Search results
144 results
- Book
- xviii, 682 pages : illustrations ; 25 cm
Summary
"A new concise and accessible textbook treating the essentials of kinetics, catalysis and chemical reactor engineering. The didactic approach is suited for undergraduate students in chemical engineering and for students in other exact science and engineering disciplines. Each part of theory is supported with a worked example and a number of exercises are included. This book distinguishes itself from the major textbooks in chemical reactor engineering by the part on laboratory practice that it presents, in which theory is applied and illustrated in kinetic and reactor experiments. Teacher support material is available upon course adoption"-- Provided by publisher.
"A new concise and accessible textbook treating the essentials of kinetics, catalysis and chemical reactor engineering. The didactic approach is suited for undergraduate students in chemical engineering and for students in other exact science and engineering disciplines. Each part of theory is supported with a worked example and a number of exercises are included. This book distinguishes itself from the major textbooks in chemical reactor engineering by the part on laboratory practice that it presents, in which theory is applied and illustrated in kinetic and reactor experiments. Teacher support material is available upon course adoption"-- Provided by publisher.
At the library
Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) | Status |
---|---|
Stacks | |
TP155 .S26 2014 | Unknown |
- Book
- 1 online resource.
Summary
- From the Contents: Single Phase Flow
- Elementary Kinetic Theory of Gases
- Multiphase Flow
- Flows of Granular Materials
- Interfacial Transport Phenomena Closures
- Chemical Reaction Engineering
- Agitation and Fluid Mixing Technology
- Bubble Column Reactors
- The Population Balance Equation.
- From the Contents: Single Phase Flow
- Elementary Kinetic Theory of Gases
- Multiphase Flow
- Flows of Granular Materials
- Interfacial Transport Phenomena Closures
- Chemical Reaction Engineering
- Agitation and Fluid Mixing Technology
- Bubble Column Reactors
- The Population Balance Equation.
3. Design of multiphase reactors [2015]
- Book
- 1 online resource
Summary
"This resource offers a primer on simple design methods for multiphase reactors in the chemical process industries, particularly the fine chemicals industry. It provides the process design engineer with simple yet theoretically sound procedures. Different types of multiphase reactors are dealt with on an individual basis. The book focuses on the problem of predicting mass transfer rates in these reactors. It also contains finally worked examples that clearly illustrate how a highly complex MPR like the Stirred Tank Reactor (STR) can be designed using simple correlations which need only a scientific calculator"-- Provided by publisher.
"This resource offers a primer on simple design methods for multiphase reactors in the chemical process industries, particularly the fine chemicals industry. It provides the process design engineer with simple yet theoretically sound procedures. Different types of multiphase reactors are dealt with on an individual basis. The book focuses on the problem of predicting mass transfer rates in these reactors. It also contains finally worked examples that clearly illustrate how a highly complex MPR like the Stirred Tank Reactor (STR) can be designed using simple correlations which need only a scientific calculator"-- Provided by publisher.
- Book
- 1 online resource.
5. Engineering catalysis [2013]
- Book
- xi, 364 pages : illustrations (some color) ; 24 cm.
Summary
With well over 90 per cent of all processes in the industrial chemical production being of catalytic nature, catalysis is a mature though ever interesting topic. The idea of this book is to tackle various aspects of heterogeneous catalysis from the engineering point of view and go all the way from engineering of catalysis, catalyst preparation, characterization, reaction kinetics, mass transfer to catalytic reactors and the implementation of catalysts in chemical technology. Aimed for graduate students it is also a useful resource for professionals coming from the more academic side.
(source: Nielsen Book Data)
(source: Nielsen Book Data)
With well over 90 per cent of all processes in the industrial chemical production being of catalytic nature, catalysis is a mature though ever interesting topic. The idea of this book is to tackle various aspects of heterogeneous catalysis from the engineering point of view and go all the way from engineering of catalysis, catalyst preparation, characterization, reaction kinetics, mass transfer to catalytic reactors and the implementation of catalysts in chemical technology. Aimed for graduate students it is also a useful resource for professionals coming from the more academic side.
(source: Nielsen Book Data)
(source: Nielsen Book Data)
At the library
Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) | Status |
---|---|
Stacks | |
TP156 .C35 M87 2013 | Unknown |
- Book
- xix, 465 p. : ill.
Summary
For the second edition of 'Microreactors in Organic Chemistry and Catalysis' all chapters have been revised and updated to reflect the latest developments in this rapidly developing field. This new edition has 60% more content, and it remains a comprehensive publication covering most aspects of the topic. The use of microreactors in homogeneous, heterogeneous as well as biphasic reactions is covered in the main part of the book, together with catalytic, bioorganic and automation approaches. The initial chapters also provide a solid physical chemistry background on fluidics in microdevices. Finally, a chapter on industrial applications and developments covers recent progress in process chemistry. An excellent reference for beginners and experts alike.
(source: Nielsen Book Data)
(source: Nielsen Book Data)
For the second edition of 'Microreactors in Organic Chemistry and Catalysis' all chapters have been revised and updated to reflect the latest developments in this rapidly developing field. This new edition has 60% more content, and it remains a comprehensive publication covering most aspects of the topic. The use of microreactors in homogeneous, heterogeneous as well as biphasic reactions is covered in the main part of the book, together with catalytic, bioorganic and automation approaches. The initial chapters also provide a solid physical chemistry background on fluidics in microdevices. Finally, a chapter on industrial applications and developments covers recent progress in process chemistry. An excellent reference for beginners and experts alike.
(source: Nielsen Book Data)
(source: Nielsen Book Data)
- Book
- 1 online resource (xix, 465 p.) : ill.
Summary
For the second edition of 'Microreactors in Organic Chemistry and Catalysis' all chapters have been revised and updated to reflect the latest developments in this rapidly developing field. This new edition has 60% more content, and it remains a comprehensive publication covering most aspects of the topic. The use of microreactors in homogeneous, heterogeneous as well as biphasic reactions is covered in the main part of the book, together with catalytic, bioorganic and automation approaches. The initial chapters also provide a solid physical chemistry background on fluidics in microdevices. Finally, a chapter on industrial applications and developments covers recent progress in process chemistry. An excellent reference for beginners and experts alike.
(source: Nielsen Book Data)
(source: Nielsen Book Data)
For the second edition of 'Microreactors in Organic Chemistry and Catalysis' all chapters have been revised and updated to reflect the latest developments in this rapidly developing field. This new edition has 60% more content, and it remains a comprehensive publication covering most aspects of the topic. The use of microreactors in homogeneous, heterogeneous as well as biphasic reactions is covered in the main part of the book, together with catalytic, bioorganic and automation approaches. The initial chapters also provide a solid physical chemistry background on fluidics in microdevices. Finally, a chapter on industrial applications and developments covers recent progress in process chemistry. An excellent reference for beginners and experts alike.
(source: Nielsen Book Data)
(source: Nielsen Book Data)
8. Chemical reactor analysis and applications for the practicing engineer [electronic resource] [2012]
- Book
- 1 online resource (xvi, 572 p.) : ill.
Summary
(source: Nielsen Book Data)
(source: Nielsen Book Data)
- Preface xi Overview xiii Part I. Introduction 1. History of Chemical Reactions 3 2. The Field of Chemistry 11 3. Process Variables 19 4. Kinetic Principles 45 5. Stoichiometry and Conversion Variables 73 Part II. Traditional Reactor Analysis 6. Reaction and Reactor Classification 111 7. The Conservation Laws 127 8. Batch Reactors 147 9. Continuous Stirred Tank Reactors (CSTRs)181 10. Tubular Flow Reactors 209 11. Reactor Comparisons 243 Part III. Reactor Applications 12. Thermal Effects 273 13. Interpretation of Kinetic Data 14. Non-Ideal Reactors 357 15. Reactor Design Considerations 383 Part IV. Other Reactor Topics 16. Catalysts 413 17. Catalytic Reactions 429 18. Fluidized and Fixed Bed Reactors 445 19. Biochemical Reactors 475 20. Open-Ended Problems 505 21. Abet-Related Topic 519 Appendix. SI Units.
