catalysts 359 5.4 Atomic-Scale Edge Structures in Industrial-Style MoS2 Nanocatalysts 363 5.5 Open-Structure Catalysts: from 2D to 3D 364 5.6 Computational Approaches 376 5.7 A Chemist s Guide to the Electronic Structure of Solids and Their Surfaces 389 5.8 Key Advances in Recent Theoretical Treatments of Heterogeneous Catalysis 415 5.9 Selected Applications of DFT to Catalysis 419 5.10 Concluding Remarks Concerning DFT Calculations in Heterogeneous Catalysis 429 Problems 430 References 433 Key References Published Since the First Edition 436 Seminal Books 436 Monographs 437 Book Chapters 437 Further Reading 437 6 Poisoning, Promotion, Deactivation and Selectivity of Catalysts 439 6.1 Background 439 6.2 Catalyst Deactivation 452 6.3 Some Modern Theories of Poisoning and Promotion 463 Problems 474 References 477 Further Reading 477 General 477 Studies of Model Surfaces 477 Theory of Poisoning and Promotion 478 7 Catalytic Process Engineering 479 Part I: Recent Advances in Reactor Design 479 7.1 Novel Operating Strategies 482 Part II: Traditional Methods of Catalytic Process Engineering 499 7.2 Traditional Catalytic Reactors 499 Problems 534 References 538 General References for Part II 539 General 539 Kinetic Models 539 Experimental Chemical Reactor Configurations 540 Slurry Reactors 540 Further Reading 540 8 Heterogeneous Catalysis: Examples, Case Histories and Current Trends 541 8.1 Synthesis of Methanol 541 8.2 Fischer Tropsch Catalysis 546 8.3 Synthesis of Ammonia 568 8.4 Oxidation of Ammonia: Stepping Toward the Fertilizer Industry 588 8.5 In situ Catalytic Reaction and Separation 592 8.6 Automobile Exhaust Catalysts and the Catalytic Monolith 601 8.7 Photocatalytic Breakdown of Water and the Harnessing of Solar Energy 614 8.8 Catalytic Processes in the Petroleum Industry 629 References 651 Further Reading 653 9 Powering the Planet in a Sustainable Manner: Some of Tomorrow s Catalysts (Actual and Desired) and Key Catalytic Features Pertaining to Renewable Feedstocks, Green Chemistry and Clean Technology 655 9.1 Introduction 655 Part I: Prospects, Practices and Principles of Generating Solar Fuels 658 9.2 Powering the Planet with Solar Fuel 658 9.3 Some Significant Advances in Photo-Assisted Water Splitting and Allied Phenomena 659 9.4 The Hydrogen Economy 677 9.4.1 The Methanol Economy 682 Part II: Current Practices in Powering the Planet and Producing Chemicals 685 9.5 Some of Tomorrow s Catalysts: Actual and Desired 685 9.6 A Biorefinery Capable of Producing Transportation Fuels and Commodity Chemicals that Starts with Metabolic Engineering and Ends with Inorganic Solid Catalysts 707 9.7 Non-enzymatic Catalytic Processing of Biomass-Derived Raw Materials to Selected Chemical Products 711 9.8 Strategies for the Design of New Catalysts 719 Part III:Thermochemical Cycles and High-Flux, Solar-Driven Conversions 724 9.9 Solar-Driven, Catalysed Thermochemical Reactions as Alternatives to Fossil-Fuel-Based Energy and Chemical Economies 724 Acknowledgements 726 Problems 726 References 729 Further Reading 732 Index 733.
  • (source: Nielsen Book Data)
This long-awaited second edition of the successful introduction to the fundamentals of heterogeneous catalysis is now completely revised and updated. Written by internationally acclaimed experts, this textbook includes fundamentals of adsorption, characterizing catalysts and their surfaces, the significance of pore structure and surface area, solid-state and surface chemistry, poisoning, promotion, deactivation and selectivity of catalysts, as well as catalytic process engineering. A final section provides a number of examples and case histories. With its color and numerous graphics plus references to help readers to easily find further reading, this is a pivotal work for an understanding of the principles involved.
(source: Nielsen Book Data)
Chemistry & ChemEng Library (Swain)
Status of items at Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) Status
Stacks
QD505 .T495 2015 Unknown
Book
xi, 745 pages : illustrations ; 29 cm
  • 1 Catalytic conversion of methane to synthesis gas byCO2 reforming 1 2 Catalytic conversion of methane to synthesis gas by partialoxidation 79 3 Catalytic combustion of clean as well as nitrogen bound fuelsover transitional metal oxides 139 4 Zeolites and their applications as catalysts and/or catalystsupports 223 5 Synthesis of mesoporous V-Mg-O oxides and their applicationsas catalysts 365 6 Synthesis of polymer supported catalysts and polymer-coatedsilica supports and their applications in catalysis 404 7 Metal sintering during heating in various atmospheres 473 8 Heterogeneous catalysis a theoretical approach 667.
  • (source: Nielsen Book Data)
Consolidating a collection of papers that Professor Eli Ruckensteinand his co-workers have published over the past four decades, Heterogeneous Catalysis Contributions to Experimental andTheoretical Studies addresses catalysts involved in reactionssuch as methane CO2 reforming, methane partial oxidation, andcatalytic combustion. Each chapter opens with an introductionsummarizing the papers included in the chapter and highlights therelevance of the chemistry to todays R&D. This valuableresource for catalytic and material scientists and graduatestudents paves the way to help develop new chemicals and materials.
(source: Nielsen Book Data)
  • 1 Catalytic conversion of methane to synthesis gas byCO2 reforming 1 2 Catalytic conversion of methane to synthesis gas by partialoxidation 79 3 Catalytic combustion of clean as well as nitrogen bound fuelsover transitional metal oxides 139 4 Zeolites and their applications as catalysts and/or catalystsupports 223 5 Synthesis of mesoporous V-Mg-O oxides and their applicationsas catalysts 365 6 Synthesis of polymer supported catalysts and polymer-coatedsilica supports and their applications in catalysis 404 7 Metal sintering during heating in various atmospheres 473 8 Heterogeneous catalysis a theoretical approach 667.
  • (source: Nielsen Book Data)
Consolidating a collection of papers that Professor Eli Ruckensteinand his co-workers have published over the past four decades, Heterogeneous Catalysis Contributions to Experimental andTheoretical Studies addresses catalysts involved in reactionssuch as methane CO2 reforming, methane partial oxidation, andcatalytic combustion. Each chapter opens with an introductionsummarizing the papers included in the chapter and highlights therelevance of the chemistry to todays R&D. This valuableresource for catalytic and material scientists and graduatestudents paves the way to help develop new chemicals and materials.
(source: Nielsen Book Data)
Chemistry & ChemEng Library (Swain)
Status of items at Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) Status
Stacks
QD505 .R83 2014 Unknown
Book
xxii, 872 pages : illustrations ; 26 cm
  • Development of Ammonia Synthesis Catalysts-- Catalytic Reaction Mechanism For Ammonia Synthesis-- Chemical Composition and Structure of Fused Iron Catalysts-- Preparation of Iron Catalysts-- Reduction of Fused Iron Catalyst-- Ruthenium Catalysts-- Performance Evaluation and Characterization of Catalysts-- Performance and Application of Catalysts-- Effect of Catalysts Performance On Economic Benefit of Catalytic Process-- Outlook and Innovation.