- (source: Nielsen Book Data)
(source: Nielsen Book Data)
- Preface xi Overview xiii Part I. Introduction 1. History of Chemical Reactions 3 2. The Field of Chemistry 11 3. Process Variables 19 4. Kinetic Principles 45 5. Stoichiometry and Conversion Variables 73 Part II. Traditional Reactor Analysis 6. Reaction and Reactor Classification 111 7. The Conservation Laws 127 8. Batch Reactors 147 9. Continuous Stirred Tank Reactors (CSTRs)181 10. Tubular Flow Reactors 209 11. Reactor Comparisons 243 Part III. Reactor Applications 12. Thermal Effects 273 13. Interpretation of Kinetic Data 14. Non-Ideal Reactors 357 15. Reactor Design Considerations 383 Part IV. Other Reactor Topics 16. Catalysts 413 17. Catalytic Reactions 429 18. Fluidized and Fixed Bed Reactors 445 19. Biochemical Reactors 475 20. Open-Ended Problems 505 21. Abet-Related Topic 519 Appendix. SI Units.
- (source: Nielsen Book Data)
(source: Nielsen Book Data)
9. Chemical reactor analysis and applications for the practicing engineer [electronic resource] [2012]
- Book
- xvi, 575 p. : ill.
Summary
(source: Nielsen Book Data)
(source: Nielsen Book Data)
- Preface xi Overview xiii Part I. Introduction 1. History of Chemical Reactions 3 2. The Field of Chemistry 11 3. Process Variables 19 4. Kinetic Principles 45 5. Stoichiometry and Conversion Variables 73 Part II. Traditional Reactor Analysis 6. Reaction and Reactor Classification 111 7. The Conservation Laws 127 8. Batch Reactors 147 9. Continuous Stirred Tank Reactors (CSTRs)181 10. Tubular Flow Reactors 209 11. Reactor Comparisons 243 Part III. Reactor Applications 12. Thermal Effects 273 13. Interpretation of Kinetic Data 14. Non-Ideal Reactors 357 15. Reactor Design Considerations 383 Part IV. Other Reactor Topics 16. Catalysts 413 17. Catalytic Reactions 429 18. Fluidized and Fixed Bed Reactors 445 19. Biochemical Reactors 475 20. Open-Ended Problems 505 21. Abet-Related Topic 519 Appendix. SI Units.
- (source: Nielsen Book Data)
(source: Nielsen Book Data)
- Preface xi Overview xiii Part I. Introduction 1. History of Chemical Reactions 3 2. The Field of Chemistry 11 3. Process Variables 19 4. Kinetic Principles 45 5. Stoichiometry and Conversion Variables 73 Part II. Traditional Reactor Analysis 6. Reaction and Reactor Classification 111 7. The Conservation Laws 127 8. Batch Reactors 147 9. Continuous Stirred Tank Reactors (CSTRs)181 10. Tubular Flow Reactors 209 11. Reactor Comparisons 243 Part III. Reactor Applications 12. Thermal Effects 273 13. Interpretation of Kinetic Data 14. Non-Ideal Reactors 357 15. Reactor Design Considerations 383 Part IV. Other Reactor Topics 16. Catalysts 413 17. Catalytic Reactions 429 18. Fluidized and Fixed Bed Reactors 445 19. Biochemical Reactors 475 20. Open-Ended Problems 505 21. Abet-Related Topic 519 Appendix. SI Units.
- (source: Nielsen Book Data)
(source: Nielsen Book Data)
10. Introduction to chemical reactor analysis [2013]
- Book
- xxxi, 532 pages : illustrations ; 26 cm
Summary
(source: Nielsen Book Data)
(source: Nielsen Book Data)
- Introduction Process Development Basic Building Blocks of Chemical Reaction Engineering Outline of the Book Introduction to Chemical Reactions Classification and Types of Reactors Reactor Performance Measures Introduction to Rate Function Transport Phenomena in Reactors Numerical Methods References The Thermodynamics of Chemical Reactions Basic Definitions Energy Changes in Systems Chemical Reaction Equilibrium Summary Problems References Mole Balances in Ideal Reactors General Mole Balance Equation Perfectly Mixed Batch Reactor Plug Flow Reactor Continuous Stirred Tank Reactor Reaction Rate in Terms of Catalyst Mass Comparison of PFR and CSTR Performance Multiple Reactions Multiple-Reactor Systems Further Thoughts on Defining Conversion Transient Reactor Operation Summary Problems Energy Balances in Ideal Reactors Influence of Temperature on Reactor Operation General Energy Balance Batch Reactor Plug Flow Reactor Continuous Stirred Tank Reactor Summary Problems References Chemical Kinetics for Homogeneous Reactions General Nature of Rate Functions Reaction Mechanism Theoretical Analysis of Reaction Rate Rate Equations for Nonelementary Reactions Mechanisms and Models Experimental Methods in Rate Data Collection and Analysis Summary Problems Nonideal Reactor Analysis Causes of Nonideal Reactor Behavior Residence Time and Mixing RTD Function RTD in Ideal Reactors Modeling RTD Mixing in Chemical Reactors Summary Problems References Introduction to Catalysis Origins of Catalysis: Historical Perspectives Definitions and Fundamental Concepts Thermodynamics Catalyst Types and Basic Structure Classification of Vapor-Phase Reactions Basic Steps in Heterogeneous Catalytic Reactions Introduction to Catalytic Reactors Summary Kinetics of Catalytic Reactions Adsorption Rate Expressions for Catalytic Reactions Mechanisms and Models Summary Problems Reference Transport Processes in Catalysis Diffusion in Bulk Phase External Mass and Heat Transfer Effects Diffusion in Porous Catalysts Diffusion with Reaction in Porous Catalysts Summary Problems References Analysis of Catalytic Reactors Packed-Bed Reactor: Introduction and Overview Conservation Equations for Packed Beds One-Dimensional Steady-State Plug Flow Models One-Dimensional Steady-State Axial Dispersion Models Two-Dimensional Steady-State Models Transient Packed-Bed Models Transport Properties in Packed Beds Autothermal Operation of Packed Beds Fluidized-Bed Reactors Metal Gauze Reactors Counter Diffusive Reactor: Radiant Heaters Monolith Reactors Reactors for Gas-Liquid-Solid Systems Summary Problems References Experimental Methods in Catalysis Kinetic Investigations Measuring Physical Properties Electron Microscopy Surface Science Studies Summary Problems References Appendix 1: Numerical Methods Nonlinear Algebraic Equations Linear Algebraic Equations Ordinary Differential Equations Numerical Integration Numerical Differentiation Partial Differential Equations Appendix 2: Thermodynamic Data Appendix 3: Useful Integrals Appendix 4: Numerical Software POLYMATH MATLAB(R) COMSOL Multiphysics Index.