  • (source: Nielsen Book Data)
This book provides a review of worldwide developments in ammonia synthesis catalysts over the last 30 years. It focuses on the new generation of Fe1-xO based catalysts and ruthenium catalysts - both are major breakthroughs for fused iron catalysts. The basic theory for ammonia synthesis is systematically explained, covering topics such as the chemical components, crystal structure, preparation, reduction, performance evaluation, characterization of the catalysts, the mechanism and kinetics of ammonia synthesis reaction. Both theory and practice are combined in this presentation, with emphasis on the research methods, application and exploitation of catalysts. The comprehensive volume includes an assessment of the economic and engineering aspects of ammonia plants based on the performance of catalysts. Recent developments in photo-catalysis, electro-catalysis, biocatalysis and new uses of ammonia are also introduced in this book.
(source: Nielsen Book Data)
  • Development of Ammonia Synthesis Catalysts-- Catalytic Reaction Mechanism For Ammonia Synthesis-- Chemical Composition and Structure of Fused Iron Catalysts-- Preparation of Iron Catalysts-- Reduction of Fused Iron Catalyst-- Ruthenium Catalysts-- Performance Evaluation and Characterization of Catalysts-- Performance and Application of Catalysts-- Effect of Catalysts Performance On Economic Benefit of Catalytic Process-- Outlook and Innovation.
  • (source: Nielsen Book Data)
This book provides a review of worldwide developments in ammonia synthesis catalysts over the last 30 years. It focuses on the new generation of Fe1-xO based catalysts and ruthenium catalysts - both are major breakthroughs for fused iron catalysts. The basic theory for ammonia synthesis is systematically explained, covering topics such as the chemical components, crystal structure, preparation, reduction, performance evaluation, characterization of the catalysts, the mechanism and kinetics of ammonia synthesis reaction. Both theory and practice are combined in this presentation, with emphasis on the research methods, application and exploitation of catalysts. The comprehensive volume includes an assessment of the economic and engineering aspects of ammonia plants based on the performance of catalysts. Recent developments in photo-catalysis, electro-catalysis, biocatalysis and new uses of ammonia are also introduced in this book.
(source: Nielsen Book Data)
Chemistry & ChemEng Library (Swain)
Status of items at Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) Status
Stacks
TP223 .L58 2013 Unknown
Book
xi, 364 pages : illustrations (some color) ; 24 cm.
With well over 90 per cent of all processes in the industrial chemical production being of catalytic nature, catalysis is a mature though ever interesting topic. The idea of this book is to tackle various aspects of heterogeneous catalysis from the engineering point of view and go all the way from engineering of catalysis, catalyst preparation, characterization, reaction kinetics, mass transfer to catalytic reactors and the implementation of catalysts in chemical technology. Aimed for graduate students it is also a useful resource for professionals coming from the more academic side.
(source: Nielsen Book Data)
With well over 90 per cent of all processes in the industrial chemical production being of catalytic nature, catalysis is a mature though ever interesting topic. The idea of this book is to tackle various aspects of heterogeneous catalysis from the engineering point of view and go all the way from engineering of catalysis, catalyst preparation, characterization, reaction kinetics, mass transfer to catalytic reactors and the implementation of catalysts in chemical technology. Aimed for graduate students it is also a useful resource for professionals coming from the more academic side.
(source: Nielsen Book Data)
Chemistry & ChemEng Library (Swain)
Status of items at Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) Status
Stacks
TP156 .C35 M87 2013 Unknown
Book
xviii, 356 p. : ill. ; 25 cm.
  • Preface vii Contributors ix About the Authors xi 1 Transition Metal Catalysis in the Pharmaceutical Industry 1 Carl A. Busacca, Daniel R. Fandrick, Jinhua J. Song, and Chris H. Senanayake (Boehringer Ingelheim Pharmaceuticals) 2 Selected Applications of Transition Metal-Catalyzed Carbon--Carbon Cross-Coupling Reactions in the Pharmaceutical Industry 25 Hong C. Shen (Roche) 3 Selected Applications of Pd- and Cu-Catalyzed Carbon--Heteroatom Cross-Coupling Reactions in the Pharmaceutical Industry 97 Jingjun Yin (Merck) 4 Asymmetric Cross-Coupling Reactions 165 Vince Yeh (Novartis) and William A. Szabo (Consultant in Drug Development) 5 Metathesis Reactions 215 Oliver R. Thiel (Amgen) 6 Transition Metal-Catalyzed Synthesis of Five- and Six-Membered Heterocycles 257 Cheol K. Chung (Merck) and Matthew L. Crawley (Main Line Health) 7 Oxidative Catalysis 277 Lamont Terrell (GlaxoSmithKline) 8 Industrial Asymmetric Hydrogenation 315 Hans-Ulrich Blaser (Solvias) Index 343.
  • (source: Nielsen Book Data)
This book focuses on the drug discovery and development applications of transition metal catalyzed processes, which can efficiently create preclinical and clinical drug candidates as well as marketed drugs. The authors pay particular attention to the challenges of transitioning academically-developed reactions into scalable industrial processes. Additionally, the book lays the groundwork for how continued development of transition metal catalyzed processes can deliver new drug candidates. This work provides a unique perspective on the applications of transition metal catalysis in drug discovery and development -- it is a guide, a historical prospective, a practical compendium, and a source of future direction for the field.
(source: Nielsen Book Data)
  • Preface vii Contributors ix About the Authors xi 1 Transition Metal Catalysis in the Pharmaceutical Industry 1 Carl A. Busacca, Daniel R. Fandrick, Jinhua J. Song, and Chris H. Senanayake (Boehringer Ingelheim Pharmaceuticals) 2 Selected Applications of Transition Metal-Catalyzed Carbon--Carbon Cross-Coupling Reactions in the Pharmaceutical Industry 25 Hong C. Shen (Roche) 3 Selected Applications of Pd- and Cu-Catalyzed Carbon--Heteroatom Cross-Coupling Reactions in the Pharmaceutical Industry 97 Jingjun Yin (Merck) 4 Asymmetric Cross-Coupling Reactions 165 Vince Yeh (Novartis) and William A. Szabo (Consultant in Drug Development) 5 Metathesis Reactions 215 Oliver R. Thiel (Amgen) 6 Transition Metal-Catalyzed Synthesis of Five- and Six-Membered Heterocycles 257 Cheol K. Chung (Merck) and Matthew L. Crawley (Main Line Health) 7 Oxidative Catalysis 277 Lamont Terrell (GlaxoSmithKline) 8 Industrial Asymmetric Hydrogenation 315 Hans-Ulrich Blaser (Solvias) Index 343.
  • (source: Nielsen Book Data)
This book focuses on the drug discovery and development applications of transition metal catalyzed processes, which can efficiently create preclinical and clinical drug candidates as well as marketed drugs. The authors pay particular attention to the challenges of transitioning academically-developed reactions into scalable industrial processes. Additionally, the book lays the groundwork for how continued development of transition metal catalyzed processes can deliver new drug candidates. This work provides a unique perspective on the applications of transition metal catalysis in drug discovery and development -- it is a guide, a historical prospective, a practical compendium, and a source of future direction for the field.
(source: Nielsen Book Data)
Chemistry & ChemEng Library (Swain)
Status of items at Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) Status
Stacks
RM301.25 .A675 2012 Unknown
Book
volumes : illustrations ; 23 cm.
  • 1. Lewis base and acid catalysts
  • 2. Brønsted base and acid catalysts, and additional topics / volume editor: K. Maruoka.
  • 1. Lewis base and acid catalysts
  • 2. Brønsted base and acid catalysts, and additional topics / volume editor: K. Maruoka.
Chemistry & ChemEng Library (Swain)
Status of items at Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) Status
Reference (non-circulating)
QD262 .S354 2011/5 In-library use
QD262 .S354 2011/6 In-library use
Book
xvii, 456 p. : ill. ; 24 cm.
  • Preface INTRODUCTION The Beginnings of Catalytic Research The Catalysis Definitions of Berzelius and Ostwald PRINCIPLES OF ORGANOMETALLIC CATALYSIS Homogeneous versus Heterogeneous Catalysis Catalytic Cycles Activity and Productivity of Catalysts Selectivity and Specificity of Catalysts Determination of Catalytic Mechanisms Glossary for Catalysis The Development of Organometallic Catalysis ELEMENTARY STEPS IN ORGANOMETALLIC CATALYSIS Cleavage and Coordination of Ligands Oxidative Addition and Reductive Elimination Oxidative Coupling and Reductive Cleavage Olefin Insertion and Beta-Hydrogen Elimination Alpha-Hydrogen Elimination and Carbene Insertion Reactions Addition of Nucleophiles and Heterolytic Fragmentation Insertion and Extrusion of CO One-Electron Reduction and Oxidation HYDROGENATION OF OLEFINS Introduction The Wilkinson Catalyst Enantioselective Hydrogenation Dihydrogen Complexes and H2 Activation Transfer Hydrogenation HYDROFORMYLATION OF OLEFINS AND FISCHER-TROPSCH SYNTHESIS Cobalt Catalysts Phosphane-Modified Rhodium Catalysts Enantioselective Hydroformylation Significance of Hydroformylation and Outlook The Fischer-Tropsch Synthesis CARBONYLATION OF METHANOL AND WATER-GAS SHIFT REACTION Principles The Monsanto Process Synthesis of Acetic Anhydride The Cativa Process Water-Gas Shift Reaction and Carbon Monoxide Dehydrogenases METATHESIS Metathesis of Olefins Metathesis of Alkynes Enyne Metathesis Delta-Bond Metathesis Metathesis of Alanes OLIGOMERIZATION OF OLEFINS Ziegler Growth Reaction Nickel Effect and Nickel-Catalyzed Dimerization of Ethene Trimerization of Ethene Shell Higher Olefin and Alpha-Sablin Processes POLYMERIZATION OF OLEFINS Introduction Ethene Polymerization Propene Polymerization Metallocene Catalysts Nonmetallocene Catalysts Copolymerization of Olefins and CO C-C LINKAGE OF DIENES Introduction Allyl and Butadiene Complexes Organometallic Elementary Steps of Allyl Ligands Oligomerization and Telomerization of Butadiene Polymerization of Butadiene C-C COUPLING REACTIONS Palladium-Catalyzed Cross-Coupling Reactions The Heck Reaction Palladium-Catalyzed Allylic Alkylation HYDROCYANATION, HYDROSILYLATION, AND HYDROAMINATION OF OLEFINS Introduction Hydrocyanation Hydrosilylation Hydroamination OXIDATION OF OLEFINS AND ALKANES The Wacker Process Epoxidation of Olefins C-H Functionalization of Alkanes NITROGEN FIXATION Fundamentals Heterogeneously Catalyzed Nitrogen Fixation Enzyme-Catalyzed Nitrogen Fixation Homogeneously Catalyzed Nitrogen Fixation.
  • (source: Nielsen Book Data)
Clearly structured and written with advanced undergraduate, graduate and PhD students in mind, this English edition of a successful German textbook not only focuses on organic reactions, but also on bio-relevant reactions. Important aspects of the catalytic mechanisms are discussed in detail while much additional information is also provided, such as industrial applications of the processes covered. With its many questions and answers included in all chapters at different knowledge levels, this book is also ideal for self-testing before exams.
(source: Nielsen Book Data)
  • Preface INTRODUCTION The Beginnings of Catalytic Research The Catalysis Definitions of Berzelius and Ostwald PRINCIPLES OF ORGANOMETALLIC CATALYSIS Homogeneous versus Heterogeneous Catalysis Catalytic Cycles Activity and Productivity of Catalysts Selectivity and Specificity of Catalysts Determination of Catalytic Mechanisms Glossary for Catalysis The Development of Organometallic Catalysis ELEMENTARY STEPS IN ORGANOMETALLIC CATALYSIS Cleavage and Coordination of Ligands Oxidative Addition and Reductive Elimination Oxidative Coupling and Reductive Cleavage Olefin Insertion and Beta-Hydrogen Elimination Alpha-Hydrogen Elimination and Carbene Insertion Reactions Addition of Nucleophiles and Heterolytic Fragmentation Insertion and Extrusion of CO One-Electron Reduction and Oxidation HYDROGENATION OF OLEFINS Introduction The Wilkinson Catalyst Enantioselective Hydrogenation Dihydrogen Complexes and H2 Activation Transfer Hydrogenation HYDROFORMYLATION OF OLEFINS AND FISCHER-TROPSCH SYNTHESIS Cobalt Catalysts Phosphane-Modified Rhodium Catalysts Enantioselective Hydroformylation Significance of Hydroformylation and Outlook The Fischer-Tropsch Synthesis CARBONYLATION OF METHANOL AND WATER-GAS SHIFT REACTION Principles The Monsanto Process Synthesis of Acetic Anhydride The Cativa Process Water-Gas Shift Reaction and Carbon Monoxide Dehydrogenases METATHESIS Metathesis of Olefins Metathesis of Alkynes Enyne Metathesis Delta-Bond Metathesis Metathesis of Alanes OLIGOMERIZATION OF OLEFINS Ziegler Growth Reaction Nickel Effect and Nickel-Catalyzed Dimerization of Ethene Trimerization of Ethene Shell Higher Olefin and Alpha-Sablin Processes POLYMERIZATION OF OLEFINS Introduction Ethene Polymerization Propene Polymerization Metallocene Catalysts Nonmetallocene Catalysts Copolymerization of Olefins and CO C-C LINKAGE OF DIENES Introduction Allyl and Butadiene Complexes Organometallic Elementary Steps of Allyl Ligands Oligomerization and Telomerization of Butadiene Polymerization of Butadiene C-C COUPLING REACTIONS Palladium-Catalyzed Cross-Coupling Reactions The Heck Reaction Palladium-Catalyzed Allylic Alkylation HYDROCYANATION, HYDROSILYLATION, AND HYDROAMINATION OF OLEFINS Introduction Hydrocyanation Hydrosilylation Hydroamination OXIDATION OF OLEFINS AND ALKANES The Wacker Process Epoxidation of Olefins C-H Functionalization of Alkanes NITROGEN FIXATION Fundamentals Heterogeneously Catalyzed Nitrogen Fixation Enzyme-Catalyzed Nitrogen Fixation Homogeneously Catalyzed Nitrogen Fixation.
  • (source: Nielsen Book Data)
Clearly structured and written with advanced undergraduate, graduate and PhD students in mind, this English edition of a successful German textbook not only focuses on organic reactions, but also on bio-relevant reactions. Important aspects of the catalytic mechanisms are discussed in detail while much additional information is also provided, such as industrial applications of the processes covered. With its many questions and answers included in all chapters at different knowledge levels, this book is also ideal for self-testing before exams.
(source: Nielsen Book Data)
Chemistry & ChemEng Library (Swain)
Status of items at Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) Status
Stacks
QD505 .S74 2012 Unknown
Book
xiv, 566 p. : ill. (some col.) ; 24 cm.
  • Catalyst Preparation-- Characterization by Spectroscopic Techniques-- Electron Microscopy-- Determination of Dispersion-- Progress in C1 Chemistry-- Catalysis in Fuel Cell Application-- Supported Metals for Hydrogen Production-- Vehicle Emission Catalysts-- Fine Chemicals.