- (source: Nielsen Book Data)
(source: Nielsen Book Data)
- Introduction Process Development Basic Building Blocks of Chemical Reaction Engineering Outline of the Book Introduction to Chemical Reactions Classification and Types of Reactors Reactor Performance Measures Introduction to Rate Function Transport Phenomena in Reactors Numerical Methods References The Thermodynamics of Chemical Reactions Basic Definitions Energy Changes in Systems Chemical Reaction Equilibrium Summary Problems References Mole Balances in Ideal Reactors General Mole Balance Equation Perfectly Mixed Batch Reactor Plug Flow Reactor Continuous Stirred Tank Reactor Reaction Rate in Terms of Catalyst Mass Comparison of PFR and CSTR Performance Multiple Reactions Multiple-Reactor Systems Further Thoughts on Defining Conversion Transient Reactor Operation Summary Problems Energy Balances in Ideal Reactors Influence of Temperature on Reactor Operation General Energy Balance Batch Reactor Plug Flow Reactor Continuous Stirred Tank Reactor Summary Problems References Chemical Kinetics for Homogeneous Reactions General Nature of Rate Functions Reaction Mechanism Theoretical Analysis of Reaction Rate Rate Equations for Nonelementary Reactions Mechanisms and Models Experimental Methods in Rate Data Collection and Analysis Summary Problems Nonideal Reactor Analysis Causes of Nonideal Reactor Behavior Residence Time and Mixing RTD Function RTD in Ideal Reactors Modeling RTD Mixing in Chemical Reactors Summary Problems References Introduction to Catalysis Origins of Catalysis: Historical Perspectives Definitions and Fundamental Concepts Thermodynamics Catalyst Types and Basic Structure Classification of Vapor-Phase Reactions Basic Steps in Heterogeneous Catalytic Reactions Introduction to Catalytic Reactors Summary Kinetics of Catalytic Reactions Adsorption Rate Expressions for Catalytic Reactions Mechanisms and Models Summary Problems Reference Transport Processes in Catalysis Diffusion in Bulk Phase External Mass and Heat Transfer Effects Diffusion in Porous Catalysts Diffusion with Reaction in Porous Catalysts Summary Problems References Analysis of Catalytic Reactors Packed-Bed Reactor: Introduction and Overview Conservation Equations for Packed Beds One-Dimensional Steady-State Plug Flow Models One-Dimensional Steady-State Axial Dispersion Models Two-Dimensional Steady-State Models Transient Packed-Bed Models Transport Properties in Packed Beds Autothermal Operation of Packed Beds Fluidized-Bed Reactors Metal Gauze Reactors Counter Diffusive Reactor: Radiant Heaters Monolith Reactors Reactors for Gas-Liquid-Solid Systems Summary Problems References Experimental Methods in Catalysis Kinetic Investigations Measuring Physical Properties Electron Microscopy Surface Science Studies Summary Problems References Appendix 1: Numerical Methods Nonlinear Algebraic Equations Linear Algebraic Equations Ordinary Differential Equations Numerical Integration Numerical Differentiation Partial Differential Equations Appendix 2: Thermodynamic Data Appendix 3: Useful Integrals Appendix 4: Numerical Software POLYMATH MATLAB(R) COMSOL Multiphysics Index.
- (source: Nielsen Book Data)
(source: Nielsen Book Data)
At the library
Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) | Status |
---|---|
Stacks | |
TP157 .H35 2013 | Unknown |
- Book
- 1 online resource (608 p.)
Summary
This comprehensive review, prepared by 24 experts, many of whom are pioneers of the subject, brings together in one place over 40 years of research in this unique publication. This book will assist R & D specialists, research chemists, chemical engineers or process managers harnessing periodic operations to improve their process plant performance. "Periodic Operation of Reactors" covers process fundamentals, research equipment and methods and provides "the state of the art" for the periodic operation of many industrially important catalytic reactions. Emphasis is on experimental results, modeling and simulation. Combined reaction and separation are dealt with, including simulated moving bed chromatographic, pressure and temperature swing and circulating bed reactors. Thus, "Periodic Operation of Reactors" offers readers a single comprehensive source for the broad and diverse new subject. This exciting new publication is a "must have" for any professional working in chemical process research and development. Key features: provides the only comprehensive reference on the fundamentals, development and applications of periodic reactor operation, using contributions from the research pioneers. This authoritative reference focuses on applications helping readers to use this book to deliver results in their own work. Complete literature references will be an invaluable assistance for readers collecting data and models from past research. About the editors: Peter L. Silveston is a Distinguished Professor Emeritus at the University of Waterloo in Canada. Professor Silveston has authored or co-authored three previous books on reactor engineering topics as well as close to 300 research publications. He is a graduate of M.I.T. and the Technical University of Munich (Germany). Robert Hudgins is a Professor Emeritus at the University of Waterloo. His research interests are reactor engineering, specifically periodic operation of catalytic reactors, and he has about 250 research publications. He is a graduate of the University of Toronto and Princeton University. Feature: a comprehensive reference on the fundamentals, development and applications of periodic operation. Benefit: provides readers with a single comprehensive source for this extremely broad and diverse subject. Feature: contributors and editors include the pioneers of the subject as well as the leading researchers in the field. Benefit: has the authority and experience of the leading players in the field. Feature: covers both fundamentals and the state of the art for each operation scenario, and brings all types of periodic operation together in a single volume. Benefit: provides a succinct reference to the most important applications in the filed, allowing readers to understand how to apply techniques or technologies to their own situation. Feature: discussion is focused on experimental results rather than theoretical ones; provides a rich source of experimental data, plus process models. Benefit: applied approach that is geared helping practicing engineers and researchers solve problems. Feature: accompanying website with modelling data. Benefit: engineers can engage with experimental and actual performance data.
(source: Nielsen Book Data)
(source: Nielsen Book Data)
This comprehensive review, prepared by 24 experts, many of whom are pioneers of the subject, brings together in one place over 40 years of research in this unique publication. This book will assist R & D specialists, research chemists, chemical engineers or process managers harnessing periodic operations to improve their process plant performance. "Periodic Operation of Reactors" covers process fundamentals, research equipment and methods and provides "the state of the art" for the periodic operation of many industrially important catalytic reactions. Emphasis is on experimental results, modeling and simulation. Combined reaction and separation are dealt with, including simulated moving bed chromatographic, pressure and temperature swing and circulating bed reactors. Thus, "Periodic Operation of Reactors" offers readers a single comprehensive source for the broad and diverse new subject. This exciting new publication is a "must have" for any professional working in chemical process research and development. Key features: provides the only comprehensive reference on the fundamentals, development and applications of periodic reactor operation, using contributions from the research pioneers. This authoritative reference focuses on applications helping readers to use this book to deliver results in their own work. Complete literature references will be an invaluable assistance for readers collecting data and models from past research. About the editors: Peter L. Silveston is a Distinguished Professor Emeritus at the University of Waterloo in Canada. Professor Silveston has authored or co-authored three previous books on reactor engineering topics as well as close to 300 research publications. He is a graduate of M.I.T. and the Technical University of Munich (Germany). Robert Hudgins is a Professor Emeritus at the University of Waterloo. His research interests are reactor engineering, specifically periodic operation of catalytic reactors, and he has about 250 research publications. He is a graduate of the University of Toronto and Princeton University. Feature: a comprehensive reference on the fundamentals, development and applications of periodic operation. Benefit: provides readers with a single comprehensive source for this extremely broad and diverse subject. Feature: contributors and editors include the pioneers of the subject as well as the leading researchers in the field. Benefit: has the authority and experience of the leading players in the field. Feature: covers both fundamentals and the state of the art for each operation scenario, and brings all types of periodic operation together in a single volume. Benefit: provides a succinct reference to the most important applications in the filed, allowing readers to understand how to apply techniques or technologies to their own situation. Feature: discussion is focused on experimental results rather than theoretical ones; provides a rich source of experimental data, plus process models. Benefit: applied approach that is geared helping practicing engineers and researchers solve problems. Feature: accompanying website with modelling data. Benefit: engineers can engage with experimental and actual performance data.
(source: Nielsen Book Data)
(source: Nielsen Book Data)
Online
www.sciencedirect.com ScienceDirect
- www.sciencedirect.com ScienceDirect
- Google Books (Full view)
- Book
- xvii, 184 p. : ill.
- Book
- 1 online resource (xxix, 707 p.) : ill.