  • (source: Nielsen Book Data)
With contributions from experts in supported metal catalysis, from both the industry and academia, this book presents the latest developments in characterization and application of supported metals in heterogeneous catalysis. In addition to a thorough and updated coverage of the traditional aspects of heterogeneous catalysis such as preparation, characterization and use in well-established technologies such as Naphtha reforming, the book also includes emerging areas where supported metal catalysis will make significant contributions in future developments, such as fuel cells and fine chemicals synthesis. The second edition of "Supported Metals in Catalysis" comes complete with new and updated chapters containing important summaries of research in a rapidly evolving field. Very few other books deal with this highly pertinent subject matter, and as such, it is a must-have for anyone working in the field of heterogeneous catalysis.
(source: Nielsen Book Data)
  • Catalyst Preparation-- Characterization by Spectroscopic Techniques-- Electron Microscopy-- Determination of Dispersion-- Progress in C1 Chemistry-- Catalysis in Fuel Cell Application-- Supported Metals for Hydrogen Production-- Vehicle Emission Catalysts-- Fine Chemicals.
  • (source: Nielsen Book Data)
With contributions from experts in supported metal catalysis, from both the industry and academia, this book presents the latest developments in characterization and application of supported metals in heterogeneous catalysis. In addition to a thorough and updated coverage of the traditional aspects of heterogeneous catalysis such as preparation, characterization and use in well-established technologies such as Naphtha reforming, the book also includes emerging areas where supported metal catalysis will make significant contributions in future developments, such as fuel cells and fine chemicals synthesis. The second edition of "Supported Metals in Catalysis" comes complete with new and updated chapters containing important summaries of research in a rapidly evolving field. Very few other books deal with this highly pertinent subject matter, and as such, it is a must-have for anyone working in the field of heterogeneous catalysis.
(source: Nielsen Book Data)
Chemistry & ChemEng Library (Swain)
Status of items at Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) Status
Stacks
QD505 .S78 2012 Unknown
Book
175 p. : ill ; 24 cm.
Chemistry & ChemEng Library (Swain)
Status of items at Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) Status
Stacks
QD505 .S2545 2011 Unknown
Book
xviii, 505 p. : ill. ; 25 cm.
  • Synthesis of Saturated Five-Membered Nitrogen Heterocycles via Pd-Catalyzed C-N Bond-Forming Reactions Transition Metal Catalyzed Approaches to Lactones Involving C-O Bond Formation The Formation of Csp2-S and Csp2-Se Bonds by Substitution and Addition Reactions Catalyzed by Transition Metal Complexes Palladium-Catalysis for Oxidative 1,2-Difunctionalization of Alkenes Rhodium-Catalyzed C-H Aminations The Palladium Catalyzed Synthesis of Aromatic Heterocycles New Reactions of Copper Acetylides: Catalytic Dipolar Cycloadditions and Beyond Transition Metal-Catalyzed Synthesis of Monocyclic Five-Membered Aromatic Heterocycles Transition Metal-Catalyzed Synthesis of Fused Five-Membered Aromatic Heterocycles Carbon-Heteroatom Bond Formation by RhI-Catalyzed Ring-Opening Reactions Gold-Catalyzed Addition of Nitrogen and Sulfur Nucleophiles to C-C Multiple Bonds Gold-Catalyzed Addition of Oxygen Nucleophiles to C-C Multiple Bonds.
  • (source: Nielsen Book Data)
Written by an experienced editor widely acclaimed within the scientific community, this book covers everything from oxygen to nitrogen functionalities. From the contents: * Palladium-Catalyzed Syntheses of Five-Membered Saturated Heterocycles * The Formation of Carbon-Sulfur and Carbon-Selenium Bonds by Substitution and Addition Reactions Catalyzed by Transition Metal Complexes * Palladium-Catalysis for Oxidative 1,2-Difunctionalization of Alkenes * Palladium-Catalyzed Formation of Aromatic Heterocycles * Rhodium-Catalyzed Amination of C-H-Bonds * Transition Metal-Catalyzed Synthesis of Heterocycles * Copper-Catalyzed Synthesis of Azoles * Palladium(II)-Catalyzed C-N Bond Formation Involving Aminopalladation of Aklenes * Carbon-Heteroatom Bond Formation by Rh(I)-Catalyzed Ring-Opening Reactions * Recent Advances in Homogeneous Gold Catalysis: Formation of Carbon-Heteroatom Bonds The result is an indispensable source of information for the strategic planning of the synthetic routes for organic, catalytic and medicinal chemists, as well as chemists in industry.
(source: Nielsen Book Data)
  • Synthesis of Saturated Five-Membered Nitrogen Heterocycles via Pd-Catalyzed C-N Bond-Forming Reactions Transition Metal Catalyzed Approaches to Lactones Involving C-O Bond Formation The Formation of Csp2-S and Csp2-Se Bonds by Substitution and Addition Reactions Catalyzed by Transition Metal Complexes Palladium-Catalysis for Oxidative 1,2-Difunctionalization of Alkenes Rhodium-Catalyzed C-H Aminations The Palladium Catalyzed Synthesis of Aromatic Heterocycles New Reactions of Copper Acetylides: Catalytic Dipolar Cycloadditions and Beyond Transition Metal-Catalyzed Synthesis of Monocyclic Five-Membered Aromatic Heterocycles Transition Metal-Catalyzed Synthesis of Fused Five-Membered Aromatic Heterocycles Carbon-Heteroatom Bond Formation by RhI-Catalyzed Ring-Opening Reactions Gold-Catalyzed Addition of Nitrogen and Sulfur Nucleophiles to C-C Multiple Bonds Gold-Catalyzed Addition of Oxygen Nucleophiles to C-C Multiple Bonds.
  • (source: Nielsen Book Data)
Written by an experienced editor widely acclaimed within the scientific community, this book covers everything from oxygen to nitrogen functionalities. From the contents: * Palladium-Catalyzed Syntheses of Five-Membered Saturated Heterocycles * The Formation of Carbon-Sulfur and Carbon-Selenium Bonds by Substitution and Addition Reactions Catalyzed by Transition Metal Complexes * Palladium-Catalysis for Oxidative 1,2-Difunctionalization of Alkenes * Palladium-Catalyzed Formation of Aromatic Heterocycles * Rhodium-Catalyzed Amination of C-H-Bonds * Transition Metal-Catalyzed Synthesis of Heterocycles * Copper-Catalyzed Synthesis of Azoles * Palladium(II)-Catalyzed C-N Bond Formation Involving Aminopalladation of Aklenes * Carbon-Heteroatom Bond Formation by Rh(I)-Catalyzed Ring-Opening Reactions * Recent Advances in Homogeneous Gold Catalysis: Formation of Carbon-Heteroatom Bonds The result is an indispensable source of information for the strategic planning of the synthetic routes for organic, catalytic and medicinal chemists, as well as chemists in industry.
(source: Nielsen Book Data)
Chemistry & ChemEng Library (Swain)
Status of items at Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) Status
Stacks
QD281 .C3 C39 2011 Unknown
Book
xxvi, 302 p. : ill. ; 24 cm.
  • Overview of Catalysis by Nanostructured Materials (R J Davis)-- Synthesis of Nanostructured Catalysts (R F Lobo)-- Spectroscopic Characterization of Nanostructured Catalysts (J T Miller)-- Electron and Tunneling Microscopy of Nanostructured Catalysts (R Sharma)-- Theory and Simulation in Catalysis (M Neurock)-- Applications: Energy from Fossil Resources (L Thompson)-- Applications: Chemicals from Fossil Resources (V V Guliants)-- Applications: Renewable Fuels and Chemicals (G Huber).
  • (source: Nielsen Book Data)
Catalyst technologies account for over $1 trillion of revenues in the U.S. economy alone. The applications range from medicines and alternative energy fuel cell technologies to the development of new and innovative clothing fibers. A WTEC panel of eight experts in the field assesses the current state of research and development in catalysis by nanostructured materials, its sources of funding, and discusses the state of the field with respect to productivity and leadership in various nations around the world. In addition to showing the numerous and highly advantageous practical applications of the field, the panel concludes that Western Europe is currently the most productive region, followed closely by the United States. Still, the R&D output of the People's Republic of China has recently surpassed that of Japan and is now poised to surpass that of the U.S. as well. As such, this assessment is a timely review of the field's progress, taking into account the increasing contributions from Asia and will be essential reading for professionals - whether they are seeking an in-depth summary of the state-of-the-art or a broad view of trends sweeping the discipline.
(source: Nielsen Book Data)
  • Overview of Catalysis by Nanostructured Materials (R J Davis)-- Synthesis of Nanostructured Catalysts (R F Lobo)-- Spectroscopic Characterization of Nanostructured Catalysts (J T Miller)-- Electron and Tunneling Microscopy of Nanostructured Catalysts (R Sharma)-- Theory and Simulation in Catalysis (M Neurock)-- Applications: Energy from Fossil Resources (L Thompson)-- Applications: Chemicals from Fossil Resources (V V Guliants)-- Applications: Renewable Fuels and Chemicals (G Huber).
  • (source: Nielsen Book Data)
Catalyst technologies account for over $1 trillion of revenues in the U.S. economy alone. The applications range from medicines and alternative energy fuel cell technologies to the development of new and innovative clothing fibers. A WTEC panel of eight experts in the field assesses the current state of research and development in catalysis by nanostructured materials, its sources of funding, and discusses the state of the field with respect to productivity and leadership in various nations around the world. In addition to showing the numerous and highly advantageous practical applications of the field, the panel concludes that Western Europe is currently the most productive region, followed closely by the United States. Still, the R&D output of the People's Republic of China has recently surpassed that of Japan and is now poised to surpass that of the U.S. as well. As such, this assessment is a timely review of the field's progress, taking into account the increasing contributions from Asia and will be essential reading for professionals - whether they are seeking an in-depth summary of the state-of-the-art or a broad view of trends sweeping the discipline.
(source: Nielsen Book Data)
Chemistry & ChemEng Library (Swain)
Status of items at Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) Status
Stacks
QD505 .I538 2011 Unknown
Book
xvii, 447 p. : ill. ; 25 cm.
  • 1 Rhodium- and Palladium-Catalyzed Asymmetric Conjugate Additions 2 Cu- and Ni-Catalyzed Conjugated Additions of Organozincs and Organoaluminums to a, ss-Unsaturated Carbonyl Compounds 3 ECAs of Organolithium Reagents, Grignard Reagents, and Examples of Cu-Catalyzed ECAs 4 Asymmetric Bifunctional Catalysis Using Heterobimetallic and Multimetallic Systems in Enantioselective Conjugate Additions 5 Enamines in Catalytic Enantioselective Conjugate Additions 6 Iminium Activation in Catalytic Enantioselective Conjugate Additions 7 Organocatalytic Enantioselective Conjugate Additions of Heteroatoms to a, ss-Unsaturated Carbonyl Compounds 8 Domino Reactions Involving Catalytic Enantioselective Conjugate Additions 9 Asymmetric Epoxidations of a, ss-Unsaturated Carbonyl Compounds 10 Catalytic Asymmetric Baylis?Hillman Reactions and Surroundings.
  • (source: Nielsen Book Data)
This unique and long-awaited handbook on this important topic in the hot field of stereoselective organic synthesis covers several types of nucleophiles. Top international authors deal with modern forms of achieving stereoselective conjugate additions based on the use of chiral auxiliaries or asymmetric catalysis, such as P-N ligands, organocatalysis, domino reactions, Lewis acid and base catalysis. There is also a discussion of the employment of enantioselective conjugate addition transformations in total synthesis of important molecules. With its reliable and previously unpublished experimental procedures, this is a true source of high quality information.
(source: Nielsen Book Data)
  • 1 Rhodium- and Palladium-Catalyzed Asymmetric Conjugate Additions 2 Cu- and Ni-Catalyzed Conjugated Additions of Organozincs and Organoaluminums to a, ss-Unsaturated Carbonyl Compounds 3 ECAs of Organolithium Reagents, Grignard Reagents, and Examples of Cu-Catalyzed ECAs 4 Asymmetric Bifunctional Catalysis Using Heterobimetallic and Multimetallic Systems in Enantioselective Conjugate Additions 5 Enamines in Catalytic Enantioselective Conjugate Additions 6 Iminium Activation in Catalytic Enantioselective Conjugate Additions 7 Organocatalytic Enantioselective Conjugate Additions of Heteroatoms to a, ss-Unsaturated Carbonyl Compounds 8 Domino Reactions Involving Catalytic Enantioselective Conjugate Additions 9 Asymmetric Epoxidations of a, ss-Unsaturated Carbonyl Compounds 10 Catalytic Asymmetric Baylis?Hillman Reactions and Surroundings.
  • (source: Nielsen Book Data)
This unique and long-awaited handbook on this important topic in the hot field of stereoselective organic synthesis covers several types of nucleophiles. Top international authors deal with modern forms of achieving stereoselective conjugate additions based on the use of chiral auxiliaries or asymmetric catalysis, such as P-N ligands, organocatalysis, domino reactions, Lewis acid and base catalysis. There is also a discussion of the employment of enantioselective conjugate addition transformations in total synthesis of important molecules. With its reliable and previously unpublished experimental procedures, this is a true source of high quality information.
(source: Nielsen Book Data)
Chemistry & ChemEng Library (Swain)
Status of items at Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) Status
Stacks
QD262 .C35538 2010 Unknown
Book
xvii, 998 p. : ill. ; 25 cm.
  • Preface. Preface to the Second Edition. Preface to the First Edition. Contributors. 1 Catalytic Asymmetric Synthesis in Non-Conventional Media/Conditions ( Chikako Ogawa and Shu Kobayashi ). 2 Asymmetric Organocatalysis. 2A Enantioselective Organocatalysis Involving Iminium, Enamine, SOMO and Photoredox Activation ( Allan J. B. Watson and David W. C. MacMillan ). 2B Asymmetric Acid-Base Bifunctional Catalysis with Organic Molecules ( Yi Wang and Li Deng ). 2C Asymmetric Phase-Transfer and Ion Pair Catalysis ( Seiji Shirakawa and Keiji Maruoka ). 3 Chiral Lewis Acids and Bronsted Acids in Asymmetric Synthesis ( Hisashi Yamamoto and Cheol Hong Cheon ). 4 Asymmetric Synthesis through C H Activation ( Huw M. L. Davies and Jorn Hansen ). 5 Asymmetric Carbon-Heteroatom Bond-Forming Reactions ( Yoshiji Takemoto and Hideto Miyabe ). 6 Enzyme-Catalyzed Asymmetric Synthesis ( Harald Groger ). 7 Transition Metal-Catalyzed Homogeneous Asymmetric Hydrogenation ( Gao Shang, Wei Li and Xumu Zhang ). 8 Asymmetric Carbon-Carbon Bond Forming Reactions. 8A Catalytic Asymmetric Conjugate Addition ( Jian-Xin Ji and Albert S. C. Chan ). 8B Enantioselective Allylic Substitutions with Carbon-Nucleophiles ( Gunter Helmchen, Uli Kazmaier and Sebastian Forster ). 8C Asymmetric Carbometallation and Carbocyclizations ( Iwao Ojima, Joseph J. Kaloko, Stephen J. Chaterpaul, Yu-Han Gary Teng and Chi-Feng Lin ). 8D Asymmetric Ene Reactions and Cycloadditions ( Koichi Mikami and Kohsuke Aikawa ). 8E Catalytic Enantioselective Olefin Metathesis Reactions ( Amir H. Hoveyda, Steven J. Malcolmson, Simon J. Meek and Adil R. Zhugralin ). 9 Asymmetric Hydrosilation of Carbon-Carbon Double Bonds and Related Reactions ( Jin Wook Han and Tamio Hayashi ). 10 Asymmetric Carbonylations ( Cyril Godard, Aurora Ruiz, Montserrat Dieguez, Oscar Pamies and Carmen Claver ). 11 Asymmetric Oxidations and Related Reactions ( Kazuhiro Matsumoto and Tsutomu Katsuki ). 12 Asymmetric Amplification and Autocatalysis ( Kenso Soai, Tsuneomi Kawasaki, and Takanori Shibata ). 13 Asymmetric Polymerization ( Shingo Ito and Kyoko Nozaki ). Index.