Summary
(source: Nielsen Book Data)
(source: Nielsen Book Data)
- Preface xv About the Author xxix Chapter 1: Mole Balances 1 1.1 The Rate of Reaction, --rA 4 1.2 The General Mole Balance Equation 8 1.3 Batch Reactors (BRs) 10 1.4 Continuous-Flow Reactors 12 1.5 Industrial Reactors 22 Chapter 2: Conversion and Reactor Sizing 33 2.1 Definition of Conversion 34 2.2 Batch Reactor Design Equations 34 2.3 Design Equations for Flow Reactors 37 2.4 Sizing Continuous-Flow Reactors 40 2.5 Reactors in Series 49 2.6 Some Further Definitions 60 Chapter 3: Rate Laws 73 3.1 Basic Definitions 74 3.2 The Reaction Order and the Rate Law 76 3.3 The Reaction Rate Constant 86 3.4 Present Status of Our Approach to Reactor Sizing and Design 93 Chapter 4: Stoichiometry 105 4.1 Batch Systems 107 4.2 Flow Systems 113 Chapter 5: Isothermal Reactor Design: Conversion 139 5.1 Design Structure for Isothermal Reactors 140 5.2 Batch Reactors (BRs) 144 5.3 Continuous Stirred Tank Reactors (CSTRs) 152 5.4 Tubular Reactors 162 5.5 Pressure Drop in Reactors 169 5.6 Synthesizing the Design of a Chemical Plant 188 Chapter 6: Isothermal Reactor Design: Molar Flow Rates 207 6.1 The Molar Flow Rate Balance Algorithm 208 6.2 Mole Balances on CSTRs, PFRs, PBRs, and Batch Reactors 208 6.3 Applications of the Molar Flow Rate Algorithm to Microreactors 212 6.4 Membrane Reactors 217 6.5 Unsteady-State Operation of Stirred Reactors 225 6.6 Semibatch Reactors 226 Chapter 7: Collection and Analysis of Rate Data 245 7.1 The Algorithm for Data Analysis 246 7.2 Determining the Reaction Order for Each of Two Reactants Using the Method of Excess 248 7.3 Integral Method 249 7.4 Differential Method of Analysis 253 7.5 Nonlinear Regression 259 7.6 Reaction Rate Data from Differential Reactors 264 7.7 Experimental Planning 271 Chapter 8: Multiple Reactions 283 8.1 Definitions 283 8.2 Algorithm for Multiple Reactions 286 8.3 Parallel Reactions 289 8.4 Reactions in Series 298 8.5 Complex Reactions 308 8.6 Membrane Reactors to Improve Selectivity in Multiple Reactions 316 8.7 Sorting It All Out 321 8.8 The Fun Part 321 Chapter 9: Reaction Mechanisms, Pathways, Bioreactions, and Bioreactors 339 9.1 Active Intermediates and Nonelementary Rate Laws 340 9.2 Enzymatic Reaction Fundamentals 349 9.3 Inhibition of Enzyme Reactions 364 9.4 Bioreactors and Biosynthesis 371 Chapter 10: Catalysis and Catalytic Reactors 409 10.1 Catalysts 409 10.2 Steps in a Catalytic Reaction 415 10.3 Synthesizing a Rate Law, Mechanism, and Rate-Limiting Step 431 10.4 Heterogeneous Data Analysis for Reactor Design 446 10.5 Reaction Engineering in Microelectronic Fabrication 456 10.6 Model Discrimination 461 Chapter 11: Nonisothermal Reactor Design--The Steady State Energy Balance and Adiabatic PFR Applications 477 11.1 Rationale 478 11.2 The Energy Balance 479 11.3 The User Friendly Energy Balance Equations 486 11.4 Adiabatic Operation 492 11.5 Adiabatic Equilibrium Conversion and Reactor Staging 502 11.6 Optimum Feed Temperature 509 Chapter 12: Steady-State Nonisothermal Reactor Design--Flow Reactors with Heat Exchange 521 12.1 Steady-State Tubular Reactor with Heat Exchange 522 12.2 Balance on the Heat Transfer Fluid 525 12.3 Algorithm for PFR/PBR Design with Heat Effects 527 12.4 CSTR with Heat Effects 545 12.5 Multiple Steady States (MSS) 556 12.6 Nonisothermal Multiple Chemical Reactions 563 12.7 Safety 577 Chapter 13: Unsteady-State Nonisothermal Reactor Design 601 13.1 The Unsteady-State Energy Balance 602 13.2 Energy Balance on Batch Reactors 604 13.3 Semibatch Reactors with a Heat Exchanger 615 13.4 Unsteady Operation of a CSTR 620 13.5 Nonisothermal Multiple Reactions 624 Appendix A: Numerical Techniques 649 Appendix B: Ideal Gas Constant and Conversion Factors 655 Appendix C: Thermodynamic Relationships Involving the Equilibrium Constant 659 Appendix D: Nomenclature 665 Appendix E: Software Packages 669 E.1 Polymath 669 E.2 AspenTech 670 E.3 COMSOL 671 E.4 Software Packages 671 Appendix F: Rate Law Data 673 Appendix G: Open-Ended Problems 675 G.1 Design of Reaction Engineering Experiment 675 G.2 Effective Lubricant Design 675 G.3 Peach Bottom Nuclear Reactor 675 G.4 Underground Wet Oxidation 675 G.5 Hydrodesulfurization Reactor Design 676 G.6 Continuous Bioprocessing 676 G.7 Methanol Synthesis 676 G.8 Alcohol Metabolism 676 G.9 Methanol Poisoning 676 G.10 Cajun Seafood Gumbo 676 Appendix H: How to Use the DVD-ROM 679 H.1 DVD-ROM Components 679 H.2 How the DVD-ROM/Web Can Help Learning Styles 682 H.3 Navigation 683 Index 685.