  • (source: Nielsen Book Data)
Since the last edition was published seven years ago, catalytic asymmetric synthesis has become crucial to chemistry and to the preparation of pharmaceutical, fine chemical, and agricultural agents. The revised Catalytic Asymmetric Synthesis includes six new chapters on topics like non-conventional media/conditions, organocatalysis, CH activation, and much more, while the book's remaining chapters have been fully updated. A new section on carbon-carbon bond forming reactions, authored by distinguished Nobel prizewinning scientists, has been added. This revision, with a helpful appendix, is an essential reference on catalytic asymmetric synthesis for both chemists and students alike.
(source: Nielsen Book Data)
  • Preface. Preface to the Second Edition. Preface to the First Edition. Contributors. 1 Catalytic Asymmetric Synthesis in Non-Conventional Media/Conditions ( Chikako Ogawa and Shu Kobayashi ). 2 Asymmetric Organocatalysis. 2A Enantioselective Organocatalysis Involving Iminium, Enamine, SOMO and Photoredox Activation ( Allan J. B. Watson and David W. C. MacMillan ). 2B Asymmetric Acid-Base Bifunctional Catalysis with Organic Molecules ( Yi Wang and Li Deng ). 2C Asymmetric Phase-Transfer and Ion Pair Catalysis ( Seiji Shirakawa and Keiji Maruoka ). 3 Chiral Lewis Acids and Bronsted Acids in Asymmetric Synthesis ( Hisashi Yamamoto and Cheol Hong Cheon ). 4 Asymmetric Synthesis through C H Activation ( Huw M. L. Davies and Jorn Hansen ). 5 Asymmetric Carbon-Heteroatom Bond-Forming Reactions ( Yoshiji Takemoto and Hideto Miyabe ). 6 Enzyme-Catalyzed Asymmetric Synthesis ( Harald Groger ). 7 Transition Metal-Catalyzed Homogeneous Asymmetric Hydrogenation ( Gao Shang, Wei Li and Xumu Zhang ). 8 Asymmetric Carbon-Carbon Bond Forming Reactions. 8A Catalytic Asymmetric Conjugate Addition ( Jian-Xin Ji and Albert S. C. Chan ). 8B Enantioselective Allylic Substitutions with Carbon-Nucleophiles ( Gunter Helmchen, Uli Kazmaier and Sebastian Forster ). 8C Asymmetric Carbometallation and Carbocyclizations ( Iwao Ojima, Joseph J. Kaloko, Stephen J. Chaterpaul, Yu-Han Gary Teng and Chi-Feng Lin ). 8D Asymmetric Ene Reactions and Cycloadditions ( Koichi Mikami and Kohsuke Aikawa ). 8E Catalytic Enantioselective Olefin Metathesis Reactions ( Amir H. Hoveyda, Steven J. Malcolmson, Simon J. Meek and Adil R. Zhugralin ). 9 Asymmetric Hydrosilation of Carbon-Carbon Double Bonds and Related Reactions ( Jin Wook Han and Tamio Hayashi ). 10 Asymmetric Carbonylations ( Cyril Godard, Aurora Ruiz, Montserrat Dieguez, Oscar Pamies and Carmen Claver ). 11 Asymmetric Oxidations and Related Reactions ( Kazuhiro Matsumoto and Tsutomu Katsuki ). 12 Asymmetric Amplification and Autocatalysis ( Kenso Soai, Tsuneomi Kawasaki, and Takanori Shibata ). 13 Asymmetric Polymerization ( Shingo Ito and Kyoko Nozaki ). Index.
  • (source: Nielsen Book Data)
Since the last edition was published seven years ago, catalytic asymmetric synthesis has become crucial to chemistry and to the preparation of pharmaceutical, fine chemical, and agricultural agents. The revised Catalytic Asymmetric Synthesis includes six new chapters on topics like non-conventional media/conditions, organocatalysis, CH activation, and much more, while the book's remaining chapters have been fully updated. A new section on carbon-carbon bond forming reactions, authored by distinguished Nobel prizewinning scientists, has been added. This revision, with a helpful appendix, is an essential reference on catalytic asymmetric synthesis for both chemists and students alike.
(source: Nielsen Book Data)
Chemistry & ChemEng Library (Swain)
Status of items at Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) Status
Stacks
QD262 .C357 2010 Unknown
Book
xii, 771 p. : ill. (some col.) ; 26 cm.
  • Preface. Introduction. 1 Surfaces: An Introduction. 2 The Structure of Surfaces. 3 Thermodynamics of Surfaces. 4 Dynamics at Surfaces. 5 Electrical Properties of Surfaces. 6 Surface Chemical Bond. 7 Mechanical Properties of Surfaces. 8 Polymer Surfaces and Biointerfaces. 9 Catalysis by Surfaces. Index.
  • (source: Nielsen Book Data)
The newest edition of this textbook emphasizes modern surface chemistry and catalysis concepts uncovered by breakthough molecular level-studies of surfaces over the past three decades. This resource also serves as a reference for properties of surfaces and interfaces. For students, the text presents the basic concepts in various properties of surfaces such as structure, thermodynamics, dynamics, electronic properties, and chemical bonds on surfaces. For advanced readers, it covers recent developments in in-situ surface analysis such as high pressure scanning tunneling microscopy, ambience pressure X-ray photoelectron spectroscopy, and sum frequency generation vibrational spectroscopy (SFG).
(source: Nielsen Book Data)
  • Preface. Introduction. 1 Surfaces: An Introduction. 2 The Structure of Surfaces. 3 Thermodynamics of Surfaces. 4 Dynamics at Surfaces. 5 Electrical Properties of Surfaces. 6 Surface Chemical Bond. 7 Mechanical Properties of Surfaces. 8 Polymer Surfaces and Biointerfaces. 9 Catalysis by Surfaces. Index.
  • (source: Nielsen Book Data)
The newest edition of this textbook emphasizes modern surface chemistry and catalysis concepts uncovered by breakthough molecular level-studies of surfaces over the past three decades. This resource also serves as a reference for properties of surfaces and interfaces. For students, the text presents the basic concepts in various properties of surfaces such as structure, thermodynamics, dynamics, electronic properties, and chemical bonds on surfaces. For advanced readers, it covers recent developments in in-situ surface analysis such as high pressure scanning tunneling microscopy, ambience pressure X-ray photoelectron spectroscopy, and sum frequency generation vibrational spectroscopy (SFG).
(source: Nielsen Book Data)
Chemistry & ChemEng Library (Swain)
Status of items at Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) Status
Stacks
QD506 .S589 2010 Unknown
Book
xxii, 459 p. : ill. (some col.) ; 25 cm.