- (source: Nielsen Book Data)
(source: Nielsen Book Data)
- Preface xv About the Author xxix Chapter 1: Mole Balances 1 1.1 The Rate of Reaction, --rA 4 1.2 The General Mole Balance Equation 8 1.3 Batch Reactors (BRs) 10 1.4 Continuous-Flow Reactors 12 1.5 Industrial Reactors 22 Chapter 2: Conversion and Reactor Sizing 33 2.1 Definition of Conversion 34 2.2 Batch Reactor Design Equations 34 2.3 Design Equations for Flow Reactors 37 2.4 Sizing Continuous-Flow Reactors 40 2.5 Reactors in Series 49 2.6 Some Further Definitions 60 Chapter 3: Rate Laws 73 3.1 Basic Definitions 74 3.2 The Reaction Order and the Rate Law 76 3.3 The Reaction Rate Constant 86 3.4 Present Status of Our Approach to Reactor Sizing and Design 93 Chapter 4: Stoichiometry 105 4.1 Batch Systems 107 4.2 Flow Systems 113 Chapter 5: Isothermal Reactor Design: Conversion 139 5.1 Design Structure for Isothermal Reactors 140 5.2 Batch Reactors (BRs) 144 5.3 Continuous Stirred Tank Reactors (CSTRs) 152 5.4 Tubular Reactors 162 5.5 Pressure Drop in Reactors 169 5.6 Synthesizing the Design of a Chemical Plant 188 Chapter 6: Isothermal Reactor Design: Molar Flow Rates 207 6.1 The Molar Flow Rate Balance Algorithm 208 6.2 Mole Balances on CSTRs, PFRs, PBRs, and Batch Reactors 208 6.3 Applications of the Molar Flow Rate Algorithm to Microreactors 212 6.4 Membrane Reactors 217 6.5 Unsteady-State Operation of Stirred Reactors 225 6.6 Semibatch Reactors 226 Chapter 7: Collection and Analysis of Rate Data 245 7.1 The Algorithm for Data Analysis 246 7.2 Determining the Reaction Order for Each of Two Reactants Using the Method of Excess 248 7.3 Integral Method 249 7.4 Differential Method of Analysis 253 7.5 Nonlinear Regression 259 7.6 Reaction Rate Data from Differential Reactors 264 7.7 Experimental Planning 271 Chapter 8: Multiple Reactions 283 8.1 Definitions 283 8.2 Algorithm for Multiple Reactions 286 8.3 Parallel Reactions 289 8.4 Reactions in Series 298 8.5 Complex Reactions 308 8.6 Membrane Reactors to Improve Selectivity in Multiple Reactions 316 8.7 Sorting It All Out 321 8.8 The Fun Part 321 Chapter 9: Reaction Mechanisms, Pathways, Bioreactions, and Bioreactors 339 9.1 Active Intermediates and Nonelementary Rate Laws 340 9.2 Enzymatic Reaction Fundamentals 349 9.3 Inhibition of Enzyme Reactions 364 9.4 Bioreactors and Biosynthesis 371 Chapter 10: Catalysis and Catalytic Reactors 409 10.1 Catalysts 409 10.2 Steps in a Catalytic Reaction 415 10.3 Synthesizing a Rate Law, Mechanism, and Rate-Limiting Step 431 10.4 Heterogeneous Data Analysis for Reactor Design 446 10.5 Reaction Engineering in Microelectronic Fabrication 456 10.6 Model Discrimination 461 Chapter 11: Nonisothermal Reactor Design--The Steady State Energy Balance and Adiabatic PFR Applications 477 11.1 Rationale 478 11.2 The Energy Balance 479 11.3 The User Friendly Energy Balance Equations 486 11.4 Adiabatic Operation 492 11.5 Adiabatic Equilibrium Conversion and Reactor Staging 502 11.6 Optimum Feed Temperature 509 Chapter 12: Steady-State Nonisothermal Reactor Design--Flow Reactors with Heat Exchange 521 12.1 Steady-State Tubular Reactor with Heat Exchange 522 12.2 Balance on the Heat Transfer Fluid 525 12.3 Algorithm for PFR/PBR Design with Heat Effects 527 12.4 CSTR with Heat Effects 545 12.5 Multiple Steady States (MSS) 556 12.6 Nonisothermal Multiple Chemical Reactions 563 12.7 Safety 577 Chapter 13: Unsteady-State Nonisothermal Reactor Design 601 13.1 The Unsteady-State Energy Balance 602 13.2 Energy Balance on Batch Reactors 604 13.3 Semibatch Reactors with a Heat Exchanger 615 13.4 Unsteady Operation of a CSTR 620 13.5 Nonisothermal Multiple Reactions 624 Appendix A: Numerical Techniques 649 Appendix B: Ideal Gas Constant and Conversion Factors 655 Appendix C: Thermodynamic Relationships Involving the Equilibrium Constant 659 Appendix D: Nomenclature 665 Appendix E: Software Packages 669 E.1 Polymath 669 E.2 AspenTech 670 E.3 COMSOL 671 E.4 Software Packages 671 Appendix F: Rate Law Data 673 Appendix G: Open-Ended Problems 675 G.1 Design of Reaction Engineering Experiment 675 G.2 Effective Lubricant Design 675 G.3 Peach Bottom Nuclear Reactor 675 G.4 Underground Wet Oxidation 675 G.5 Hydrodesulfurization Reactor Design 676 G.6 Continuous Bioprocessing 676 G.7 Methanol Synthesis 676 G.8 Alcohol Metabolism 676 G.9 Methanol Poisoning 676 G.10 Cajun Seafood Gumbo 676 Appendix H: How to Use the DVD-ROM 679 H.1 DVD-ROM Components 679 H.2 How the DVD-ROM/Web Can Help Learning Styles 682 H.3 Navigation 683 Index 685.
- (source: Nielsen Book Data)
(source: Nielsen Book Data)
Online
proquest.safaribooksonline.com Safari Books Online
- proquest.safaribooksonline.com Safari Books Online
- Google Books (Full view)
- Book
- 1 online resource (xxviii, 315 p.) : ill.
Summary
- List of Figures
- List of Tables
- Preface
- Nomenclature
- Introduction
- Part One. Bubble Columns
- Sparged Stirred Vessels
- Thin Film Reactors
- Macroscale Modelling
- Mesoscale Modelling Using the Lattice Boltzmann Method
- Part Two. Upset Conditions
- Behaviour of Vessel Contents and Outflow Calculations
- Choked Flow
- Part Three. Measurement Techniques
- Index.
- List of Figures
- List of Tables
- Preface
- Nomenclature
- Introduction
- Part One. Bubble Columns
- Sparged Stirred Vessels
- Thin Film Reactors
- Macroscale Modelling
- Mesoscale Modelling Using the Lattice Boltzmann Method
- Part Two. Upset Conditions
- Behaviour of Vessel Contents and Outflow Calculations
- Choked Flow
- Part Three. Measurement Techniques
- Index.
- Book
- 1 online resource (xxv, 372 p.) : ill.
Summary
(source: Nielsen Book Data)
(source: Nielsen Book Data)
- Engineering Hierarchically Architectured Zeolites by Demetallation Au Allows Catalysis at Room Temperature The Fascinating Structure and the Potential of Metal Organic Frameworks (MOFs) Enzymatic Catalysis Today and Tomorrow The Wonderful World of Fenton Chemistry in Solid Catalyst Synthesis Challenges in Catalysis for Sustainability Catalytic Processing of Biomass into Chemicals Structured Reactors, a Wealth of Opportunities Zeolite Membranes in Catalysis: What is New and How Bright is the Future Microstructures on Macroscale: Microchannel Reactors for Medium- and Large-Size Processes Intensification of Heat Transfer in Chemical Reactors: Heat Exchanger Reactors Reactors Using Alternative Energy Forms for Green Synthetic Routes, New Functional Products and Nanotechnology Switching from Batch to Continuous Processing for Fine and Intermediate Scale Chemicals Manufacture Progress in Methods for Identification of Micro- and Macroscale Physical Phenomena in Chemical Reactors: Improvements in Scale-Up of Chemical Reactors.
- (source: Nielsen Book Data)
(source: Nielsen Book Data)
- Engineering Hierarchically Architectured Zeolites by Demetallation Au Allows Catalysis at Room Temperature The Fascinating Structure and the Potential of Metal Organic Frameworks (MOFs) Enzymatic Catalysis Today and Tomorrow The Wonderful World of Fenton Chemistry in Solid Catalyst Synthesis Challenges in Catalysis for Sustainability Catalytic Processing of Biomass into Chemicals Structured Reactors, a Wealth of Opportunities Zeolite Membranes in Catalysis: What is New and How Bright is the Future Microstructures on Macroscale: Microchannel Reactors for Medium- and Large-Size Processes Intensification of Heat Transfer in Chemical Reactors: Heat Exchanger Reactors Reactors Using Alternative Energy Forms for Green Synthetic Routes, New Functional Products and Nanotechnology Switching from Batch to Continuous Processing for Fine and Intermediate Scale Chemicals Manufacture Progress in Methods for Identification of Micro- and Macroscale Physical Phenomena in Chemical Reactors: Improvements in Scale-Up of Chemical Reactors.
- (source: Nielsen Book Data)
(source: Nielsen Book Data)
16. Chemical reactions and chemical reactors [2009]
- Book
- xix, 452 p. : ill. ; 26 cm.
Summary
(source: Nielsen Book Data)
(source: Nielsen Book Data)
- 1. Reactions and Reaction Rates. 2. Reaction Rates-Some Generalizations. 3. Ideal Reactors. 4. Sizing and Analysis of Ideal Reactors. 5. Reaction Rate Fundamentals (Chemical Kinetics). 6. Analysis of Experimental Kinetic Data. 7. Multiple Reactions. 8. Use of the Energy Balance in reactor Sizing and Analysis. 9. Heterogeneous Catalysis Revisited. 10. "Nonideal" Reactors. Nomenclature. Index.
- (source: Nielsen Book Data)
(source: Nielsen Book Data)
- 1. Reactions and Reaction Rates. 2. Reaction Rates-Some Generalizations. 3. Ideal Reactors. 4. Sizing and Analysis of Ideal Reactors. 5. Reaction Rate Fundamentals (Chemical Kinetics). 6. Analysis of Experimental Kinetic Data. 7. Multiple Reactions. 8. Use of the Energy Balance in reactor Sizing and Analysis. 9. Heterogeneous Catalysis Revisited. 10. "Nonideal" Reactors. Nomenclature. Index.
- (source: Nielsen Book Data)
(source: Nielsen Book Data)
At the library
Chemistry & ChemEng Library (Swain)
Chemistry & ChemEng Library (Swain) | Status |
---|---|
Stacks | |
QD501 .R66 2009 | Unknown |
17. Development of a reactor model for chemical conversion of Lunar regolith [electronic resource] [2009]
- Book
- 1 online resource (10 p.) : ill.
- Book
- xviii, 473 p. : ill.
Summary
(source: Nielsen Book Data)
(source: Nielsen Book Data)
- Preface. Notation. Chapter 1: Overview of Chemical Reaction Engineering. 1.1 Classification of Chemical Reactions. 1.2 Classification of Chemical Reactors. 1.3 Phenomena and Concepts. 1.4 Common Practices. 1.5 Industrial Reactors. 1.6 Summary. Bibliography. Chapter 2: Stoichiometry . 2.1 The Four Contexts of "Chemical Reactions". 2.2 Chemical Formula and Stoichiometic Relations. 2.3 Reaction Extent. 2.4 Independent and Dependent Chemical Reactions. 2.5 Characterization of Reactor Feed. 2.6 Characterization of Reactor Performance. 2.7 Dimensionless Extents. 2.8 Independent Species Specifications. 2.9 Summary. Bibliography. Problems. Chapter 3: Chemical Kinetics. 3.1 Species Formation Rates. 3.2 Rates of Chemical Reactions. 3.3 Rate Expressions of Reaction Rates. 3.4 Effects of Transport Limitations. 3.5 Characteristic Reaction Time. 3.6 Summary. Bibliography. Problems. Chapter 4: Species Balances and Design Equations. 4.1 Macroscopic Species Balances - General Species-based Design Equations. 4.2 Species-based Design Equations of Ideal Reactors. 4.3 Reaction-based Design Equations. 4.4 Dimensionless Design Equations. 4.5 Summary. Bibliography. Problems. Chapter 5: Energy Balances. 5.1 Review of Thermodynamic Relations. 5.2 Energy Balances. 5.3 Summary. Bibliography. Problems. Chapter 6: Ideal Batch Reactor. 6.1 Design Equations and Auxiliary Relations. 6.2 Isothermal Operations with Single Reactions. 6.3 Isothermal Operations with Multiple Reactions. 6.4 Non-Isothermal Operations. 6.5 Summary. Problems. Chapter 7: Plug Flow Reactor. 7.1 Design Equations and Auxiliary Relations. 7.2 Isothermal Operations with Single Reactions. 7.3 Isothermal Operations with Multiple Reactions. 7.4 Non-Isothermal Operations. 7.5 Effects of Pressure Drop. 7.6 Summary. Problems. Chapter 8: Continuous Stirred Tank Reactor (CSTR). 8.1 Design Equations and Auxiliary Relations. 8.2 Isothermal Operations with Single Reactions. 8.3 Isothermal Operations with Multiple Reactions. 8.4 Non-Isothermal Operations. 8.5 Summary. Problems. Chapter 9: Other Reactor Configurations. 9.1 Semi-Batch Reactors. 9.2 Plug-Flow Reactor with Distributed Feed. 9.3 Distillation Reactor. 9.4 Recycle Reactor. 9.5 Summary. Problems. Chapter 10: Economic-Based Optimization of Reactor Operations. 10.1 Economic Objective Functions. 10.2 Batch and Semi-Batch Reactors. 10.3 Flow Reactors. 10.4 Summary. Problems. Appendices. Appendix A: Summary of Key Relationships. Appendix B: Microscopic Species Balances - Continuity Equations. Appendix C: Summary of Numerical Methods. Index.
- (source: Nielsen Book Data)
(source: Nielsen Book Data)
- Preface. Notation. Chapter 1: Overview of Chemical Reaction Engineering. 1.1 Classification of Chemical Reactions. 1.2 Classification of Chemical Reactors. 1.3 Phenomena and Concepts. 1.4 Common Practices. 1.5 Industrial Reactors. 1.6 Summary. Bibliography. Chapter 2: Stoichiometry . 2.1 The Four Contexts of "Chemical Reactions". 2.2 Chemical Formula and Stoichiometic Relations. 2.3 Reaction Extent. 2.4 Independent and Dependent Chemical Reactions. 2.5 Characterization of Reactor Feed. 2.6 Characterization of Reactor Performance. 2.7 Dimensionless Extents. 2.8 Independent Species Specifications. 2.9 Summary. Bibliography. Problems. Chapter 3: Chemical Kinetics. 3.1 Species Formation Rates. 3.2 Rates of Chemical Reactions. 3.3 Rate Expressions of Reaction Rates. 3.4 Effects of Transport Limitations. 3.5 Characteristic Reaction Time. 3.6 Summary. Bibliography. Problems. Chapter 4: Species Balances and Design Equations. 4.1 Macroscopic Species Balances - General Species-based Design Equations. 4.2 Species-based Design Equations of Ideal Reactors. 4.3 Reaction-based Design Equations. 4.4 Dimensionless Design Equations. 4.5 Summary. Bibliography. Problems. Chapter 5: Energy Balances. 5.1 Review of Thermodynamic Relations. 5.2 Energy Balances. 5.3 Summary. Bibliography. Problems. Chapter 6: Ideal Batch Reactor. 6.1 Design Equations and Auxiliary Relations. 6.2 Isothermal Operations with Single Reactions. 6.3 Isothermal Operations with Multiple Reactions. 6.4 Non-Isothermal Operations. 6.5 Summary. Problems. Chapter 7: Plug Flow Reactor. 7.1 Design Equations and Auxiliary Relations. 7.2 Isothermal Operations with Single Reactions. 7.3 Isothermal Operations with Multiple Reactions. 7.4 Non-Isothermal Operations. 7.5 Effects of Pressure Drop. 7.6 Summary. Problems. Chapter 8: Continuous Stirred Tank Reactor (CSTR). 8.1 Design Equations and Auxiliary Relations. 8.2 Isothermal Operations with Single Reactions. 8.3 Isothermal Operations with Multiple Reactions. 8.4 Non-Isothermal Operations. 8.5 Summary. Problems. Chapter 9: Other Reactor Configurations. 9.1 Semi-Batch Reactors. 9.2 Plug-Flow Reactor with Distributed Feed. 9.3 Distillation Reactor. 9.4 Recycle Reactor. 9.5 Summary. Problems. Chapter 10: Economic-Based Optimization of Reactor Operations. 10.1 Economic Objective Functions. 10.2 Batch and Semi-Batch Reactors. 10.3 Flow Reactors. 10.4 Summary. Problems. Appendices. Appendix A: Summary of Key Relationships. Appendix B: Microscopic Species Balances - Continuity Equations. Appendix C: Summary of Numerical Methods. Index.