  • CHEMISTRY OF METALATED CONTAINER MOLECULES Introduction Metalated Container Molecules: A Brief Overview Metalated Container Molecules of Binucleating Supporting Ligands THE CHEMISTRY OF SUPERBASIC GUANIDINES Properties of the Guanidine Functionality Design of Superbasic Proton Sponges Some Perspectives in Proton Sponge Chemistry Multidentate Superbasic Guanidine Ligands as Receptors for Metal Cations The Chemistry of Guanidine Copper Complexes The Chemistry of Guanidine Zinc Complexes IRON COMPLEXES AND DIOXYGEN ACTIVATION Introduction Dinuclear Iron Peroxo Complexes Tripodal Tetradentate Ligands and Derivatives Monomuclear Iron Peroxo Complexes Mononuclear Iron Oxo Species Work in Progress TUNING OF STRUCTURES AND PROPERTIES OF BISPIDINE COMPLEXES Introduction Jahn-Teller Isomerism with Copper(II) Bispidines Stabilization of High-Spin Ferryl Complexes Jahn-Teller-Distorted Cobalt(III) Complexes NOVEL PHOSPHORUS AND NITROGEN DONOR LIGANDS BEARING SECONDARY FUNCTIONALITIES FOR APPLICATIONS IN HOMOGENEOUS CATALYSIS Introduction Phosphine Ligands Nitrogen Donor Ligands Without Phosphorus Sites SQUARE-PYRAMIDAL COORDINATED PHOSPHINE IRON FRAGMENTS: A TALE OF THE UNEXPECTED Introduction Polyphosphine Ligands with Three and Four Coordinating Arms C-P Bond Activation and Agostic Interactions in Iron Complexes of Polypodal Phosphine Ligands Mechanistic Considerations REGIOSELECTIVE CATALYTIC ACTIVITY OF COMPLEXES WITH NH, NR-SUBSTIUTED HETEROCYCLIC CARBENE LIGANDS Introduction Concept of Regioselective Substrate Activation Synthesis of Complexes with NH, NR-Stabilized NHC Ligands Preparation of Substrates for Catalytic Experiments Catalysis Experiments FUNCTIONALIZED CYCLOHEPTATRIENYL-CYCLOPENTADIENYL SANDWICH COMPLEXES AS BUILDING BLOCKS IN METALLO-SUPRAMOLECULAR CHEMISTRY Introduction Syntheses and Electronic Structure of Group 4 Cycloheptatrienyl-Cyclopentadienyl Sandwich Complexes Syntheses and Reactivity of Ansa-Cycloheptatrienyl-Cyclopentadienyl Complexes Ring-Opening Reactions of Ansa-Cycloheptatrienyl-Cyclopentadienyl Complexes Phosphine-Functionalized Cycloheptatrienyl-Cyclopentadienyl Sandwich Complexes MONOSACCHARIDE LIGANDS IN ORGANOTITANIUM AND ORGANOZIRCONIUM CHEMISTRY Introduction Synthesis of Organotitanium Carbohydrate Compounds Organotitanium Carbohydrate Compounds for Use in Catalytic Reactions: Polymerization of Ethylene Intramolecular Hydroamination of Aminoalkenes Organozirconium Carbohydrate Compounds Amine Exchange Chiral Recognition REACTIONS OF C-F BONDS WITH TITANOCENE AND ZIRCONOCENE: FROM SECONDARY INTERACTION VIA BOND CLEAVAGE TO CATALYSIS Introduction and Background Secondary Interactions with C-F Bonds Formation of M-F Bonds Stoichiometric Formation of Zr-H Bonds Catalytic Formation of Zr-H Bonds BISAZINES IN THE COORDINATION SPHERE OF EARLY TRANSITION METALS Introduction Results and Discussion BIFUNCTIONAL MOLECULAR SYSTEMS WITH PENDANT BIS(PENTAFLUOROPHENYL)BORYL GROUPS: FROM INTRAMOLECULAR CH-ACTIVATION TO HETEROLYTIC DIHYDROGEN SPLITTING Introduction Bifunctional Zirconum/Boron Systems Bifunctional Group 9 Metal/Boron Systems Bifunctional Phosphorus/Boron Systems RUTHENIUM-CONTAINING POLYOXOTUNGSTATES: STRUCTURE AND REDOX ACTIVITY Introduction The Organoruthenium(II)-Containing 49-Tungsto-8-Phosphate[{K(H2O)}3{Ro(p-cymene)()H2O)}4P8W49O186(H 2O)2]27- The Mono-Ruthenium(III)-Substituted Keggin-Type 11-Tungstosilicate [alpha-SiW11O39Ru111(H2=)]5- and its Dimerization FROM NO TO PEROXIDE ACTIVATION BY MODEL IRON(III) COMPLEXES Introduction NO Activation by Fe(III) Complexes Peroxide Activation by Fe(III) Complexes SYNTHETIC NITROGEN FIXATION WITH MOLYBDENUM AND TUNGSTEN PHOSPHINE COMPLEXES: NEW DEVELOPMENTS Introduction Mechanistic Investigation of the Chatt Cycle New Phosphine and Mixed P/N Ligands for Synthetic Nitrogen Fixation DIRECTED C-H FUNCTIONALIZATIONS Introduction Results and Discussion DEVELOPMENT OF NOVEL RUTHENIUM AND IRON CATALYSTS FOR EPOXIDATION WITH HYDROGEN PEROXIDE Introduction Development of Epoxidation Catalysts Using H2O2 PENTACOORDINATING BIS(OXAZOLINE) LIGANDS WITH SECONDARY BINDING SITES FLAVIN PHOTOCATALYSTS WITH SUBSTRATE BINDING SITES Introduction Templated Flavin Photoreductions Templated Flavin Photooxidations NEW CATALYTIC CU-, PD- AND STOICHIOMETRIC MG-, ZN-MEDIATED BOND ACTIVATIONS Introduction Catalytic Activation Stoichiometric Activation FROM COBALT(II)-ACTIVATED MOLECULAR OXYGEN TO HYDROCYMETHYL-SUBSTITUTED TETRAHYDROFURANS Introduction Thermochemical Considerations Cobalt(II)-Diketonate Complexes Reactivity Stereoselectivity Survey A Derivative of Magnosalicin Expanding the Scope REGIODIVERGENT EPOXIDE OPENING Epoxide Opening via Nucleophilic Substitution: Limitations Arising from the SN2-Mechanism Regiodivergent Epoxide Opening (REO): Mechanistic Implications, Synthetic Potential, and Aspects of Catalyst Design Reductive Epoxide Opening via Electron Transfer from Titanocene(III) Reagents Synthetic Realization of Titanocene-Catalyzed REO SUPRAMOLECULAR CONTAINERS: HOST-GUEST CHEMISTRY AND REACTIVITY Introduction M4L4Tetrahedra Amino Acid-Bridged Dinuclear Titanium(IV) Complexes as Metalloenzyme Mimicry SELF-ASSEMBLY OF DINUCLEAR HELICAL METALLOSUPRAMOLECULAR COORDINATION COMPOUNDS Introduction The Concept of Diastereoselective Self-Assembly of Dinuclear Helicates Synthesis of Building Blocks for the Covalent Assembly of Bis(Chelating) Ligands Synthesis of Bis(Chelating) Ligands and Their Dinuclear Metal Complexes.
  • (source: Nielsen Book Data)
The use of secondary interactions for the activation of non-reactive substrates constitutes a new and modern approach in catalysis. This first comprehensive treatment of this important research field covers the entire field and reveals the links between the various chemical disciplines. It thus adopts an interdisciplinary approach, making it of interest to the whole chemical community. This book is a must for organic, inorganic, catalytic and complex chemists, as well as those working with/on organometallics.