- (source: Nielsen Book Data)
(source: Nielsen Book Data)
- Book
- xviii, 473 p. : ill. ; 26 cm.
Summary
(source: Nielsen Book Data)
(source: Nielsen Book Data)
- Preface. Notation. Chapter 1: Overview of Chemical Reaction Engineering. 1.1 Classification of Chemical Reactions. 1.2 Classification of Chemical Reactors. 1.3 Phenomena and Concepts. 1.4 Common Practices. 1.5 Industrial Reactors. 1.6 Summary. Bibliography. Chapter 2: Stoichiometry . 2.1 The Four Contexts of "Chemical Reactions". 2.2 Chemical Formula and Stoichiometic Relations. 2.3 Reaction Extent. 2.4 Independent and Dependent Chemical Reactions. 2.5 Characterization of Reactor Feed. 2.6 Characterization of Reactor Performance. 2.7 Dimensionless Extents. 2.8 Independent Species Specifications. 2.9 Summary. Bibliography. Problems. Chapter 3: Chemical Kinetics. 3.1 Species Formation Rates. 3.2 Rates of Chemical Reactions. 3.3 Rate Expressions of Reaction Rates. 3.4 Effects of Transport Limitations. 3.5 Characteristic Reaction Time. 3.6 Summary. Bibliography. Problems. Chapter 4: Species Balances and Design Equations. 4.1 Macroscopic Species Balances - General Species-based Design Equations. 4.2 Species-based Design Equations of Ideal Reactors. 4.3 Reaction-based Design Equations. 4.4 Dimensionless Design Equations. 4.5 Summary. Bibliography. Problems. Chapter 5: Energy Balances. 5.1 Review of Thermodynamic Relations. 5.2 Energy Balances. 5.3 Summary. Bibliography. Problems. Chapter 6: Ideal Batch Reactor. 6.1 Design Equations and Auxiliary Relations. 6.2 Isothermal Operations with Single Reactions. 6.3 Isothermal Operations with Multiple Reactions. 6.4 Non-Isothermal Operations. 6.5 Summary. Problems. Chapter 7: Plug Flow Reactor. 7.1 Design Equations and Auxiliary Relations. 7.2 Isothermal Operations with Single Reactions. 7.3 Isothermal Operations with Multiple Reactions. 7.4 Non-Isothermal Operations. 7.5 Effects of Pressure Drop. 7.6 Summary. Problems. Chapter 8: Continuous Stirred Tank Reactor (CSTR). 8.1 Design Equations and Auxiliary Relations. 8.2 Isothermal Operations with Single Reactions. 8.3 Isothermal Operations with Multiple Reactions. 8.4 Non-Isothermal Operations. 8.5 Summary. Problems. Chapter 9: Other Reactor Configurations. 9.1 Semi-Batch Reactors. 9.2 Plug-Flow Reactor with Distributed Feed. 9.3 Distillation Reactor. 9.4 Recycle Reactor. 9.5 Summary. Problems. Chapter 10: Economic-Based Optimization of Reactor Operations. 10.1 Economic Objective Functions. 10.2 Batch and Semi-Batch Reactors. 10.3 Flow Reactors. 10.4 Summary. Problems. Appendices. Appendix A: Summary of Key Relationships. Appendix B: Microscopic Species Balances - Continuity Equations. Appendix C: Summary of Numerical Methods. Index.
- (source: Nielsen Book Data)
(source: Nielsen Book Data)
- Preface. Notation. Chapter 1: Overview of Chemical Reaction Engineering. 1.1 Classification of Chemical Reactions. 1.2 Classification of Chemical Reactors. 1.3 Phenomena and Concepts. 1.4 Common Practices. 1.5 Industrial Reactors. 1.6 Summary. Bibliography. Chapter 2: Stoichiometry . 2.1 The Four Contexts of "Chemical Reactions". 2.2 Chemical Formula and Stoichiometic Relations. 2.3 Reaction Extent. 2.4 Independent and Dependent Chemical Reactions. 2.5 Characterization of Reactor Feed. 2.6 Characterization of Reactor Performance. 2.7 Dimensionless Extents. 2.8 Independent Species Specifications. 2.9 Summary. Bibliography. Problems. Chapter 3: Chemical Kinetics. 3.1 Species Formation Rates. 3.2 Rates of Chemical Reactions. 3.3 Rate Expressions of Reaction Rates. 3.4 Effects of Transport Limitations. 3.5 Characteristic Reaction Time. 3.6 Summary. Bibliography. Problems. Chapter 4: Species Balances and Design Equations. 4.1 Macroscopic Species Balances - General Species-based Design Equations. 4.2 Species-based Design Equations of Ideal Reactors. 4.3 Reaction-based Design Equations. 4.4 Dimensionless Design Equations. 4.5 Summary. Bibliography. Problems. Chapter 5: Energy Balances. 5.1 Review of Thermodynamic Relations. 5.2 Energy Balances. 5.3 Summary. Bibliography. Problems. Chapter 6: Ideal Batch Reactor. 6.1 Design Equations and Auxiliary Relations. 6.2 Isothermal Operations with Single Reactions. 6.3 Isothermal Operations with Multiple Reactions. 6.4 Non-Isothermal Operations. 6.5 Summary. Problems. Chapter 7: Plug Flow Reactor. 7.1 Design Equations and Auxiliary Relations. 7.2 Isothermal Operations with Single Reactions. 7.3 Isothermal Operations with Multiple Reactions. 7.4 Non-Isothermal Operations. 7.5 Effects of Pressure Drop. 7.6 Summary. Problems. Chapter 8: Continuous Stirred Tank Reactor (CSTR). 8.1 Design Equations and Auxiliary Relations. 8.2 Isothermal Operations with Single Reactions. 8.3 Isothermal Operations with Multiple Reactions. 8.4 Non-Isothermal Operations. 8.5 Summary. Problems. Chapter 9: Other Reactor Configurations. 9.1 Semi-Batch Reactors. 9.2 Plug-Flow Reactor with Distributed Feed. 9.3 Distillation Reactor. 9.4 Recycle Reactor. 9.5 Summary. Problems. Chapter 10: Economic-Based Optimization of Reactor Operations. 10.1 Economic Objective Functions. 10.2 Batch and Semi-Batch Reactors. 10.3 Flow Reactors. 10.4 Summary. Problems. Appendices. Appendix A: Summary of Key Relationships. Appendix B: Microscopic Species Balances - Continuity Equations. Appendix C: Summary of Numerical Methods. Index.
- (source: Nielsen Book Data)
(source: Nielsen Book Data)
Online
www3.interscience.wiley.com
- www3.interscience.wiley.com
- dx.doi.org Wiley Online Library
- Google Books (Full view)
- Book
- 1 online resourece (xxxii, 608 p.) : ill.
Summary
(source: Nielsen Book Data)
(source: Nielsen Book Data)
- Preface to the Second Edition. Symbols. 1 Elementary Reactions in Ideal Reactors. 1.1 Material Balances. 1.2 Elementary Reactions. 1.3 Reaction Order and Mechanism. 1.4 Ideal, Isothermal Reactors. 1.5 Mixing Times and Scaleup. 1.6 Dimensionless Variables and Numbers. 1.7 Batch Versus Flow and Tank Versus Tube. 2 Multiple Reactions in Batch Reactors. 2.1 Multiple and Nonelementary Reactions. 2.2 Component Reaction Rates for Multiple Reactions. 2.3 Multiple Reactions in Batch Reactors. 2.4 Numerical Solutions to Sets of First-Order ODEs. 2.5 Analytically Tractable Examples. 2.6 Variable-Volume Batch Reactors. 2.7 Scaleup of Batch Reactions. 2.8 Stoichiometry and Reaction Coordinates. 3 Isothermal Piston Flow Reactors. 3.1 Piston Flow with Constant Mass Flow. 3.2 Scaleup Relationships for Tubular Reactors. 3.3 Scaleup Strategies for Tubular Reactors. 3.4 Scaling Down. 3.5 Transpired-Wall Reactors. 4 Stirred Tanks and Reactor Combinations. 4.1 Continuous Flow Stirred Tank Reactors. 4.2 Method of False Transients. 4.3 CSTRs with Variable Density. 4.4 Scaling Factors for Liquid Phase Stirred Tanks. 4.5 Combinations of Reactors. 4.6 Imperfect Mixing. 5 Thermal Effects and Energy Balances. 5.1 Temperature Dependence of Reaction Rates. 5.2 Energy Balance. 5.3 Scaleup of Nonisothermal Reactors. 6 Design and Optimization Studies. 6.1 Consecutive Reaction Sequence. 6.2 Competitive Reaction Sequence. 7 Fitting Rate Data and Using Thermodynamics. 7.1 Fitting Data to Models. 7.2 Thermodynamics of Chemical Reactions. 8 Real Tubular Reactors in Laminar Flow. 8.1 Flow in Tubes with Negligible Diffusion. 8.2 Tube Flows with Diffusion. 8.3 Method of Lines. 8.4 Effects of Variable Viscosity. 8.5 Comprehensive Models. 8.6 Performance Optimization. 8.7 Scaleup of Laminar Flow Reactors. 9 Packed Beds and Turbulent Tubes. 9.1 Packed-Bed Reactors. 9.2 Turbulence. 9.3 Axial Dispersion Model. 9.4 Scaleup and Modeling Considerations. 10 Heterogeneous Catalysis. 10.1 Overview of Transport and Reaction Steps. 10.2 Governing Equations for Transport and Reaction. 10.3 Intrinsic Kinetics. 10.4 Effectiveness Factors. 10.5 Experimental Determination of Intrinsic Kinetics. 10.6 Unsteady Operation and Surface Inventories. 11 Multiphase Reactors. 11.1 Gas-Liquid and Liquid-Liquid Reactors. 11.2 Three-Phase Reactors. 11.3 Moving-Solids Reactors. 11.4 Noncatalytic Fluid-Solid Reactions. 11.5 Scaleup of Multiphase Reactors. 12 Biochemical Reaction Engineering. 12.1 Enzyme Catalysis. 12.2 Cell Culture. 12.3 Combinatorial Chemistry. 13 Polymer Reaction Engineering. 13.1 Polymerization Reactions. 13.2 Molecular Weight Distributions. 13.3 Kinetics of Condensation Polymerizations. 13.4 Kinetics of Addition Polymerizations. 13.5 Polymerization Reactors. 13.6 Scaleup Considerations. 14 Unsteady Reactors. 14.1 Unsteady Stirred Tanks. 14.2 Unsteady Piston Flow. 14.3 Unsteady Convective Diffusion. 15 Residence Time Distributions. 15.1 Residence Time Theory. 15.2 Residence Time Models. 15.3 Reaction Yields. 15.4 Extensions of Residence Time Theory. 15.5 Scaleup Considerations. 16 Reactor Design at Meso-, Micro-, and Nanoscales. 16.1 Mesoscale Reactors. 16.2 Microscale Reactors. 16.3 Nanoscale Reactors. 16.4 Scaling, Up or Down. Suggested Further Readings. Problems. References. Index.
- (source: Nielsen Book Data)
(source: Nielsen Book Data)
- Preface to the Second Edition. Symbols. 1 Elementary Reactions in Ideal Reactors. 1.1 Material Balances. 1.2 Elementary Reactions. 1.3 Reaction Order and Mechanism. 1.4 Ideal, Isothermal Reactors. 1.5 Mixing Times and Scaleup. 1.6 Dimensionless Variables and Numbers. 1.7 Batch Versus Flow and Tank Versus Tube. 2 Multiple Reactions in Batch Reactors. 2.1 Multiple and Nonelementary Reactions. 2.2 Component Reaction Rates for Multiple Reactions. 2.3 Multiple Reactions in Batch Reactors. 2.4 Numerical Solutions to Sets of First-Order ODEs. 2.5 Analytically Tractable Examples. 2.6 Variable-Volume Batch Reactors. 2.7 Scaleup of Batch Reactions. 2.8 Stoichiometry and Reaction Coordinates. 3 Isothermal Piston Flow Reactors. 3.1 Piston Flow with Constant Mass Flow. 3.2 Scaleup Relationships for Tubular Reactors. 3.3 Scaleup Strategies for Tubular Reactors. 3.4 Scaling Down. 3.5 Transpired-Wall Reactors. 4 Stirred Tanks and Reactor Combinations. 4.1 Continuous Flow Stirred Tank Reactors. 4.2 Method of False Transients. 4.3 CSTRs with Variable Density. 4.4 Scaling Factors for Liquid Phase Stirred Tanks. 4.5 Combinations of Reactors. 4.6 Imperfect Mixing. 5 Thermal Effects and Energy Balances. 5.1 Temperature Dependence of Reaction Rates. 5.2 Energy Balance. 5.3 Scaleup of Nonisothermal Reactors. 6 Design and Optimization Studies. 6.1 Consecutive Reaction Sequence. 6.2 Competitive Reaction Sequence. 7 Fitting Rate Data and Using Thermodynamics. 7.1 Fitting Data to Models. 7.2 Thermodynamics of Chemical Reactions. 8 Real Tubular Reactors in Laminar Flow. 8.1 Flow in Tubes with Negligible Diffusion. 8.2 Tube Flows with Diffusion. 8.3 Method of Lines. 8.4 Effects of Variable Viscosity. 8.5 Comprehensive Models. 8.6 Performance Optimization. 8.7 Scaleup of Laminar Flow Reactors. 9 Packed Beds and Turbulent Tubes. 9.1 Packed-Bed Reactors. 9.2 Turbulence. 9.3 Axial Dispersion Model. 9.4 Scaleup and Modeling Considerations. 10 Heterogeneous Catalysis. 10.1 Overview of Transport and Reaction Steps. 10.2 Governing Equations for Transport and Reaction. 10.3 Intrinsic Kinetics. 10.4 Effectiveness Factors. 10.5 Experimental Determination of Intrinsic Kinetics. 10.6 Unsteady Operation and Surface Inventories. 11 Multiphase Reactors. 11.1 Gas-Liquid and Liquid-Liquid Reactors. 11.2 Three-Phase Reactors. 11.3 Moving-Solids Reactors. 11.4 Noncatalytic Fluid-Solid Reactions. 11.5 Scaleup of Multiphase Reactors. 12 Biochemical Reaction Engineering. 12.1 Enzyme Catalysis. 12.2 Cell Culture. 12.3 Combinatorial Chemistry. 13 Polymer Reaction Engineering. 13.1 Polymerization Reactions. 13.2 Molecular Weight Distributions. 13.3 Kinetics of Condensation Polymerizations. 13.4 Kinetics of Addition Polymerizations. 13.5 Polymerization Reactors. 13.6 Scaleup Considerations. 14 Unsteady Reactors. 14.1 Unsteady Stirred Tanks. 14.2 Unsteady Piston Flow. 14.3 Unsteady Convective Diffusion. 15 Residence Time Distributions. 15.1 Residence Time Theory. 15.2 Residence Time Models. 15.3 Reaction Yields. 15.4 Extensions of Residence Time Theory. 15.5 Scaleup Considerations. 16 Reactor Design at Meso-, Micro-, and Nanoscales. 16.1 Mesoscale Reactors. 16.2 Microscale Reactors. 16.3 Nanoscale Reactors. 16.4 Scaling, Up or Down. Suggested Further Readings. Problems. References. Index.
- (source: Nielsen Book Data)
(source: Nielsen Book Data)
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