(source: Nielsen Book Data)
  • CHEMISTRY OF METALATED CONTAINER MOLECULES Introduction Metalated Container Molecules: A Brief Overview Metalated Container Molecules of Binucleating Supporting Ligands THE CHEMISTRY OF SUPERBASIC GUANIDINES Properties of the Guanidine Functionality Design of Superbasic Proton Sponges Some Perspectives in Proton Sponge Chemistry Multidentate Superbasic Guanidine Ligands as Receptors for Metal Cations The Chemistry of Guanidine Copper Complexes The Chemistry of Guanidine Zinc Complexes IRON COMPLEXES AND DIOXYGEN ACTIVATION Introduction Dinuclear Iron Peroxo Complexes Tripodal Tetradentate Ligands and Derivatives Monomuclear Iron Peroxo Complexes Mononuclear Iron Oxo Species Work in Progress TUNING OF STRUCTURES AND PROPERTIES OF BISPIDINE COMPLEXES Introduction Jahn-Teller Isomerism with Copper(II) Bispidines Stabilization of High-Spin Ferryl Complexes Jahn-Teller-Distorted Cobalt(III) Complexes NOVEL PHOSPHORUS AND NITROGEN DONOR LIGANDS BEARING SECONDARY FUNCTIONALITIES FOR APPLICATIONS IN HOMOGENEOUS CATALYSIS Introduction Phosphine Ligands Nitrogen Donor Ligands Without Phosphorus Sites SQUARE-PYRAMIDAL COORDINATED PHOSPHINE IRON FRAGMENTS: A TALE OF THE UNEXPECTED Introduction Polyphosphine Ligands with Three and Four Coordinating Arms C-P Bond Activation and Agostic Interactions in Iron Complexes of Polypodal Phosphine Ligands Mechanistic Considerations REGIOSELECTIVE CATALYTIC ACTIVITY OF COMPLEXES WITH NH, NR-SUBSTIUTED HETEROCYCLIC CARBENE LIGANDS Introduction Concept of Regioselective Substrate Activation Synthesis of Complexes with NH, NR-Stabilized NHC Ligands Preparation of Substrates for Catalytic Experiments Catalysis Experiments FUNCTIONALIZED CYCLOHEPTATRIENYL-CYCLOPENTADIENYL SANDWICH COMPLEXES AS BUILDING BLOCKS IN METALLO-SUPRAMOLECULAR CHEMISTRY Introduction Syntheses and Electronic Structure of Group 4 Cycloheptatrienyl-Cyclopentadienyl Sandwich Complexes Syntheses and Reactivity of Ansa-Cycloheptatrienyl-Cyclopentadienyl Complexes Ring-Opening Reactions of Ansa-Cycloheptatrienyl-Cyclopentadienyl Complexes Phosphine-Functionalized Cycloheptatrienyl-Cyclopentadienyl Sandwich Complexes MONOSACCHARIDE LIGANDS IN ORGANOTITANIUM AND ORGANOZIRCONIUM CHEMISTRY Introduction Synthesis of Organotitanium Carbohydrate Compounds Organotitanium Carbohydrate Compounds for Use in Catalytic Reactions: Polymerization of Ethylene Intramolecular Hydroamination of Aminoalkenes Organozirconium Carbohydrate Compounds Amine Exchange Chiral Recognition REACTIONS OF C-F BONDS WITH TITANOCENE AND ZIRCONOCENE: FROM SECONDARY INTERACTION VIA BOND CLEAVAGE TO CATALYSIS Introduction and Background Secondary Interactions with C-F Bonds Formation of M-F Bonds Stoichiometric Formation of Zr-H Bonds Catalytic Formation of Zr-H Bonds BISAZINES IN THE COORDINATION SPHERE OF EARLY TRANSITION METALS Introduction Results and Discussion BIFUNCTIONAL MOLECULAR SYSTEMS WITH PENDANT BIS(PENTAFLUOROPHENYL)BORYL GROUPS: FROM INTRAMOLECULAR CH-ACTIVATION TO HETEROLYTIC DIHYDROGEN SPLITTING Introduction Bifunctional Zirconum/Boron Systems Bifunctional Group 9 Metal/Boron Systems Bifunctional Phosphorus/Boron Systems RUTHENIUM-CONTAINING POLYOXOTUNGSTATES: STRUCTURE AND REDOX ACTIVITY Introduction The Organoruthenium(II)-Containing 49-Tungsto-8-Phosphate[{K(H2O)}3{Ro(p-cymene)()H2O)}4P8W49O186(H 2O)2]27- The Mono-Ruthenium(III)-Substituted Keggin-Type 11-Tungstosilicate [alpha-SiW11O39Ru111(H2=)]5- and its Dimerization FROM NO TO PEROXIDE ACTIVATION BY MODEL IRON(III) COMPLEXES Introduction NO Activation by Fe(III) Complexes Peroxide Activation by Fe(III) Complexes SYNTHETIC NITROGEN FIXATION WITH MOLYBDENUM AND TUNGSTEN PHOSPHINE COMPLEXES: NEW DEVELOPMENTS Introduction Mechanistic Investigation of the Chatt Cycle New Phosphine and Mixed P/N Ligands for Synthetic Nitrogen Fixation DIRECTED C-H FUNCTIONALIZATIONS Introduction Results and Discussion DEVELOPMENT OF NOVEL RUTHENIUM AND IRON CATALYSTS FOR EPOXIDATION WITH HYDROGEN PEROXIDE Introduction Development of Epoxidation Catalysts Using H2O2 PENTACOORDINATING BIS(OXAZOLINE) LIGANDS WITH SECONDARY BINDING SITES FLAVIN PHOTOCATALYSTS WITH SUBSTRATE BINDING SITES Introduction Templated Flavin Photoreductions Templated Flavin Photooxidations NEW CATALYTIC CU-, PD- AND STOICHIOMETRIC MG-, ZN-MEDIATED BOND ACTIVATIONS Introduction Catalytic Activation Stoichiometric Activation FROM COBALT(II)-ACTIVATED MOLECULAR OXYGEN TO HYDROCYMETHYL-SUBSTITUTED TETRAHYDROFURANS Introduction Thermochemical Considerations Cobalt(II)-Diketonate Complexes Reactivity Stereoselectivity Survey A Derivative of Magnosalicin Expanding the Scope REGIODIVERGENT EPOXIDE OPENING Epoxide Opening via Nucleophilic Substitution: Limitations Arising from the SN2-Mechanism Regiodivergent Epoxide Opening (REO): Mechanistic Implications, Synthetic Potential, and Aspects of Catalyst Design Reductive Epoxide Opening via Electron Transfer from Titanocene(III) Reagents Synthetic Realization of Titanocene-Catalyzed REO SUPRAMOLECULAR CONTAINERS: HOST-GUEST CHEMISTRY AND REACTIVITY Introduction M4L4Tetrahedra Amino Acid-Bridged Dinuclear Titanium(IV) Complexes as Metalloenzyme Mimicry SELF-ASSEMBLY OF DINUCLEAR HELICAL METALLOSUPRAMOLECULAR COORDINATION COMPOUNDS Introduction The Concept of Diastereoselective Self-Assembly of Dinuclear Helicates Synthesis of Building Blocks for the Covalent Assembly of Bis(Chelating) Ligands Synthesis of Bis(Chelating) Ligands and Their Dinuclear Metal Complexes.
  • (source: Nielsen Book Data)
The use of secondary interactions for the activation of non-reactive substrates constitutes a new and modern approach in catalysis. This first comprehensive treatment of this important research field covers the entire field and reveals the links between the various chemical disciplines. It thus adopts an interdisciplinary approach, making it of interest to the whole chemical community. This book is a must for organic, inorganic, catalytic and complex chemists, as well as those working with/on organometallics.
(source: Nielsen Book Data)
dx.doi.org Wiley Online Library
Chemistry & ChemEng Library (Swain)
Status of items at Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) Status
Stacks
QD505 .A28 2009 Unknown

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